We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
Building upon the work of Hu, Paz, and Zhang [1,2] on open quantum systems we consider the quantum Brownian motion (QBM) model with one oscillator (position variable
x) as the system, {\it nonlinearly} coupled to an environment of
N harmonic oscillators (with mass
mn, natural frequency
ωn, position
qn and momentum
pn variables) in the form
∑n(vn1(x)qnk+vn2(x)pnl) where
k,l are integers (the present work only considers the
k=l=2 cases). The vertex functions $v_{n1}, v_{n2} $ are of the form
vn1=λCn1f(x),vn2(x)=−λCn2mn−2ωn−2f(x) where
Cn1,2 are the coupling constants with the
nth oscillator,
f(x) is any arbitrary function of
x, and
λ is a dimensionless constant. Employing the closed-time-path formalism the influence action
SIF is calculated using a perturbative expansion in
λ. It is possible to identify the terms in
SIF quadratic or higher in
Δ(s)≡f(x+(s))−f(x−(s)) to constitute the noise kernel, while terms linear in
Δ to that of the dissipation kernel. The non-Gaussian noise kernel gives rise to non-zero three-point correlation function of the corresponding stochastic force. The pathway presented here should be useful for the exploration of \textit{non-Gaussian properties of systems nonlinearly coupled with their environments}; examples in early universe cosmology and in quantum optomechanics (QOM) are mentioned. A modified fluctuation-dissipation relation (FDR) is also established, which ensures the consistency of the model and the accuracy of results even at higher perturbative orders. Another result of significance is the derivation of a nonlinear Langevin equation which is expected to be useful for many open quantum system applications.
Abstract General concepts in the theory of fluctuations and dissipation are reviewed and applied to examples in quantum optics. Brownian motion, Fokker-Planck and Langevin equations, and the Wiener-Khintchine theorem are reviewed, followed by a derivation and discussion of the fluctuation-dissipation theorem. The general problem of an oscillator coupled to a heat bath is revisited, as is the nonrelativistic theory of radiation reaction. The general ideas about fluctuations and dissipation developed in the first part of the chapter are then applied to the theory of the fundamental laser linewidth, the photon statistics of linear amplifiers and attenuators, the noise figure, amplified spontaneous emission, and the quantum theory of the beam slitter and homodyne detection.
We consider the non-Markovian Langevin evolution of a dissipative dynamical system in quantum mechanics in the path integral formalism. After discussing the role of the frequency cutoff for the interaction of the system with the heat bath and the kernel and noise correlator that follow from the most common choices, we derive an analytic expansion for the exact non-Markovian dissipation kernel and the corresponding colored noise in the general case that is consistent with the fluctuation-dissipation theorem and incorporates systematically non-local corrections. We illustrate the modifications to results obtained using the traditional (Markovian) Langevin approach in the case of the exponential kernel and analyze the case of the non-Markovian Brownian motion.
We analytically describe the decay to equilibrium of generic observables of a nonintegrable system after a perturbation in the form of a random matrix. We further obtain an analytic form for the time-averaged fluctuations of an observable in terms of the rate of decay to equilibrium. Our result shows the emergence of a fluctuation-dissipation theorem corresponding to a classical Brownian process, specifically, the Ornstein-Uhlenbeck process. Our predictions can be tested in quantum simulation experiments, thus helping to bridge the gap between theoretical and experimental research in quantum thermalization. We test our analytic results by exact numerical experiments in a spin chain. We argue that our fluctuation-dissipation relation can be used to measure the density of states involved in the nonequilibrium dynamics of an isolated quantum system.
Abstract We propose a Langevin equation to describe the quantum Brownian motion of bounded particles based on a distinctive formulation concerning both the fluctuation and dissipation forces. The fluctuation force is similar to that employed in the classical case. It is a white noise with a variance proportional to the temperature. The dissipation force is not restricted to be proportional to the velocity and is determined in a way as to guarantee that the stationary state is given by a density operator of the Gibbs canonical type. To this end we derived an equation that gives the time evolution of the density operator, which turns out to be a quantum Fokker–Planck–Kramers equation. The approach is applied to the harmonic oscillator in which case the dissipation force is found to be non Hermitian and proportional to the velocity and position.