It is often claimed, that from a quantum system of d levels, and entropy S and heat bath of temperature T one can draw kT(ln d -S) amount of work. However, the usual arguments based on Szilard engine are not fully rigorous. Here we prove the formula within Hamiltonian description of drawing work from a quantum system and a heat bath, at a cost of entropy of the system. We base on the derivation of thermodynamical laws and quantities in [R. Alicki, J. Phys. A, 12, L103 (1979)] within a weak coupling limit. Our result provides fully physical scenario for extracting thermodynamical work from quantum correlations [J. Oppenheim et al. Phys. Rev. Lett. 89, 180402 (2002)]. We also derive Landauer principle as a consquence of second law within the considered model.
It is often claimed, that from a quantum system of d levels, and entropy S and heat bath of temperature T one can draw kT(ln d -S) amount of work. However, the usual arguments based on Szilard engine are not fully rigorous. Here we prove the formula within Hamiltonian description of drawing work from a quantum system and a heat bath, at a cost of entropy of the system. We base on the derivation of thermodynamical laws and quantities in [R. Alicki, J. Phys. A, 12, L103 (1979)] within a weak coupling limit. Our result provides fully physical scenario for extracting thermodynamical work from quantum correlations [J. Oppenheim et al. Phys. Rev. Lett. 89, 180402 (2002)]. We also derive Landauer principle as a consquence of second law within the considered model.
It is often claimed, that from a quantum system of d levels, and entropy S and heat bath of temperature T one can draw kT lnd–TS amount of work. However, the usual arguments basing on Szilard engine, are not fully rigorous. Here we prove the formula within Hamiltonian description of drawing work from a quantum system and a heat bath, at the cost of entropy of the system. We base on the derivation of thermodynamical laws and quantities in [10] within weak coupling limit. Our result provides fully physical scenario for extracting thermodynamical work form quantum correlations [4]. We also derive Landauer's principle as a consequence of the second law within the considered model.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature. We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
Extending the quantum formulation of [Phys. Rev. X 3, 041003 (2013)] to a more general setting for studying the thermodynamics of information processing including initial correlations, we generalize the second law of thermodynamics to account for information processing in such autonomous systems. We consider a composite quantum system consisting of a principal system, heat bath, memory, and work source, and adopt an autonomous Hamiltonian framework. We derive constraints on the total Hamiltonian that ensure the work source to act as a catalyst preserving its original randomness, namely that the total unitary evolution must have a unitary partial transpose. We show that this requirement is equivalent to the commutativity of operators acting on the joint system of the principal system, bath, and memory, which underlies the Hamiltonian structure. Next, we generalize the quantum speed limit for the joint dynamics of system and memory to the quantum thermodynamic speed limit, from which we obtain a dynamical version of Landauer's bound. More importantly, we also interpret this quantum thermodynamic speed limit in the context of quantum hypothesis testing.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature . We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
We present a critical examination of the difficulties with the quantum versions of a lifted weight that are widely used as work storage systems in quantum thermodynamics. To overcome those difficulties, we turn to the strong connections between information and thermodynamics illuminated by Szilard’s engine and Landauer’s principle, and consider the concept of informational work storage. This concept is in sharp contrast with the usual one of mechanical work storage underlying the idealization of a quantum weight. An informational work storage system based on maximally mixed qubits that does not act as an entropy sink and is capable of truly distinguishing work from heat is studied. Applying it to the problem of single-shot work extraction in various extraction schemes, we show that for a given system state the maximum extractable work is independent of extraction scheme, in accordance with the second law of thermodynamics.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.