Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature . We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature . We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature. We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
Thermodynamics is one of the main pillars of theoretical physics, and it has a special appeal of having wide applicability to a large variety of different physical systems. However, many assumptions in thermodynamics apply only to systems which are bulk material, i.e. consisting a large number of microscopic classical particles. Due to the advancement of designing nanoscale engines, especially in the light of devices that are used today in the processing of quantum information, is thermodynamics still applicable? Can we refine the core principles of thermodynamics to suit such nanoscale quantum systems as well? The central aim of this thesis is to construct a theory of thermodynamics that holds for nanoscale quantum systems, even those as small and simple as a single qubit. We do this by starting out from the core basics of quantum theory: unitary dynamics on closed quantum systems. We adapt a resource theoretic approach inspired by quantum information theory, which defines the quantum states and operations allowed to be used in a thermodynamic evolution. With this framework that naturally adopts the first law as an energy preserving condition, we show the refinement of both the zeroeth and second law of thermodynamics. The zeroeth law explains the physical significance of the Gibbs thermal state. On the other hand, we show that the second law sees refinement in the quantum nanoregime: instead of having the free energy as the sole quantity dictating the possibility of a thermodynamic state transition, we derive a family of generalized free energies that also constitute necessary conditions for a transition to occur. Moreover, these conditions become sufficient for states which are block-diagonal in the energy eigenbasis. In this thesis, we also brought our approach of thermodynamics to the next step: we apply our findings on the second laws, in order to analyze the maximum achievable efficiency for quantum heat engines. In classical thermodynamics, the Carnot efficiency has been long known as the theoretical maximum which does not depend on the specific structure of the thermal baths used, but only on its temperature. With the additional free energies we discover, we show that although quantum heat engines may achieve the Carnot efficiency, such an achievability is no longer independent of the Hamiltonians of the thermal baths. In other words, we find additional restrictions that surface in the study of quantum nanoscale heat engines, which are a direct consequence of the generalized second laws. This has provided us with a deeper understanding into the fundamental limitations of how efficient devices can be made in the realm of microscopic quantum systems.
The concept of thermal information conservation offers a new perspective on the interplay between thermodynamics and quantum information theory. In this work we introduce the thermal information quantity Q_T, defined for an isolated quantum system as the negative logarithm of the density of states weighted by the Boltzmann factor. We demonstrate that Q_T behaves as a conserved quantity during unitary evolution under a broad class of Hamiltonians that respect a hidden symmetry connecting energy and entropy. By establishing a rigorous link between Q_T and the von Neumann entropy, we show that the standard second law of thermodynamics can be viewed as a special case of a more general conservation principle. The implications of this principle for the design of quantum thermal engines, error‑free quantum memory, and the fundamental limits of heat transport are discussed. The framework also provides a natural bridge between classical thermodynamic irreversibility and quantum reversibility, suggesting that the apparent arrow of time in macroscopic systems may emerge from constraints on Q_T rather than from entropy production alone. Keywords: Thermal information, quantum thermodynamics, conservation law, entropy, quantum engines.
The first law of thermodynamics, which governs energy conservation, is traditionally formulated as an equality. Surprisingly, we demonstrate that the first law alone implies a universal Landauer-like inequality linking changes in system entropy and energy. However, contrasting with the Landauer principle derived from the second law of thermodynamics, our obtained Landauer-like inequality solely relies on system information and is applicable in scenarios where implementing the Landauer principle becomes challenging. Furthermore, the Landauer-like inequality can complement the Landauer principle by establishing a dual {\it upper} bound on heat dissipation. We illustrate the practical utility of the Landauer-like inequality in dissipative quantum state preparation and quantum information erasure applications. Our findings offer new insights into identifying thermodynamic constraints relevant to the fields of quantum thermodynamics and the energetics of quantum information processing and more specifically, this approach could facilitate investigations into systems coupled to non-thermal baths or scenarios where access to bath information is limited.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.