A rigorous application of the correspondence rules shows that the operator of the angular momentum of a quantum particle---corresponding to the classical magnitude $\mathbf{l}= m \mathbf{r} \wedge \mathbf{v}$---is given by $\mathbf{\hat{l}}=\mathbf{r}\wedge(-i\hbar\mathbf{\nabla} -\frac{e}{c}\mathbf{A})$ in the presence of an electromagnetic field. Thus, despite the general opinion on the corresponding rules of quantization, the eigenvalues of the angular momentum depend on the configuration of the electromagnetic field. The usual rules of commutation $[{\hat{l}}_i,{\hat{l}}_j]=i\hbarε_{ijk}{\hat{l}}_k$, that are at the foundation of the calculus of angular momentum and of the theory of \emph{spin}---and Bohm's example of the EPR argument---are not valid in the presence of an electromagnetic field. The expected value of the operator $\mathbf{\hat{l}}=-i\hbar\mathbf{r}\wedge\mathbf{\nabla}$ is not gauge invariant, it depends on the calibration of the electrodynamic potentials.
A rigorous application of the correspondence rules shows that the operator of the angular momentum of a quantum particle---corresponding to the classical magnitude l=mr∧v---is given by l^=r∧(−iℏ∇−ceA) in the presence of an electromagnetic field. Thus, despite the general opinion on the corresponding rules of quantization, the eigenvalues of the angular momentum depend on the configuration of the electromagnetic field. The usual rules of commutation [l^i,l^j]=iℏεijkl^k, that are at the foundation of the calculus of angular momentum and of the theory of \emph{spin}---and Bohm's example of the EPR argument---are not valid in the presence of an electromagnetic field. The expected value of the operator l^=−iℏr∧∇ is not gauge invariant, it depends on the calibration of the electrodynamic potentials.
By introducing operator representations for angular-momentum states referred to arbitrary axes of quantization, two independent angular momenta, each referred to its own axis of quantization, may be combined quantum-mechanically. An interpretation in terms of complementarity shows that this method of adding angular momenta corresponds to a "causal" description, while the usual method (using only one axis of quantization) is a "geometric" or spacetime description. "Causal" angular-momentum states automatically avoid the sums over magnetic quantum numbers in cascade processes.
In this paper it is shown that Maxwell's theory of the electromagnetic field in vacuum can be stated in a form closely parallel to Dirac's theory of the electron. The electromagnetic field is described by a three-by-one column matrix whose elements are linear combinations of the three independent spinor components of the field. The Maxwell equations take a form similar to the Dirac equation for a free electron but involving three-by-three matrices. In terms of a wave function normalized so that the integral-square is the number of photons, the classical expressions for the energy, momentum, and angular momentum in the field are related to expected values of the Hamiltonian, momentum, and angular momentum operators. The angular momentum operator consists of an orbital part plus a three-by-three spin-one matrix part. As in Dirac's theory, the contributions from the states of negative Hamiltonian eigenvalue must be subtracted---these are states of opposite circular polarization.
It is shown by direct computation that angular momentum cannot be reduced to two dimensions by assuming lack of dependence on the z coordinate. Formally, this is because the independence of z breaks rotational invariance. As a physical example, it is shown that a gauge- and rotation-invariant description of planar electrons in a perpendicular magnetic field must have a three-dimensional form, even though all the terms refer to planar coordinates alone. The physical concepts underlying common formal manipulations with the quantum angular momentum operator are treated at a level directly useful to students encountering them thoroughly for the first time. The letter may also serve as a contextual introduction to advanced quantization issues, usually studied at graduate level.
Angular momentum is one of the more abstract topics in quantum mechanics. This chapter begins with a review of classical angular momentum. Quantum-mechanical angular momentum is then introduced by obtaining operators from their classical counterparts. The commutation relations amongst those operators and the corresponding uncertainty relations then follow. Eigenstates and eigenvalues of the angular momentum operators are then introduced (but not derived). From these follow the raising and lowering operators. Physical meaning is imparted to quantum angular momentum by considering predictions for sequential measurements, and by comparing the conceptual pictures of angular momentum in classical and quantum mechanics. Finally, quantum spin and orbital angular momenta, and the deep differences between them, are discussed.
Physical processes are usually described using four-dimensional vector quantities - coordinate vector, momentum vector, current vector. But at the fundamental level they are characterized by coordinate and momentum spinors. The propagation of fields and their interaction takes place at the spinor level, and since each spinor uniquely corresponds to a certain vector, the results of physical processes appear before us in vector form. For example, the relativistic Schrödinger equation and the Dirac equation are formulated by means of coordinate vectors, momentum vectors and quantum operators corresponding to them. In the Dirac equation the wave function is a spinor with complex components, but still coordinates and momentum are vectors. For a closed description of nature using only spinor quantities, it is necessary to have an equation similar to the Dirac equation in which momentum, coordinates and operators are spinors. It is such an equation that is presented in this paper. Using the example of the interaction between an electron and an electromagnetic field, we can see that the spinor equation contains more detailed information about the interaction than the vector equations. This is not new for quantum mechanics, since it describes interactions using complex wave functions, which cannot be observed directly, and only when measured goes to probabilities in the form of squares of the moduli of the wave functions. In the same way spinor quantities are not observable, but they completely determine observable vectors. In Section 2 of the paper, we analyze the quadratic form for an arbitrary four-component complex vector based on Pauli matrices. The form is invariant with respect to Lorentz transformations including any rotations and boosts. The invariance of the form allows us to construct on its basis an equation for a free particle combining the properties of the relativistic wave equation and the Dirac equation. For an electron in the presence of an electromagnetic potential it is shown that taking into account the commutation relations between the momentum and coordinate components allows us to obtain from this equation the known results describing the interactions of the electron spin with the electric and magnetic field. In the presence of a potential the momentum components cease to commute with each other. To neutralize this effect, the Schrödinger equation is supplemented by several equations with mixed partial derivatives on coordinates. In section 3 of the paper this quadratic form is expressed through momentum spinors, which makes it possible to obtain an equation for the spinor wave function in spinor coordinate space by replacing the momentum spinor components by partial derivative operators on the corresponding coordinate spinor component. Section 4 presents a modification of the theory of the path integral, which consists in considering the path integral in the spinor coordinate space. The Lagrangian densities for the scalar field and for the electron field, along with their corresponding propagators, are presented. An equation of motion for the electron is proposed that is relativistically invariant. This novel equation permitted the construction of an actually invariant procedure for the second quantization of the fermion field in spinor coordinate space. Furthermore, it is demonstrated that the field operators are a combination of plane waves in spinor or vector space, with the coefficients of which being pseudospinors or pseudovectors. Each of these pseudovectors or pseudospinors corresponds to one of the particles presented in the theory of electrodynamics. Furthermore, each plane wave possesses an additional coefficient in the form of a creation or annihilation operator. In vector space, these operators commute, whereas in spinor space they anticommutate. The paper presents the spinor and vector representations of the field operators in explicit form, comprising sets of 16 pseudospinors or 4 pseudovectors corresponding to particles represented in electrodynamics. An explicit form of the symmetric traceless tensor with spin two, zero mass and two polarizations is presented, which can serve as a model of the graviton. The results obtained may prompt changes in some aspects of the construction of Feynman diagrams. Among other things, it presents a purely mathematical derivation of Maxwell's inhomogeneous equations without reference to empirical data on the action of electric current, which is usually referred to when deriving equations. Section 4 presents Einstein's inhomogeneous equation, which features the Riemann tensor rather than the Ricci tensor, with the energy-momentum tensor of a charged particle having four indices rather than two. In the case where a particle of matter has a charge, another Riemann tensor is added to Einstein’s equation, in addition to the usual Riemann curvature tensor, which describes the additional curvature created for a charged particle by an electromagnetic field.
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.