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arXiv:quant-ph/0206143 · The Journal of Physical Chemistry A

Quantum Zeno Effect in a Model Multilevel Molecule

Domenico Bruno, Paolo Facchi A, Savino Longo, P. Minelli, Saverio Pascazio, Antonello Scardicchio

Published Oct 29, 2009• 2 citations
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Abstract

We study the dynamics of the populations of a model molecule endowed with two sets of rotational levels of different parity, whose ground levels are energetically degenerate and coupled by a constant interaction. The relaxation rate from one set of levels to the other one has an interesting dependence on the average collision frequency of the molecules in the gas. This is interpreted as a quantum Zeno effect due to the decoherence effects provoked by the molecular collisions.

DOI
10.1021/jp9050512

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We study the dynamics of the populations of a model molecule endowed with two sets of rotational levels of different parity, whose ground levels are energetically degenerate and coupled by a constant interaction. The relaxation rate from one set of levels to the other one has an interesting dependence on the average collision frequency of the molecules in the gas. This is interpreted as a quantum Zeno effect due to the decoherence effects provoked by the molecular collisions.
A model multilevel molecule described by two sets of rotational internal energy levels of different parity and degenerate ground states, coupled by a constant interaction, is considered, by assuming that the random collisions in a gas of identical molecules, provoke transitions between adjacent energy levels of the same parity. The prescriptions of the continuous time quantum random walk is applied to the single molecule, interpreted as an open quantum system, and the master equation driving its internal dynamics is built for a general distribution of random collision times. Over estimated long time scales, the dynamics of the coherence terms and the populations of the energy levels is evaluated analytically for relevant classes of non-Poissonian distributions of the collision times. Inverse power law relaxations and the inverse Zeno effect emerge over estimated long time scales and the stable asymptotic equilibrium configuration results to be independent of the distribution of the collision times.
Using an optical centrifuge to control molecular rotation in an extremely broad range of angular momenta, we study coherent rotational dynamics of nitrogen molecules in the presence of collisions. We cover the range of rotational quantum numbers between J=8 and J=66 at room temperature and study a crossover between the adiabatic and nonadiabatic regimes of rotational relaxation, which cannot be easily accessed by thermal means. We demonstrate that the rate of rotational decoherence changes by more than an order of magnitude in this range of J values and show that its dependence on J can be described by a simplified scaling law.
Zeno and anti-Zeno effects in the evolution of the multi-photonic dissociation dynamics of the diatomic molecule HBr[Formula: see text] owing to repeated measurements demand if the system in the initial state have been studied. The effects have been calculated numerically for the case of vibrational population transfer and dissociation dynamics of HBr[Formula: see text] taking it as a model. We use time-dependent Fourier grid Hamiltonian (TDFGH) method as a mathematical tool in presence of intense radiation field as perturbation. The effects have been explored through a probable mechanism of population transfer from the ground vibrational state to the different upper vibrational states which ultimately go to the dissociation continuum. The results show significant differences in the mechanism of population transfer and the significant role of time interval of measurement ([Formula: see text] in Zeno and anti-Zeno effects. In case of survival probability of ground vibrational states, there is Zeno effect when the frequency of the laser to which the molecule is submitted is near the vibrational [Formula: see text] to [Formula: see text] resonance, while there is anti-Zeno effect if it is far from this resonance.
It is proven experimentally that the ortho-para conversion of the nuclear spin isomers of 13CH3F{}^{13}{\mathrm{CH}}_{3}\mathrm{F}13CH3​F molecules can be slowed down by increasing the gas pressure. The observed ``freezing'' of the molecular quantum states can be considered as an example of the quantum Zeno effect induced by collisions.
Abstract We experimentally study quantum Zeno effects in a parity-time (PT) symmetric cold atom gas periodically coupled to a reservoir. Based on the state-of-the-art control of inter-site couplings of atoms in a momentum lattice, we implement a synthetic two-level system with passive PT symmetry over two lattice sites, where an effective dissipation is introduced through repeated couplings to the rest of the lattice. Quantum Zeno (anti-Zeno) effects manifest in our experiment as the overall dissipation of the two-level system becoming suppressed (enhanced) with increasing coupling intensity or frequency. We demonstrate that quantum Zeno regimes exist in the broken PT symmetry phase, and are bounded by exceptional points separating the PT symmetric and PT broken phases, as well as by a discrete set of critical coupling frequencies. Our experiment establishes the connection between PT-symmetry-breaking transitions and quantum Zeno effects, and is extendable to higher dimensions or to interacting regimes, thanks to the flexible control with atoms in a momentum lattice.
Analytical expressions for describing the dynamics of the populations of the states of a five-level model molecule during fluorescence reflecting the quantum beats of the populations of its two excited degenerate states coupled by dynamic interaction are derived. The cases of excitation of the molecule by a short light pulse in a state with an energy higher than the energy of the degenerate states and into one of the degenerate states are considered. The populations of states are determined by solving the Schrödinger equation for the amplitudes of probability of populating the states of the composite system comprised of the molecule and a quantized radiation field. It was found that the resulting expressions satisfy the optical Bloch equations for the considered dynamics of the populations of the molecule’s states. Significant distinctions of the present results on the simulation of quantum beats from the corresponding simulation results reported in some works, performed based on different approaches, are revealed. The reasons for these differences are discussed.