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arXiv:quant-ph/0205192 · Fortschritte der Physik

Dipole‐dipole coupling in the presence of dispersing and absorbing bodies

D.‐G. Welsch, H.T. Dung, L. Knöll

Published Feb 26, 2003• 5 citations
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Abstract

Abstract An effective Hamiltonian and equations of motion for treating both the resonant dipole‐dipole interaction between two‐level atoms and the resonant atom‐field interaction are derived, which can suitably be used for studying the influence of arbitrary dispersing and absorbing material surroundings on these interactions. It is shown that the dipole‐dipole interaction and the atom‐field interaction, respectively, are closely related to the real part and the imaginary part of the (classical) Green tensor. The theory is applied to the study of the transient behavior of two atoms that initially share a single excitation, with special emphasis on the role of the two competing processes of virtual and real photon exchange in the energy transfer between the atoms. To illustrate the powerfulness of the theory, specific results for the case of the atoms being near a dispersing and absorbing microsphere are presented. In particular, the regimes of weak and strong atom‐field coupling are addressed.

DOI
10.1002/prop.200310036

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Abstract An effective Hamiltonian and equations of motion for treating both the resonant dipole‐dipole interaction between two‐level atoms and the resonant atom‐field interaction are derived, which can suitably be used for studying the influence of arbitrary dispersing and absorbing material surroundings on these interactions. It is shown that the dipole‐dipole interaction and the atom‐field interaction, respectively, are closely related to the real part and the imaginary part of the (classical) Green tensor. The theory is applied to the study of the transient behavior of two atoms that initially share a single excitation, with special emphasis on the role of the two competing processes of virtual and real photon exchange in the energy transfer between the atoms. To illustrate the powerfulness of the theory, specific results for the case of the atoms being near a dispersing and absorbing microsphere are presented. In particular, the regimes of weak and strong atom‐field coupling are addressed.
Within the framework of quantization of the macroscopic electromagnetic field, equations of motion and an effective Hamiltonian for treating both the resonant dipole-dipole interaction between two-level atoms and the resonant atom-field interaction are derived, which can suitably be used for studying the influence of arbitrary dispersing and absorbing material surroundings on these interactions. The theory is applied to the study of the transient behavior of two atoms that initially share a single excitation, with special emphasis on the role of the two competing processes of virtual- and real-photon exchange in the energy transfer between the atoms. In particular, it is shown that for weak atom-field interaction there is a time window, where the energy transfer follows a rate regime of the type obtained by ordinary second-order perturbation theory. Finally, it is shown that the resonant dipole-dipole interaction can change the singlet line of the emitted light to a doublet spectrum for weak atom-field interaction and the doublet spectrum to a triplet spectrum for strong atom-field interaction.
Within the framework of quantization of a macroscopic electromagnetic field, a master equation describing both the resonant dipole-dipole interaction (RDDI) and the resonant atom-field interaction in the presence of dispersing and absorbing macroscopic bodies is derived, with the relevant couplings being expressed in terms of the surroundings-assisted Green’s tensor. It is shown that, under certain conditions, the RDDI can be regarded as being governed by an effective Hamiltonian. The theory, which applies to both weak and strong atom-field coupling, is used to study the resonant energy exchange between two (two-level) atoms initially sharing a single excitation. In particular, it is shown that, in the regime of weak atom-field coupling, there is a time window where the energy transfer follows a transfer-rate law of the type obtained by ordinary second-order perturbation theory. Finally, the spectrum of the light emitted during the energy transfer is studied and the line splittings are discussed.
Within the framework of quantization of the macroscopic electromagnetic field, a master equation describing both the resonant dipole-dipole interaction (RDDI) and the resonant atom-field interaction (RAFI) in the presence of dispersing and absorbing macroscopic bodies is derived, with the relevant couplings being expressed in terms of the surroundings-assisted Green tensor. It is shown that under certain conditions the RDDI can be regarded as being governed by an effective Hamiltonian. The theory, which applies to both weak and strong atom-field coupling, is used to study the resonant energy exchange between two (two-level) atoms sharing initially a single excitation. In particular, it is shown that in the regime of weak atom-field coupling there is a time window, where the energy transfer follows a transfer-rate law of the type obtained by ordinary second-order perturbation theory. Finally, the spectrum of the light emitted during the energy transfer is studied and the line splittings are discussed.
A general theory of the interaction of the quantized electromagnetic field with atoms, in the presence of dispersing and absorbing dielectric bodies of given Kramers-Kronig consistent permittivities, is developed. It is based on a source-quantity representation of the electromagnetic field, in which the electromagnetic-field operators are expressed in terms of a continuous set of fundamental bosonic fields via the Green tensor of the classical problem. Introducing scalar and vector potentials, the formalism is extended to include in the theory the interaction of the quantized electromagnetic field with additional atoms. Both the minimal-coupling scheme and the multipolar-coupling scheme are considered. The theory replaces the standard concept of mode decomposition, which fails for complex permittivities. It enables us to treat the effects of dispersion and absorption in a consistent way and to give a unified approach to the atom-field interaction, without any restriction to a particular interaction regime in a particular frequency range. All relevant information about the dielectric bodies, such as form and intrinsic dispersion and absorption, is contained in the Green tensor. The application of the theory to the spontaneous decay of an excited atom in the presence of dispersing and absorbing bodies is addressed.
Starting from the quantized version of Maxwell's equations for the electromagnetic field in an arbitrary linear Kramers-Kronig dielectric, the Heisenberg equations of motion for a two-level atom resonantly coupled to the radiation field in the presence of dispersive and absorbing dielectric bodies are derived. The theory is applied to the problem of spontaneous decay of excited atoms in absorbing media. The decay rate is calculated for the (Glauber-Lewenstein) real-cavity model, and a comparison with the recently studied (Clausius-Mosotti) virtual-cavity model [S. Scheel, L. Kn\"oll, D.-G. Welsch, and S. M. Barnett, Phys. Rev. A 60, 1590 (1999)] is given. It is shown that owing to nonradiative decay associated with absorption, the rate of spontaneous decay sensitively depends on the cavity radius, particularly when the atomic transition frequency approaches an absorption band of the medium. Only when the effect of absorption is fully disregarded, is the familiar local-field correction factor recovered.
Studied within the framework of both classical and quantum-mechanical approaches is the resonance interaction between two atomic dipoles one of which is located inside a dielectric microsphere and the other near its outer surface. The dispersion equation of this system is found. The analysis of this equation in a quasistatic approximation has shown that the behavior of the eigenfrequencies depends in a complex manner on the parameters of the system, and that exact resonance can be achieved, provided the parameters are suitably selected. Based on the solutions of the above equation, relationships are found between the energy-transfer rate and the system parameters. It is demonstrated that as the inside atom approaches the surface of the microsphere, resonance excitation transfer from one atom to the other can take place. Similar results are obtained when using the quantum-mechanical density matrix to define the atomic interaction. The results obtained can be of use in implementing selective microscopy with a nanometer-high spatial resolution.