We study the relaxation of a quantum system towards the thermal equilibrium using tools developed within the context of quantum information theory. We consider a model in which the system is a qubit, and reaches equilibrium after several successive two-qubit interactions (thermalizing machines) with qubits of a reservoir. We characterize completely the family of thermalizing machines. The model shows a tight link between dissipation, fluctuations, and the maximal entanglement that can be generated by the machines. The interplay of quantum and classical information processes that give rise to practical irreversibility is discussed.
We study the relaxation of a quantum system towards the thermal equilibrium using tools developed within the context of quantum information theory. We consider a model in which the system is a qubit, and reaches equilibrium after several successive two-qubit interactions (thermalizing machines) with qubits of a reservoir. We characterize completely the family of thermalizing machines. The model shows a tight link between dissipation, fluctuations, and the maximal entanglement that can be generated by the machines. The interplay of quantum and classical information processes that give rise to practical irreversibility is discussed.
Classical engines turn thermal resources into work, which is maximized for reversible operations. The quantum realm has expanded the range of useful operations beyond energy conversion, and incoherent resources beyond thermal reservoirs. This is the case of entanglement generation in a driven-dissipative protocol, which we hereby analyze as a continuous quantum machine. We show that for such machines the more irreversible the process, the larger the concurrence. Maximal concurrence and entropy production are reached for the hot reservoir being at negative effective temperature, beating the limits set by classic thermal operations on an equivalent system.
Two-level systems (TLS) are widely recognized as a dominant source of energy relaxation in superconducting qubits, limiting coherence times and device performance. While TLS-induced dissipation is often modeled as independent channels, interacting TLS can form finite many-body environments whose dynamical role in qubit relaxation remains insufficiently understood. Building on the information-erasure-based framework for irreversible thermalization developed in our previous work, we present a microscopic model and numerical simulations of a superconducting qubit coupled to a finite interacting many-body TLS environment as a concrete physical realization of this mechanism. We show that effective irreversible energy relaxation can emerge from intrinsic many-body dynamics without invoking external baths or phenomenological dissipation. The introduction of information erasure drives a transition from coherent oscillatory energy exchange to nonoscillatory exponential relaxation of the qubit. The relaxation times exhibit the scaling T1,T2∝Jq,τ−2 with respect to the qubit-TLS coupling strength, consistent with Fermi's golden rule and Lindblad-type descriptions. Importantly, both exponential decay and its scaling behavior arise directly from microscopic many-body dynamics. These results provide quantitative insight into TLS-induced decoherence mechanisms and establish a microscopic link between information erasure, many-body thermalization, and irreversible relaxation in superconducting quantum systems.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Abstract We devise an autonomous quantum thermal machine consisting of three pairwise-interacting qubits, two of which are locally coupled to thermal reservoirs. The machine operates autonomously, as it requires no time-coherent control, external driving or quantum bath engineering, and is instead propelled by a chemical potential bias. Under ideal conditions, we show that this out-of-equilibrium system can deterministically generate a maximally entangled steady-state between two of the qubits, or any desired pure two-qubit entangled state, emerging as a dark state of the system. We study the robustness of entanglement production with respect to several relevant parameters, obtaining nearly-maximally-entangled states well-away from the ideal regime of operation. Furthermore, we show that our machine architecture can be generalised to a configuration with 2n − 1 qubits, in which only a potential bias and two-body interactions are sufficient to generate genuine multipartite maximally entangled steady states in the form of a W state of n qubits.
The investigation of thermalization in isolated quantum many-body systems has a long history, dating back to the time of developing statistical mechanics. Most quantum many-body systems in nature are considered to thermalize, while some never achieve thermal equilibrium. The central problem is to clarify whether a given system thermalizes, which has been addressed previously, but not resolved. Here, we show that this problem is undecidable. The resulting undecidability even applies when the system is restricted to one-dimensional shift-invariant systems with nearest-neighbour interaction, and the initial state is a fixed product state. We construct a family of Hamiltonians encoding dynamics of a reversible universal Turing machine, where the fate of a relaxation process changes considerably depending on whether the Turing machine halts. Our result indicates that there is no general theorem, algorithm, or systematic procedure determining the presence or absence of thermalization in any given Hamiltonian.
We design a universal quantum homogenizer, which is a quantum machine that takes as an input a system qubit initially in the state ρ and a set of N reservoir qubits initially prepared in the same state ξ. In the homogenizer the system qubit sequentially interacts with the reservoir qubits via the partial swap transformation. The homogenizer realizes, in the limit sense, the transformation such that at the output each qubit is in an arbitratily small neighbourhood of the state ξ irrespective of the initial states of the system and the reservoir qubits. This means that the system qubit undergoes an evolution that has a fixed point, which is the reservoir state ξ. We also study approximate homogenization when the reservoir is composed of a finite set of identically prepared qubits. The homogenizer allows us to understand various aspects of the dynamics of open systems interacting with environments in non-equilibrium states. In particular, the reversibility vs or irreversibility of the dynamics of the open system is directly linked to specific (classical) information about the order in which the reservoir qubits interacted with the system qubit. This aspect of the homogenizer leads to a model of a quantum safe with a classical combination.We analyze in detail how entanglement between the reservoir and the system is created during the process of quantum homogenization. We show that the information about the initial state of the system qubit is stored in the entanglement between the homogenized qubits.