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arXiv:quant-ph/0009023

A puzzle in quantum dynamics

Chen, C. Y.

Published Sep 6, 2000• 1 citation
arXivHTMLPDF

Abstract

The textbook treatment in that the wave function of a dynamical system is expanded in an eigenfunction series is investigated. With help of an elementary example and some mathematical theorems, it is revealed that in terms of solving the time-dependent Schrödinger equation the treatment involves in divergence trouble . The root reason behind the trouble is finally analyzed.

DOI
10.48550/arxiv.quant-ph/0009023

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The textbook treatment in that the wave function of a dynamical system is expanded in an eigenfunction series is investigated. With help of an elementary example and some mathematical theorems, it is revealed that in terms of solving the time-dependent Schrödinger equation the treatment involves in divergence trouble . The root reason behind the trouble is finally analyzed.
Quantum tunneling is an important model in elementary quantum mechanics. However, since solution of its wave function involves transcendental equation, many elementary quantum mechanics textbooks often focus on the explanation of transmission coefficient, and rarely mention the evolution of wave function. Although this process is mentioned in some textbooks, it is often solved by graphic method, which is not conducive to beginners' understanding of the process. In this paper, a numerical calculation method for beginners is proposed to solve this problem. According to Dirac's vectorization idea, the state vectors and operators in the Schrodinger equation are discretized in the form of vectors and matrices, respectively, and the time-dependent evolution of wave function tunneling under several potential barriers is solved by Julia numerically.
Over the course of the past two to three decades, new tools of presentation and mathematical treatment have emerged and the subject matter of quantum mechanics has gone through significant changes. A Textbook on Modern Quantum Mechanics presents the selected elementary, intermediate, and advance topics with rejuvenated approach to the subject matter. Newly merged topics from contemporary physics and chemistry are included in the text as well as solved examples. The book covers: (i) fundamental discoveries that are the foundation of modern quantum mechanics; (ii) solution of Schrödinger’s wave equation for 1D problems and their importance; (iii) matrix and vector formulation of quantum mechanics; (iv) transformations, symmetries, and conservation laws; (v) angular and spin momenta; (vi) solution of Schrödinger equation for central potentials; (vii) time-independent perturbation theory, variational method and WKB approximation; (viii) quantum theory of scattering; (xi) many-particle systems and their quantum mechanical treatments; (x) time-dependent perturbations and the interaction of fields with matter; (xi) relativistic quantum mechanics; and (xii) quantization of fields and the second quantization. Key Features: It provides everything a student needs to know for succeeding at all levels of the undergraduate and graduate studies. It covers most of the topics that are taught under (a) elementary, (b) intermediate, and (c) advance courses of quantum mechanics at universities and colleges. It has detailed and elegant mathematical treatment with contemporary style of interpretation and presentation in simple English. Solved examples and unsolved exercises that are part of each chapter to consolidate the readers' understanding of fundamental concepts. The subject matter of the book is well tested on the students taught by the author over a period of 30 years. This is a valuable textbook for students pursuing Bachelor of Science, Master of Science, and Doctor of Philosophy (PhD) degrees in the subjects of Physics, Chemistry, and materials science in India, South Asian countries, the United States, and Europe.
Some aspects of the interpretation of quantum theory are discussed.It is emphasized that quantum theory is formulated in a Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutator relations between 'canonically conjugated' coordinate and momentum operators leads to a wrong version of quantum mechanics.In this connection the Feynman integral formalism is also discussed.In this formalism the measure is not well-defined and there is no idea how to distinguish between the true version of quantum mechanics and an incorrect one; it is rather a mnemonic rule to generate perturbation series from an undefined zero order term.The origin of time is analyzed in detail by the example of atomic collisions.It is shown that the time-dependent Schrödinger equation for the closed three-body (two nuclei + electron) system has no physical meaning since in the high impact energy limit it transforms into an equation with two independent time-like variables; the time appears in the stationary Schrödinger equation as a result of extraction of a classical subsystem (two nuclei) from a closed three-body system.Following the Einstein-Rosen-Podolsky experiment and Bell's inequality the wave function is interpreted as an actual field of information in the elementary form.The relation between physics and mathematics is also discussed.