arXiv:physics/9909027 · Physical Review A

Slowing and cooling molecules and neutral atoms by time-varying electric-field gradients

Jason Maddi, Timothy P. Dinneen, Harvey Gould

Published Nov 1, 1999• 74 citations

Abstract

A method of slowing, accelerating, cooling, and bunching molecules and neutral atoms using time-varying electric-field gradients is demonstrated with cesium atoms in a fountain. The effects are measured and found to be in agreement with our calculations. Time-varying electric-field-gradient slowing and cooling is applicable to atoms that have large dipole polarizabilities, including atoms that are not amenable to laser slowing and cooling, to Rydberg atoms, and to molecules, especially polar molecules with large electric dipole moments. The possible applications of this method include slowing and cooling thermal beams of atoms and molecules, launching cold atoms from a trap into a fountain, and measuring atomic dipole polarizabilities.

DOI: 10.1103/physreva.60.3882

Related papers

Slowing molecules and neutral atoms by time-varying electric field gradients

Jason Maddi, T. Dinneen, Harvey Gould

Summary form only given. Isochronous electric field gradients have been used to deflect beams of molecules and neutral atoms. However, time-varying electric field gradients can be used to accelerate, slow, cool, or bunch these same beams. The method works best for polar molecules with large dipole moments and atoms with large polarizabilities.

Quantum Electronics and Laser Science ConferenceJan 1, 20000 citations

Decelerating Neutral Dipolar Molecules

Giel Berden, Hendrick L. Bethlem, Gerard Meijer

Slowing down atoms using laser cooling, together with techniques like magnetic trapping and evaporative cooling, has led to numerous exciting results over the last decade [1], with the realization of Bose-Einstein condensation as the most spectacular achievement [2]. Laser-cooling schemes are applicable to atoms since closed multilevel systems can be realized and many consecutive absorptionemission cycles can be induced. This leads to a significant momentum transfer from the photons of the laser to the atom, resulting in a change of the velocity of the atom. There currently is a great interest in producing cold molecules for the study of cold molecule-molecule collisions, molecular quantum collective effects, Doppler-free spectroscopy, frequency standards, as well as many other applications already realized for atoms [3]. Slowing down of neutral molecules, a prerequisite for being able to trap them, has proven to be considerably more difficult to be achieved, however. The above-mentioned laser-cooling scheme cannot be applied to slow down molecules as no simple closed-level systems can be found; the unavoidable off-resonant radiative decay of molecules from the excited state to other vibrational levels in the electronic ground state hampers efficient momentum transfer [4]. Once molecules are present at sufficiently low kinetic energies, below a fraction of a cm21, they can be trapped in various ways. Trapping of neutral molecules in inhomogeneous magnetic [3] and electric fields [5] and trapping based on the use of evanescent fields close to the dielectricvacuum interface have been proposed [6]. It has also been suggested that extremely high laser powers might be used to induce a dipole moment in polarizable molecules, leading to trapping of these molecules in the laser beam [7]. Other methods to produce slow molecules have been put forward and have recently been successfully applied to produce the first samples of trapped molecules. By injecting molecules in a cold buffer gas, sufficiently low kinetic energies of the injected molecules can be obtained after thermalization that they can subsequently be trapped in an inhomogeneous magnetic field. This has recently been demonstrated for CaH injected in 3He buffer gas at temperatures of around 0.3 K [8]. Associative collisions between ultracold trapped atoms [9] have proven to be

Jan 1, 1999134 citations

Production and application of translationally cold molecules

Hendrick L. Bethlem, Gerard Meijer

Inspired by the spectacular successes in the field of cold atoms, there is currently great interest in cold molecules. Cooling molecules is useful for various fundamental physics studies and gives access to an exotic regime in chemistry where the wave property of the molecules becomes important. Although cooling molecules has turned out to be considerably more difficult than cooling atoms, a number of methods to produce samples of cold molecules have been demonstrated over the last few years. This paper aims to review the application of cold molecules and the methods to produce them. Emphasis is put on the deceleration of polar molecules using time-varying electric fields. The operation principle of the array of electrodes that is used to decelerate polar molecules is described in analogy with, and using terminology from, charged-particle accelerators. It is shown that, by applying an appropriately timed high voltage burst, molecules can be decelerated while the phase-space density, i.e. the number of molecules per position-velocity interval, remains constant. In this way the high density and low temperature in the moving frame of a pulsed molecular beam can be transferred to the laboratory frame. Experiments on metastable CO in states that are either repelled by or attracted to high electric fields are presented. Loading of slow molecules into traps and storage rings is discussed.

International Reviews in Physical ChemistryJan 1, 2003229 citations

Slowing of supersonically cooled atoms and molecules by time-varying nonresonant induced dipole forces

Břetislav Friedrich

We describe a versatile method for slowing molecules (or atoms) which relies on high-field-seeking states created by the polarizability interaction with a nonresonant laser field. A pulsed supersonic beam expansion is employed to precool the molecules internally and to narrow their velocity spread. The molecules are scooped at right angles by a nonresonant laser beam steered by a scanner and decelerated on a circular path by gradually reducing the beam's angular speed.

Physical Review AJan 14, 200048 citations

Sympathetic Cooling and Slowing of Molecules with Rydberg Atoms

Chi Zhang, Seth T. Rittenhouse, Timur V. Tscherbul +2 more

We propose to sympathetically slow and cool polar molecules in a cold, low-density beam using laser-cooled Rydberg atoms. The elastic collision cross sections between molecules and Rydberg atoms are large enough to efficiently thermalize the molecules even in a low-density environment. Molecules traveling at 100 m/s can be stopped in under 30 collisions with little inelastic loss. Our method does not require photon scattering from the molecules and can be generically applied to complex species for applications in precision measurement, quantum information science, and controlled chemistry.

arXiv:2307.01418Physical Review LettersJan 19, 202410 citations

Deceleration and trapping of polar molecules using time-varying electric fields

Hendrick L. Bethlem

What we experience as an agreeable temperature is in fact due to a constant bombardment of our skin by very fast molecules. At room temperature the average velocity of air molecules around us is about 500 m/s, corresponding to about 2000 km/hour. Only at very low temperatures, close to the absolute zero (0 K = -273.15 C), will the molecules come to rest. The high velocities at ordinary temperatures limit our ability to study the molecules. This thesis describes a method to slow down a beam of polar molecules using time-varying electric fields. When the molecules are decelerated to low velocities they will have insufficient kinetic energy to escape from the electric fields, and they will be trapped. In this way molecules can be stored and studied over long periods of time. This thesis is organized as follows: In chapter I the motivation for studying cold molecules is made more explicit, and an overview is given of other methods to cool molecules. In Chapter II the interaction between molecules and electric fields is outlined. In Chapter III and IV deceleration of a beam of metastable CO is presented, using molecules in states which are either repelled by, or attracted to high electric fields. Finally, in Chapter V ammonia molecules are brought to a standstill and subsequently held in an electrostatic trap

APSJan 1, 20023 citations