Alkaline-earth-metal atoms in their lowest
(nsnp) 3P2 state are exceptionally long lived and can be trapped magnetically. The nonspherical atomic structure leads to anisotropic long-range interactions between two metastable alkaline-earth-metal atoms. The anisotropy affects the rotational motion of the diatomic system and couples states of different rotational quantum numbers. This paper develops a tensorial decomposition of the most important long-range interaction operators, and a systematic inclusion of molecular rotations, in the presence of an external magnetic field. This analysis illuminates the nature of the coupling between the various degrees of freedom. The consequences are illustrated by application to a system of practical interest: metastable
88Sr. Using atomic parameters determined in a nearly ab initio calculation, we compute adiabatic potential-energy curves. The anisotropic interatomic interaction, in combination with the applied magnetic field, is demonstrated to induce the formation of a long-range molecular potential well. This curve correlates to two fully polarized, low-field seeking atoms in a rotational s-wave state. The coupling among molecular rotational states controls the existence of the potential well, and its properties vary as a function of magnetic-field strength, thus allowing the scattering length in this state to be tuned. The scattering length of metastable
88Sr displays a resonance at a field of 339 G.
Ultracold collisions between metastable bosonic
88Sr [
(5s5p)3P2] and fermionic
87Sr [
(5s5p)3P2 (i=9/2)] atoms are investigated based on an approach of tensorial analysis. The scattering physics of two atoms in fully polarized
s-wave entrance channels is studied in detail. In the Born-Oppenheimer approximation, the strong anisotropic interatomic interaction is demonstrated to induce formations of long-range molecular potential wells. However, besides significantly modifying the elastic scattering, the anisotropic interatomic interaction leads to the strong multichannel coupling between different partial waves, which triggers a high rate of inelastic losses. By applying an external static magnetic field
B0=B0ez, the inelastic scattering can be suppressed while the elastic scattering is significantly enhanced. Additionally, the energy-dependent complex
s-wave scattering lengths at a given relative collision energy strongly depend on the strength of magnetic field. We, moreover, self-consistently investigate ultracold collisions of two atoms at low temperatures in an optical lattice site. In the $\ensuremath{\delta}$-function pseudopotential approximation, we derive the effective
s-wave scattering lengths, energy eigenvalues, elastic and inelastic scattering rates, and their dependence on the external magnetic field. We find that (i) the effective scattering lengths of ultracold atoms in entrance channels of interest display resonance behavior at certain values of magnetic field and (ii) the extra Zeeman interaction not only leads to the suppression of inelastic scattering but also enlarges the elastic scattering rates.
Metastability and long-range interactions of Mg, Ca, and Sr in the lowest-energy metastable
3P2 state are investigated. The calculated lifetimes are 38 min for
Mg∗, 118 min for
Ca∗, and 17 min for
Sr∗, supporting feasibility of cooling and trapping experiments. The quadrupole-quadrupole long-range interactions of two metastable atoms are evaluated for various molecular symmetries. Hund's case (c)
4g potential possesses a large 100--1000 K potential barrier. Therefore magnetic trap losses can possibly be reduced using cold metastable atoms in a stretched
M=2 state. Calculations were performed in the framework of ab initio relativistic configuration interaction method coupled with the random-phase approximation.
We explore the scattering properties of ultracold ground-state Cs atoms at magnetic fields between 450 G (45 mT) and 1000 G. We identify 17 previously unreported Feshbach resonances, including two very broad ones near 549 and 787 G. We measure the binding energies of several different dimer states by magnetic field modulation spectroscopy. We use least-squares fitting to these experimental results, together with previous measurements at lower field, to determine a six-parameter model of the long-range interaction potential, designated M2012. Coupled-channels calculations using M2012 provide an accurate mapping between the
s-wave scattering length and the magnetic field over the entire range of fields considered. This mapping is crucial for experiments that rely on precise tuning of the scattering length, such as those on Efimov physics.
This thesis has investigated the dynamics of ultracold atomic collisions in the presence of both static magnetic and oscillating radio-frequency (rf) fields. The bound state structure and scattering length of 39K+133Cs was examined in the presence of only a static magnetic field, where it was found that no Feshbach resonance of suitable width for magnetoassociation existed at a magnetic field where caesium can be cooled to degeneracy. We then showed that zero-energy Feshbach resonances may be engineered using an rf field in places where they did not previously exist. An rf field with frequency 79.9 MHz was chosen to induce a resonance near 21 G. The widths of such rf-induced Feshbach resonances increase quadratically with rf field strength. The resonances presented are lossless with circularly polarized rf, and the molecules created are long-lived even with plane-polarized RF. Collisional losses in rf-dressed magnetic traps were also investigated. An rf-induced loss mechanism that does not exist in the absence of rf radiation was identified. This mechanism is not suppressed by a centrifugal barrier in the outgoing channel, and can be much faster than spin relaxation, which is centrifugally suppressed. We explore the dependence of the rf-induced loss rate on singlet and triplet scattering lengths, hyperfine splittings and the strength of the rf field. The results were interpreted in terms of an adiabatic model of the collision dynamics, and calculate the corresponding nonadiabatic couplings. The loss rate can vary by 10 orders of magnitude as a function of singlet and triplet scattering lengths. 87Rb is a special case, where several factors combine to reduce rf-induced losses; as a result, they are slow compared to spin-relaxation losses. For most other alkali-metal pairs, rf-induced losses are expected to be much faster and may dominate. For heteronuclear mixtures an rf-modified spin-exchange mechanism was identified that results in loss rates orders of magnitude greater than the rf-induced loss rates in homonuclear cases. Fast loss is expected in mixtures where the Lande g-factors differ.
Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic
4He∗+4He∗ and fermionic
3He∗+3He∗ systems, and heteronuclear collisions of the mixed
3He∗+4He∗ system, are investigated over the temperature range 1 $\ensuremath{\mu}\mathrm{K}$ to 1 K. Carefully constructed Born-Oppenheimer molecular potentials are used to describe the electrostatic interaction between the colliding atoms, and complex optical potentials to represent loss through ionization from the ${}^{1,3}\mathrm{\ensuremath{\Sigma}}$ states. Magnetic spin-dipole-mediated transitions from the ${}^{5}\mathrm{\ensuremath{\Sigma}}$ state are included and results reported for spin-polarized and unpolarized systems. Comparisons are made with experimental results, previous semiclassical models, and a perturbed single-channel model.