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arXiv:physics/0111098 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Discrete four-stroke quantum heat engine exploring the origin of friction

Ronnie Kosloff, Tova Feldmann

Published May 16, 2002• 145 citations
arXivHTMLPDF

Abstract

The optimal power performance of a first-principle quantum heat engine model shows friction-like phenomena when the internal fluid Hamiltonian does not commute with the external control field. The model is based on interacting two-level systems where the external magnetic field serves as a control variable.
DOI
10.1103/physreve.65.055102

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The fundamentals of a quantum heat engine are derived from first principles. The study is based on the equation of motion of a minimum set of operators, which is then used to define the state of the system. The relation between the quantum framework and the thermodynamical observables is examined. A four-stroke heat engine model with a coupled two-level system as a working fluid is used to explore the fundamental relations. In the model used, the internal Hamiltonian does not commute with the external control field, which defines the two adiabatic branches. Heat is transferred to the working fluid by coupling to hot and cold reservoirs under constant field values. Explicit quantum equations of motion for the relevant observables are derived on all branches. The dynamics on the heat transfer constant field branches is solved in closed form. On the adiabats, a general numerical solution is used and compared with a particular analytic solution. These solutions are combined to construct the cycle of operation. The engine is then analyzed in terms of the frequency-entropy and entropy-temperature graphs. The irreversible nature of the engine is the result of finite heat transfer rates and frictionlike behavior due to noncommutability of the internal and external Hamiltonians.
The unavoidable irreversible loss of power in a heat engine is found to be of quantum origin. Following thermodynamic tradition, a model quantum heat engine operating in an Otto cycle is analysed, where the working medium is composed of an ensemble of harmonic oscillators and changes in volume correspond to changes in the curvature of the potential well. Equations of motion for quantum observables are derived for the complete cycle of operation. These observables are sufficient to determine the state of the system and with it all thermodynamical variables. Once the external controls are set, the engine settles to a limit cycle. Conditions for optimal work, power and entropy production are derived. At high temperatures and quasistatic operating conditions, the efficiency at maximum power coincides with the endoreversible result . The optimal compression ratio varies from in the quasistatic limit where the irreversibility is dominated by heat conductance to in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions, the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.
An irreversible cycle model of a quantum heat engine with internal friction is established, which is composed of two adiabatic and two isomagnetic field processes. The working substance of the cycle consists of an ensemble of many non-interacting spin-1/2 systems. Based on a quantum master equation and semi-group approach, the general performance characteristics of the heat engine are investigated. The general expressions for several important parameters, such as the efficiency, power output, and rate of the entropy production, are derived. The performance of the cycle is optimized with respect to the temperatures of the working substance. By numerical solutions, the maximum power output and the corresponding parameters are calculated. The optimal regions of efficiency, temperatures of the working substance, and cycle period are determined. Moreover, the performance of the heat engine in the frictionless case is obtained, which is different from that in the friction case. Finally, the results obtained are generalized to the performance optimization of the heat engine working with spin-J systems.
The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square root of the temperature ratio in the quasistatic limit where their reversibility is dominated by heat conductance to the temperature ratio to the power of 1/4 in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.
After starting a reciprocating heat engine it eventually settles to a stable mode of operation. A first principle quantum heat engine also approaches this stable limit cycle. The studied engine is based on a working medium consisting of an ensemble of quantum systems composed of two coupled spins. A four-stroke cycle of operation is studied, with two isochore branches where heat is transferred from the hot/cold baths and two adiabats where work is exchanged. The dynamics is generated by a completely positive map. It has been shown that the performance of this model resembles an engine with intrinsic friction. The quantum conditional entropy is employed to prove the monotonic approach to a limit cycle. Other convex measures such as the quantum distance display the same monotonic approach. The equations of motion of the engine are solved for the different branches and are combined to a global propagator that relates the state of the engine in the beginning of the cycle to the state after one period of operation of the cycle. The eigenvalues of the propagator define the rate of relaxation toward the limit cycle. A longitudinal and transverse mode of approach to the limit cycle is thus identified. The entropy balance is used to explore the necessary conditions which lead to a stable limit cycle. The phenomena of friction can be identified with a zero change in the von Neumann entropy of the working medium.
Incorporating time into thermodynamics allows for addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model in order to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction, and thermalization in the presence of external driving. We construct various finite-time engine cycles that are based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.