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arXiv:math-ph/0510047 · Journal of Physics A Mathematical and General

New classes of potentials for which the radial Schrödinger equation can be solved at zero energy

Khosrow Chadan, Reido Kobayashi

Published Mar 15, 2006• 3 citations
arXivHTMLPDF

Abstract

Given two spherically symmetric and short range potentials $V_0$ and V_1 for which the radial Schrodinger equation can be solved explicitely at zero energy, we show how to construct a new potential $V$ for which the radial equation can again be solved explicitely at zero energy. The new potential and its corresponding wave function are given explicitely in terms of V_0 and V_1, and their corresponding wave functions ϕ_0 and ϕ_1. V_0 must be such that it sustains no bound states (either repulsive, or attractive but weak). However, V_1 can sustain any (finite) number of bound states. The new potential V has the same number of bound states, by construction, but the corresponding (negative) energies are, of course, different. Once this is achieved, one can start then from V_0 and V, and construct a new potential \bar{V} for which the radial equation is again solvable explicitely. And the process can be repeated indefinitely. We exhibit first the construction, and the proof of its validity, for regular short range potentials, i.e. those for which rV_0(r) and rV_1(r) are L^1 at the origin. It is then seen that the construction extends automatically to potentials which are singular at r= 0. It can also be extended to V_0 long range (Coulomb, etc.). We give finally several explicit examples.

DOI
10.1088/0305-4470/39/13/016

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Given two spherically symmetric and short range potentials V0V_0V0​ and V_1 for which the radial Schrodinger equation can be solved explicitely at zero energy, we show how to construct a new potential VVV for which the radial equation can again be solved explicitely at zero energy. The new potential and its corresponding wave function are given explicitely in terms of V_0 and V_1, and their corresponding wave functions ϕ_0 and ϕ_1. V_0 must be such that it sustains no bound states (either repulsive, or attractive but weak). However, V_1 can sustain any (finite) number of bound states. The new potential V has the same number of bound states, by construction, but the corresponding (negative) energies are, of course, different. Once this is achieved, one can start then from V_0 and V, and construct a new potential \bar{V} for which the radial equation is again solvable explicitely. And the process can be repeated indefinitely. We exhibit first the construction, and the proof of its validity, for regular short range potentials, i.e. those for which rV_0(r) and rV_1(r) are L^1 at the origin. It is then seen that the construction extends automatically to potentials which are singular at r= 0. It can also be extended to V_0 long range (Coulomb, etc.). We give finally several explicit examples.
We consider the quantum-mechanical problem of a particle bound to a configuration of spherical potentials, each of finite range. If the Schr\"odinger equation can be solved for each potential by itself, then it is shown how to solve it for the configuration, provided the potentials do not overlap. The energy levels are the zeros of a determinant of formally infinite order, but in practice this is always well approximated by a finite determinant and often by one of small order. As illustrative examples we consider some states of a particle bound to three square wells with the configuration of an equilateral triangle, and to two truncated Coulomb potentials. The possibility of extending an approximate version of the method to overlapping potentials is pointed out.
Demonstrating the completeness of wave function solutions of the radial Schrödinger equation is a very difficult task. Existing proofs, relying on operator theory, are often very abstract and far from intuitive comprehension. However, it is possible to obtain rigorous proofs amenable to physical insight, if one restricts the considered class of Schrödinger potentials. One can mention, in particular, unbounded potentials yielding a purely discrete spectrum and short-range potentials. However, those possessing a Coulomb tail, very important for physical applications, have remained problematic due to their long-range character. The method proposed in this paper allows to treat them correctly, provided that the non-Coulomb part of potentials vanishes after a finite radius. Nonlocality of potentials can also be handled. The main idea in the proposed demonstration is that regular solutions behave like sine/cosine functions for large momenta, so that their expansions verify Fourier transform properties. The highly singular point at k=0 of long-range potentials is dealt with properly using analytical properties of Coulomb wave functions. Lebesgue measure theory is avoided, rendering the demonstration clear from a physical point of view.
Demonstrating the completeness of wave functions solutions of the radial Schrodinger equation is a very difficult task. Existing proofs, relying on operator theory, are often very abstract and far from intuitive comprehension. However, it is possible to obtain rigorous proofs amenable to physical insight, if one restricts the considered class of Schrodinger potentials. One can mention in particular unbounded potentials yielding a purely discrete spectrum and short-range potentials. However, those possessing a Coulomb tail, very important for physical applications, have remained problematic due to their long-range character. The method proposed in this paper allows to treat them correctly, provided the non-Coulomb part of potentials vanishes after a finite radius. Non-locality of potentials can also be handled. The main idea in the proposed demonstration is that regular solutions behave like sine/cosine functions for large momenta, so that their expansions verify Fourier transform properties. The highly singular point at k = 0 of long-range potentials is dealt with properly using analytical properties of Coulomb wave functions. Lebesgue measure theory is avoided, rendering the demonstration clear from a physical point of view.
By using a simple procedure the general solution of the time-independent radial Schrodinger Equation for spherical symmetric potentials was made without making any approximation. The wave functions are always periodic. It appears two diffucilties: one of them is the solution of the equation E= U(r), where E and U(r) are the total an effective potential energies, respectively, and the other is the calculation of the integral of the square root of U(r). If analytical calculations are not possible, one must apply numerical methods. To find the energy wave function of the ground state, there is no need for the calculation of this integral, it is sufficient to find the classical turning points, that is to solve the equation E=U(r).
Abstract In this chapter we consider the time-independent Schrödinger equation for three spatial dimensions. Making use of the orbital angular momentum observables, including the Laplacian in spherical polar coordinates, and introducing an effective potential, we recast the three-dimensional Schrödinger as a one-dimensional differential equation for the reduced radial wave function. In this context we discuss conditions for the existence of bound states and an upper bound on the ground-state energy obtained from the Rayleigh-Ritz variational principle. As an example we then consider the bound-state solutions for the spherical potential well and discuss the conditions for it admitting a ground state. We then turn to the Coulomb potential representing the hydrogen atom and discuss methods for obtaining upper and lower bounds on the ground-state energy to explain the stability of matter. Finally, obtain the Laguerre-polynomial solutions of the radial Schrödinger equation for the hydrogen atom, determine their energies and discuss their properties
The analytic solution of the radial Schrodinger equation is studied by using the tight coupling condition of several positive-power and inverse-power potential functions in this article. Furthermore, the precisely analytic solutions and the conditions that decide the existence of analytic solution have been searched when the potential of the radial Schrodinger equation is V (r) = �1r 8 + �2r 3 + �3r 2 + �3r 1 + �2r 3 + �1r 4 . Generally speaking, there is only an approximate solution, but not analytic solution for Schrodinger equation with several potentials' superposition. However, the conditions that decide the existence of analytic solution have been found and the analytic solution and its energy level structure are obtained for the Schrodinger equation with the potential which is motioned above in this paper. According to the single-value, finite and continuous standard of wave function in a quantum system, the authors firstly solve the asymptotic solution through the radial coordinate r ! 1 and r ! 0; secondly, they make the asymptotic solutions combining with the series solutions nearby the neighborhood of irregular singularities; and then they compare the power series coefficients, deduce a series of analytic solutions ofthe stationary state wave function and corresponding energy level structure by tight coupling among the coefficients of potential functions for the radial Schrodinger equation; and lastly, they discuss the solutions and make conclusions.