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arXiv:cond-mat/9810406 · Physical Review Letters

Topological Origin of the Phase Transition in a Mean-Field Model

Lapo Casetti, E. G. D. Cohen, Marco Pettini

Published May 24, 1999• 43 citations
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Abstract

We argue that the phase transition in the mean-field $\mathrm{XY}$ model is related to a particular change in the topology of its configuration space. The nature of this topological change can be discussed on the basis of elementary Morse theory using the potential energy per particle $V$ as a Morse function. The value of $V$ where such a topological change occurs equals the thermodynamic value of $V$ at the phase transition and the number of (Morse) critical points grows very fast with the number of particles $N$. Furthermore, as in statistical mechanics, the way the thermodynamic limit is taken is crucial in topology.

DOI
10.1103/physrevlett.82.4160

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We argue that the phase transition in the mean-field XY\mathrm{XY}XY model is related to a particular change in the topology of its configuration space. The nature of this topological change can be discussed on the basis of elementary Morse theory using the potential energy per particle VVV as a Morse function. The value of VVV where such a topological change occurs equals the thermodynamic value of VVV at the phase transition and the number of (Morse) critical points grows very fast with the number of particles NNN. Furthermore, as in statistical mechanics, the way the thermodynamic limit is taken is crucial in topology.
Abstract We propose a topological approach suitable to establish a connection between thermodynamics and topology in the microcanonical ensemble. Indeed, we report on results that point to the possibility of describing interacting classical spin systems in the thermodynamic limit, including the occurrence of a phase transition, using topological arguments only. Our approach relies on Morse theory, through the determination of the critical points of the potential energy, which is the proper Morse function. Our main finding is that, in the context of the classical models studied, the Euler characteristic χ ( E ) embeds the necessary features for a correct description of several magnetic thermodynamic quantities of the systems, such as the magnetization, correlation function, susceptibility, and critical temperature. Despite the classical nature of the models, such quantities are those that do not violate the laws of thermodynamics (with the proviso that van der Waals loop states are mean field (MF) artifacts). We also discuss the subtle connection between our approach using the Euler entropy, defined by the logarithm of the modulus of χ ( E ) per site, and that using the Boltzmann microcanonical entropy. Moreover, the results suggest that the loss of regularity in the Morse function is associated with the occurrence of unstable and metastable thermodynamic solutions in the MF case. The reliability of our approach is tested in two exactly soluble systems: the infinite-range and the one-dimensional short-range XY models in the presence of a magnetic field. In particular, we confirm that the topological hypothesis holds for both the infinite-range ( T c ≠ 0 ) and the short-range ( T c = 0) XY models. Further studies are very desirable in order to clarify the extension of the validity of our proposal.
The thermodynamics and topology of mean-field models with 2+k body interaction terms (generalizing XY model) are derived. Focusing on two particular cases (2+4 and 2+6 body interaction terms), a comparison between thermodynamic (phase transition energy, thermodynamically forbidden energy regions) and topological (singularity and curvature of saddle entropy) properties is performed. We find that (i) a topological change is present at the phase transition energy; however, (ii) only one topological change occurs, also for those models exhibiting two phase transitions; (iii) the order of a phase transition is not completely signaled by the curvature of topological quantities.
We use a topological approach to describe the frustration- and field-induced phase transitions exhibited by the infinite-range XY model on the AB2 chain, including noncollinear spin structures. For this purpose, we have computed the Morse number and the Euler characteristic, as well as other topological invariants, which are found to behave similarly as a function of the energy level in the context of Morse theory. In particular, we use a method based on an analogy with statistical mechanics to compute the Euler characteristic, which proves to be quite feasible. We also introduce topological energies which help us to clarify several properties of the transitions, both at zero and finite temperatures. In addition, we establish a nontrivial direct connection between the thermodynamics of the systems, which have been solved exactly under the saddle-point approach, and the topology of their configuration space. This connection allows us to identify the nondegeneracy condition under which the divergence of the density of Jacobian's critical points [jl(E)] at the critical energy of a topology-induced phase transition, proposed by Kastner and Schnetz [Phys. Rev. Lett. 100, 160601 (2008)] as a necessary criterion, is suppressed. Finally, our findings and those available in the literature suggest that the cusplike singularity exhibited both by the Euler characteristic and the topological contribution for the entropy at the critical energy, put together with the divergence of jl(E) , and emerge as necessary and sufficient conditions for the occurrence of the finite-temperature topology-induced phase transitions examined in this work. The general character of this proposal should be subject to a more rigorous scrutiny.
Many-body systems when continuous phase transition occurs are mainly built in the interrelationship between particles, implemented through many-body correlations. Some of them may exhibit so-called topological order hardly measured by experiments. Therefore we need, beyond mean-field theory, the complex-systems approach that stresses the systemic complexity of many-body network at criticality. According to our previous study, network space experiences the homogeneous-heterogeneous transition invisible in traditional phase transitions. The network robustness can be a useful indicator to capture the critical phenomena of phase transitions with/without symmetry breaking. In this work, we demonstrate the idea of the change of robust networks is successfully applied to the well-known 1D quantum and 2D classical XY models.
We employ a topological approach to investigate the nature of quasistationary states of the mean-field XY Hamiltonian model. We focus on the quasistationary states reached when the system is initially prepared in a fully magnetized configuration. By means of numerical simulations and analytical considerations, we show that, along the quasistationary trajectories, the system evolves in a manifold of critical points of the potential energy function. Although these critical points are maxima, the large number of directions with marginal stability may be responsible for the slow relaxation dynamics and the trapping of the system in such trajectories.
Superfluids and superconductors can be either fully gapped or gapless with nodal structures in momentum space. Both the gapped and nodal phases can be topologically protected and possess nontrivial topological invariants. Topological quantum phase transitions exist at zero temperature between different gapped phases or between gapped and nodal phases. These phase transitions can be driven by chemical potential and/or spin exchange fields. The two phases separated by the phase transition can have the same local order but differ in global topology. Thus, these topological quantum phase transitions cannot be described by the Landau paradigm of symmetry breaking. Although some aspects of these transitions, such as the change of topological invariants and gapless boundary states, have been discussed before, a complete theory of these transitions has yet to be developed. In this dissertation, we construct effective field theories to study the universality and thermodynamic signatures of these transitions. We find four different universality classes in superfluids and superconductors. Certain thermodynamic quantities, such as compressibility or spin susceptibility, change non-analytically across the transitions. For certain time-reversal symmetry breaking fields that lead to bulk phase transitions, there also exist topological phase transitions on the surface. All the topological phase transitions studied in this dissertation only exist at zero temperature. At finite temperature, different states are connected by smooth crossovers. There exists a quantum critical region at finite temperature near the quantum critical point (QCP). In this quantum critical region, thermodynamic quantities have universal scaling dependence on temperature dictated by the universality class of the QCP. We argue that these scaling properties can be used to probe and differentiate these QCPs. These bulk and surface topological quantum phase transitions are discussed in various concrete models, such as chiral and time-reversal invariant p-wave superfluids, topological superconductors of emergent Dirac fermions, and topological superconducting model of CuₓBi₂Se₃.