We use a topological approach to describe the frustration- and field-induced phase transitions exhibited by the infinite-range XY model on the AB2 chain, including noncollinear spin structures. For this purpose, we have computed the Morse number and the Euler characteristic, as well as other topological invariants, which are found to behave similarly as a function of the energy level in the context of Morse theory. In particular, we use a method based on an analogy with statistical mechanics to compute the Euler characteristic, which proves to be quite feasible. We also introduce topological energies which help us to clarify several properties of the transitions, both at zero and finite temperatures. In addition, we establish a nontrivial direct connection between the thermodynamics of the systems, which have been solved exactly under the saddle-point approach, and the topology of their configuration space. This connection allows us to identify the nondegeneracy condition under which the divergence of the density of Jacobian's critical points [jl(E)] at the critical energy of a topology-induced phase transition, proposed by Kastner and Schnetz [Phys. Rev. Lett. 100, 160601 (2008)] as a necessary criterion, is suppressed. Finally, our findings and those available in the literature suggest that the cusplike singularity exhibited both by the Euler characteristic and the topological contribution for the entropy at the critical energy, put together with the divergence of jl(E) , and emerge as necessary and sufficient conditions for the occurrence of the finite-temperature topology-induced phase transitions examined in this work. The general character of this proposal should be subject to a more rigorous scrutiny.
We use a topological approach to describe the frustration- and field-induced phase transitions exhibited by the infinite-range XY model on the AB2 chain, including noncollinear spin structures. For this purpose, we have computed the Morse number and the Euler characteristic, as well as other topological invariants, which are found to behave similarly as a function of the energy level in the context of Morse theory. In particular, we use a method based on an analogy with statistical mechanics to compute the Euler characteristic, which proves to be quite feasible. We also introduce topological energies which help us to clarify several properties of the transitions, both at zero and finite temperatures. In addition, we establish a nontrivial direct connection between the thermodynamics of the systems, which have been solved exactly under the saddle-point approach, and the topology of their configuration space. This connection allows us to identify the nondegeneracy condition under which the divergence of the density of Jacobian's critical points [jl(E)] at the critical energy of a topology-induced phase transition, proposed by Kastner and Schnetz [Phys. Rev. Lett. 100, 160601 (2008)] as a necessary criterion, is suppressed. Finally, our findings and those available in the literature suggest that the cusplike singularity exhibited both by the Euler characteristic and the topological contribution for the entropy at the critical energy, put together with the divergence of jl(E) , and emerge as necessary and sufficient conditions for the occurrence of the finite-temperature topology-induced phase transitions examined in this work. The general character of this proposal should be subject to a more rigorous scrutiny.
Abstract We propose a topological approach suitable to establish a connection between thermodynamics and topology in the microcanonical ensemble. Indeed, we report on results that point to the possibility of describing interacting classical spin systems in the thermodynamic limit, including the occurrence of a phase transition, using topological arguments only. Our approach relies on Morse theory, through the determination of the critical points of the potential energy, which is the proper Morse function. Our main finding is that, in the context of the classical models studied, the Euler characteristic χ ( E ) embeds the necessary features for a correct description of several magnetic thermodynamic quantities of the systems, such as the magnetization, correlation function, susceptibility, and critical temperature. Despite the classical nature of the models, such quantities are those that do not violate the laws of thermodynamics (with the proviso that van der Waals loop states are mean field (MF) artifacts). We also discuss the subtle connection between our approach using the Euler entropy, defined by the logarithm of the modulus of χ ( E ) per site, and that using the Boltzmann microcanonical entropy. Moreover, the results suggest that the loss of regularity in the Morse function is associated with the occurrence of unstable and metastable thermodynamic solutions in the MF case. The reliability of our approach is tested in two exactly soluble systems: the infinite-range and the one-dimensional short-range XY models in the presence of a magnetic field. In particular, we confirm that the topological hypothesis holds for both the infinite-range ( T c ≠ 0 ) and the short-range ( T c = 0) XY models. Further studies are very desirable in order to clarify the extension of the validity of our proposal.
We argue that the phase transition in the mean-field XY model is related to a particular change in the topology of its configuration space. The nature of this topological change can be discussed on the basis of elementary Morse theory using the potential energy per particle V as a Morse function. The value of V where such a topological change occurs equals the thermodynamic value of V at the phase transition and the number of (Morse) critical points grows very fast with the number of particles N. Furthermore, as in statistical mechanics, the way the thermodynamic limit is taken is crucial in topology.
Frustration in many-body spin systems is a situation where the spins cannot orient themselves to fully minimize the interactions with their neighbors. It is caused, in general, by competing interactions or by the lattice structure, as in the antiferromagnets on non-bipartite lattices. Over the years frustrated systems have been studied substantially, since frustration can destabilize the antiferromagnetic order, lead to different phases of matter and induce various exotic properties. Frustration can be caused also by a choice of boundary conditions, i.e. the lattice topology. For instance, a ring with an odd number of sites is non-bipartite, which makes antiferromagnets in this setting frustrated. The subject of this thesis are zero-temperature one-dimensional quantum systems exactly in this setting. The major content is discussing how such a simple setting can influence the antiferromagnetic order, by studying spin-1/2 chains with discrete symmetries, whose breaking is related to the onset of the order. After reviewing the known results on topological frustration, dealing with non-thermodynamic quantities, we develop an approach for studying symmetry breaking, that is both suitable for exact analytical computations and meaningful for discussing the order also in a finite system. It consists of the realization that many spin-1/2 chains without external magnetic fields, such as the quantum XY chain, possess anticommuting global symmetries when the number of lattice sites is an odd number, implying the ground-state degeneracy already in a finite system. In this framework, we discover that topological frustration, despite being induced only by the choice of boundary conditions and even/odd system size choice, can affect the magnetization in the thermodynamic limit and system's quantum phase transitions. We find that topological frustration can destroy local order, create a site-dependent magnetization that varies in space with an incommensurate pattern, induce a first-order quantum phase transition that is not present without frustration and modify the nature of a second-order transition, by destroying local order at both sides of the transition and preserving only non-local string order parameters. All these results indicate the incompleteness of the approach to quantum many-body systems, based on the Ginzburg-Landau theory, that tries to capture the properties of the system by taking the system size to infinity before computing the observables and neglects the influence of the chain length as a relevant scale. We find that topological frustration can affect also non-equilibrium properties, by considering a local quantum quench setup. Namely, we study the Loschmidt echo and find it displays qualitatively and quantitatively different behavior for antiferromagnetic rings with an even and odd number of sites. Most of all, the differences become clearer for large system sizes, thus allowing to distinguish in a simple out-of-equilibrium experiment a system made by a certain, large, number of spins from the one with a single additional spin. The thesis also contains a mathematical part. In studying order parameters of models mappable to free fermions, Toeplitz determinants with symbols that possess a part proportional to the delta function arise. We derive asymptotic formulas for this type of determinants.
Superfluids and superconductors can be either fully gapped or gapless with nodal structures in momentum space. Both the gapped and nodal phases can be topologically protected and possess nontrivial topological invariants. Topological quantum phase transitions exist at zero temperature between different gapped phases or between gapped and nodal phases. These phase transitions can be driven by chemical potential and/or spin exchange fields. The two phases separated by the phase transition can have the same local order but differ in global topology. Thus, these topological quantum phase transitions cannot be described by the Landau paradigm of symmetry breaking. Although some aspects of these transitions, such as the change of topological invariants and gapless boundary states, have been discussed before, a complete theory of these transitions has yet to be developed. In this dissertation, we construct effective field theories to study the universality and thermodynamic signatures of these transitions. We find four different universality classes in superfluids and superconductors. Certain thermodynamic quantities, such as compressibility or spin susceptibility, change non-analytically across the transitions. For certain time-reversal symmetry breaking fields that lead to bulk phase transitions, there also exist topological phase transitions on the surface. All the topological phase transitions studied in this dissertation only exist at zero temperature. At finite temperature, different states are connected by smooth crossovers. There exists a quantum critical region at finite temperature near the quantum critical point (QCP). In this quantum critical region, thermodynamic quantities have universal scaling dependence on temperature dictated by the universality class of the QCP. We argue that these scaling properties can be used to probe and differentiate these QCPs. These bulk and surface topological quantum phase transitions are discussed in various concrete models, such as chiral and time-reversal invariant p-wave superfluids, topological superconductors of emergent Dirac fermions, and topological superconducting model of CuₓBi₂Se₃.
The thermodynamics and topology of mean-field models with 2+k body interaction terms (generalizing XY model) are derived. Focusing on two particular cases (2+4 and 2+6 body interaction terms), a comparison between thermodynamic (phase transition energy, thermodynamically forbidden energy regions) and topological (singularity and curvature of saddle entropy) properties is performed. We find that (i) a topological change is present at the phase transition energy; however, (ii) only one topological change occurs, also for those models exhibiting two phase transitions; (iii) the order of a phase transition is not completely signaled by the curvature of topological quantities.
The entanglement in quantum XY spin chains of arbitrary length is investigated via the geometric measure of entanglement. The emergence of entanglement is explained intuitively from the perspective of perturbations. The model is solved exactly and the energy spectrum is determined and analyzed in particular for the lowest two levels for both finite and infinite systems. The overlaps for these two levels are calculated analytically for arbitrary number of spins. The entanglement is hence obtained by maximizing over a single parameter. The corresponding ground-state entanglement surface is then determined over the entire phase diagram, and its behavior can be used to delineate the boundaries in the phase diagram. For example, the field-derivative of the entanglement becomes singular along the critical line. The form of the divergence is derived analytically and it turns out to be dictated by the universality class controlling the quantum phase transition. The behavior of the entanglement near criticality can be understood via a scaling hypothesis, analogous to that for free energies. The entanglement density vanishes along the so-called disorder line in the phase diagram, the ground space is doubly degenerate and spanned by two product states. The entanglement for the superposition of the lowest two states is also calculated. The exact value of the entanglement depends on the specific form of superposition. However, in the thermodynamic limit the entanglement density turns out to be independent of the superposition. This proves that the entanglement density is insensitive to whether the ground state is chosen to be the spontaneously Z2 symmetry broken one or not. The finite-size scaling of entanglement at critical points is also investigated from two different view points. First, the maximum in the field-derivative of the entanglement density is computed and fitted to a logarithmic dependence of the system size, thereby deducing the correlation length exponent for the Ising class using only the behavior of entanglement. Second, the entanglement density itself is shown to possess a correction term inversely proportional to the system size, with the coefficient being universal (but with different values for the ground state and the first excited state, respectively).