This paper presents a conserving gapless mean-field theory for weakly interacting Bose gases. We first construct a mean-field Luttinger-Ward thermodynamic functional in terms of the condensate wave function
Ψ and the Nambu Green's function
G^ for the quasiparticle field. Imposing its stationarity respect to
Ψ and
G^ yields a set of equations to determine the equilibrium for general non-uniform systems. They have a plausible property of satisfying the Hugenholtz-Pines theorem to provide a gapless excitation spectrum. Also, the corresponding dynamical equations of motion obey various conservation laws. Thus, the present mean-field theory shares two important properties with the exact theory: ``conserving'' and ``gapless.'' The theory is then applied to a homogeneous weakly interacting Bose gas with s-wave scattering length
a and particle mass
m to clarify its basic thermodynamic properties under two complementary conditions of constant density
n and constant pressure
p. The superfluid transition is predicted to be first-order because of the non-analytic nature of the order-parameter expansion near
Tc inherent in Bose systems, i.e., the Landau-Ginzburg expansion is not possible here. The transition temperature
Tc shows quite a different interaction dependence between the
n-fixed and
p-fixed cases. In the former case
Tc increases from the ideal gas value
T0 as
Tc/T0=1+2.33an1/3, whereas it decreases in the latter as
Tc/T0=1−3.84a(mp/2πℏ2)1/5. Temperature dependences of basic thermodynamic quantities are clarified explicitly.
We formulate a conserving gapless mean-field theory for Bose-Einstein condensates on the basis of a Luttinger-Ward thermodynamic functional. It is applied to a weakly interacting uniform gas with density
n and s-wave scattering length
a to clarify its fundamental thermodynamic properties. It is found that the condensation here occurs as a first-order transition. The shift of the transition temperature
ΔTc from the ideal-gas result
T0 is positive and given to the leading order by
ΔTc=2.33an1/3T0, in agreement with a couple of previous estimates. The theory is expected to form a new theoretical basis for trapped Bose-Einstein condensates at finite temperatures.
The ground states of Bose-Einstein condensates (BECs) of spin-2 bosons are classified into three distinct phases (ferromagnetic, ``antiferromagnetic,'' and cyclic) depending on the s-wave scattering lengths of binary collisions for total-spin 0, 2, and 4 channels. Many-body spin correlations and magnetic response of the condensate in each of these phases are studied in a mesoscopic regime, while low-lying excitation spectra are investigated in the thermodynamic regime. In the mesoscopic regime, where the system is so tightly confined that the spatial degrees of freedom are frozen, the exact, many-body ground state for each phase is found to be expressed in terms of the creation operators of pair or trio bosons having spin correlations. These pairwise and trio-wise units are shown to bring about some unique features of spin-2 BECs such as a huge jump in magnetization from minimum to maximum possible values and the robustness of the minimum-magnetization state against an applied magnetic field. In the thermodynamic regime, where the system is spatially uniform, low-lying excitation spectra in the presence of magnetic field are obtained analytically using the Bogoliubov approximation. In the ferromagnetic phase, the excitation spectrum consists of one Goldstone mode and four single-particle modes. In the antiferromagnetic phase, where spin-singlet ``pairs'' undergo Bose-Einstein condensation, the spectrum consists of two Goldstone modes and three massive ones, all of which become massless when magnetic field vanishes. In the cyclic phase, where boson ``trios'' condense into a spin-singlet state, the spectrum is characterized by two Goldstone modes, one single-particle mode having a magnetic-field-independent energy gap, and a gapless single-particle mode that becomes massless in the absence of magnetic field.
Quantum field theory of equilibrium and nonequilibrium Bose-Einstein condensates is formulated so as to satisfy three basic requirements: the Hugenholtz-Pines relation; conservation laws; identities among vertices originating from Goldstone's theorem I. The key inputs are irreducible four-point vertices, in terms of which we derive a closed system of equations for Green's functions, three- and four-point vertices, and two-particle Green's functions. It enables us to study correlated Bose-Einstein condensates with a gapless branch of single-particle excitations without encountering any infrared divergence. The single- and two-particle Green's functions are found to share poles, i.e., the structure of the two-particle Green's functions predicted by Gavoret and Nozières for a homogeneous condensate at
T=0 is also shown to persist at finite temperatures, in the presence of inhomogeneity, and also in nonequilibrium situations.
We present a topical review of the development of finite-temperature field theories of Bose-Einstein condensation in weakly interacting atomic gases. We highlight the difficulties in obtaining a consistent finite-temperature theory that has a gapless excitation spectrum in accordance with Goldstone's theorem and which is free from both ultraviolet and infrared divergences. We present results from the two consistent theories developed so far. These are the Hartree-Fock-Bogoliubov theory within the Popov approximation and a many-body T -matrix approach which we have termed gapless-Hartree-Fock-Bogoliubov (GHFB). Comparison with the available experimental results is made and the remaining difficulties are highlighted.
We investigate Bose-Einstein condensation of trapped spin-1 atoms with ferromagnetic or antiferromagnetic two-body contact interactions. We adopt the mean field theory and develop a Hartree-Fock-Popov type approximation in terms of a semiclassical two-fluid model. For antiferromagnetic interactions, our study reveals double condensations as atoms in the $\ensuremath{\mid}{m}_{F}=0⟩$ state never seem to condense under the constraints of both the conservation of total atom number
N and magnetization
M. For ferromagnetic interactions, however, triple condensations can occur. Our results can be conveniently understood in terms of the interplay of three factors: (anti)ferromagnetic atom-atom interactions,
M conservation, and the miscibilities between and among different condensed components.