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arXiv:cond-mat/0410192 · Journal of the Physical Society of Japan

Non-dissipative Thermal Transport and Magnetothermal Effect for the Spin-1/2 Heisenberg Chain

Kazumitsu Sakai, Andreas Klümper

Published Jan 1, 2005• 22 citations
arXivHTMLPDF

Abstract

Anomalous magnetothermal effects are discussed in the spin-1/2 Heisenberg chain.The energy current is related to one of the non-trivial conserved quantities underlying integrability and therefore both the diagonal and off diagonal dynamical correlations of spin and energy current diverge.The energy-energy and spin-energy current correlations at finite temperatures are exactly calculated by a lattice path integral formulation.The low-temperature behavior of the thermomagnetic (magnetic Seebeck) coefficient is also discussed.Due to effects of strong correlations, we observe the magnetic Seebeck coefficient changes sign at certain interaction strengths and magnetic fields.

DOI
10.1143/jpsjs.74s.196

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Anomalous magnetothermal effects are discussed in the spin-1/2 Heisenberg chain.The energy current is related to one of the non-trivial conserved quantities underlying integrability and therefore both the diagonal and off diagonal dynamical correlations of spin and energy current diverge.The energy-energy and spin-energy current correlations at finite temperatures are exactly calculated by a lattice path integral formulation.The low-temperature behavior of the thermomagnetic (magnetic Seebeck) coefficient is also discussed.Due to effects of strong correlations, we observe the magnetic Seebeck coefficient changes sign at certain interaction strengths and magnetic fields.
A current of magnetic moments will flow in the spin-1/2 Heisenberg chain in the presence of an external magnetic field B and a temperature gradient $\ensuremath{\Delta}T$ along the chain. We show that this magnetothermal effect is strictly infinite for the integrable Heisenberg model in one dimension. We set up the response formalism and derive several new generalized Einstein relations for this magnetothermal effect which vanishes in the absence of an external magnetic field. We estimate the size of the magnetothermal response by exact diagonalization and quantum Monte Carlo simulations and make contact with recent transport measurements for the one-dimensional Heisenberg compound Sr2CuO3.{\mathrm{Sr}}_{2}{\mathrm{CuO}}_{3}.Sr2​CuO3​.
Transport properties in the presence of magnetic fields are numerically studied for the spin-1/2 Heisenberg XXZ chain. The breakdown of the spin-reversal symmetry due to the magnetic field induces the magnetothermal effect. In analogy with the thermoelectric effect in electron systems, the thermomagnetic power (magnetic Seebeck coefficient) is provided, and is numerically evaluated by the exact diagonalization for wide ranges of temperatures and various magnetic fields. For the antiferromagnetic regime, we find the magnetic Seebeck coefficient changes sign at certain temperatures, which is interpreted as an effect of strong correlations. We also compute the thermomagnetic figure of merit determining the efficiency of the thermomagnetic devices for cooling or power generation.
We study the heat conduction of the spin-1∕21∕21∕2 XXZXXZXXZ chain in finite magnetic fields where magnetothermal effects arise. Due to the integrability of this model, all transport coefficients diverge, signaled by finite Drude weights. Using exact diagonalization and mean-field theory, we analyze the temperature and field dependence of the thermal Drude weight for various exchange anisotropies under the condition of zero magnetization-current flow. First, we find a strong magnetic field dependence of the Drude weight, including a suppression of its magnitude with increasing field strength and a nonmonotonic field-dependence of the peak position. Second, for small exchange anisotropies and magnetic fields in the massless as well as in the fully polarized regime, the mean-field approach is in excellent agreement with the exact diagonalization data. Third, at the field-induced quantum critical line between the para- and ferromagnetic region, we propose a universal low-temperature behavior of the thermal Drude weight.
The heat conductivity $\ensuremath{\kappa}(T)$ of integrable models, like the one-dimensional spin-1/21/21/2 nearest-neighbor Heisenberg model, is infinite even at finite temperatures as a consequence of the conservation laws associated with integrability. Small perturbations lead to finite but large transport coefficients which we calculate perturbatively using exact diagonalization and moment expansions. We show that there are two different classes of perturbations. While an interchain coupling of strength ${J}_{\ensuremath{\perp}}$ leads to $\ensuremath{\kappa}(T)\ensuremath{\propto}1/{J}_{\ensuremath{\perp}}^{2}$ as expected from simple golden-rule arguments, we obtain a much larger $\ensuremath{\kappa}(T)\ensuremath{\propto}1/{J}^{\ensuremath{'}4}$ for a weak next-nearest-neighbor interaction ${J}^{\ensuremath{'}}$. This can be explained by a new approximate conservation law of the $J\mathrm{\text{\ensuremath{-}}}{J}^{\ensuremath{'}}$ Heisenberg chain.
We investigate transport in several translationally invariant spin-12\frac{1}{2}21​ chains in the limit of high temperatures. We concretely consider spin transport in the anisotropic Heisenberg chain, the pure Heisenberg chain within an alternating field, and energy transport in an Ising chain which is exposed to a tilted field. Our approach is essentially based on a connection between the evolution of the variance of an inhomogeneous nonequilibrium density and the current-autocorrelation function at finite times. Although this relationship is not restricted to the case of diffusive transport, it allows to extract a quantitative value for the diffusion constant in that case. By means of numerically exact diagonalization we indeed observe diffusive behavior in the considered spin chains for a range of model parameters and confirm the diffusion coefficients which were obtained for these systems from nonequilibrium bath scenarios.