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arXiv:cond-mat/0406617 · New Journal of Physics

Phase diagrams for an ideal gas mixture of fermionic atoms and bosonic molecules

JAMES E. JUN. WILLIAMS, Nicolai Gayle Nygaard, Charles W. Clark

Published Sep 30, 2004• 30 citations
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Abstract

We calculate the phase diagrams for a harmonically trapped ideal gas mixture of fermionic atoms and bosonic molecules in chemical and thermal equilibrium, where the internal energy of the molecules can be adjusted relative to that of the atoms by use of a tunable Feshbach resonance. We plot the molecule fraction and the fraction of Bose-condensed molecules as functions of the temperature and internal molecular energy. We show the paths traversed in the phase diagrams when the molecular energy is varied either suddenly or adiabatically. Our model calculation helps to interpret the adiabatic phase diagrams obtained in recent experiments on the Bose–Einstein condensation to Bardeen–Cooper–Schrieffer crossover, in which the condensate fraction is plotted as a function of the initial temperature of the Fermi gas measured before a sweep of the magnetic field through the resonance region.

DOI
10.1088/1367-2630/6/1/123

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We calculate the phase diagrams for a harmonically trapped ideal gas mixture of fermionic atoms and bosonic molecules in chemical and thermal equilibrium, where the internal energy of the molecules can be adjusted relative to that of the atoms by use of a tunable Feshbach resonance. We plot the molecule fraction and the fraction of Bose-condensed molecules as functions of the temperature and internal molecular energy. We show the paths traversed in the phase diagrams when the molecular energy is varied either suddenly or adiabatically. Our model calculation helps to interpret the adiabatic phase diagrams obtained in recent experiments on the Bose–Einstein condensation to Bardeen–Cooper–Schrieffer crossover, in which the condensate fraction is plotted as a function of the initial temperature of the Fermi gas measured before a sweep of the magnetic field through the resonance region.
We determine the adiabatic phase diagram of a resonantly-coupled system of Fermi atoms and Bose molecules confined in the harmonic trap by using the local density approximation. The adiabatic phase diagram shows the fermionic condensate fraction composed of condensed molecules and Cooper pair atoms. The key idea of our work is conservation of entropy through the adiabatic process, extending the study of Williams et al. [Williams et al., New J. Phys. 6, 123 (2004)] for an ideal gas mixture to include the resonant interaction in a mean-field theory. We also calculate the molecular conversion efficiency as a function of initial temperature. Our work helps to understand recent experiments on the BCS-BEC crossover, in terms of the initial temperature measured before a sweep of the magnetic field.
The entropy and kinetic, potential, and interaction energies of an atomic Fermi gas in a trap are studied under the assumption of thermal equilibrium for finite temperature. A Feshbach resonance can cause the fermions to pair into diatomic molecules. The entropy and energies of mixtures of such molecules with unpaired atoms are calculated, in relation to recent experiments on molecular Bose-Einstein condensates produced in this manner. It is shown that, starting with a Fermi gas of temperature T=0.1TF0T=0.1{T}_{F}^{0}T=0.1TF0​, where TF0{T}_{F}^{0}TF0​ is the noninteracting Fermi temperature, an extremely cold degenerate Fermi gas of temperature $T\ensuremath{\lesssim}0.01{T}_{F}^{0}$ may be produced without further evaporative cooling. This requires adiabatic passage of the resonance, subsequent sudden removal of unpaired atoms, and adiabatic return. We also calculate the ratio of the interaction energy to the kinetic energy, a straightforward experimental signal which may be used to determine the temperature of the atoms and indicate condensation of the molecules.
We consider a Bose-Fermi mixture with a broad and tunable Feshbach resonance allowing to change continuously the attraction between bosons and fermions from weak to strong coupling. We set up a diagrammatic formalism which includes both the Bose-Fermi tunable attraction and the Bose-Bose repulsion at zero temperature. Remarkably, we find that for boson density smaller than or equal to the fermion density, the boson condensate fraction does not depend on the density imbalance across most of the resonance. In the limit of vanishing boson concentration, we find very good agreement with previous results for the polaron quasi-particle residue obtained in the context of strongly polarized Fermi-Fermi mixtures [1]. We calculate also the boson and fermion chemical potentials and momentum distribution functions and, when the condensate fraction vanishes, we recover the results of our previous works for the normal phase [2,3]. In addition, we calculate the effective masses and Fermi steps for the unpaired and composite fermions. We find that the Fermi step of the unpaired fermions remains pinned to the value given by the Fermi radius of a free Fermi gas across most of the resonance, in agreement with the Luttinger’s theorem [4], until molecules start to form (g≈1). The formation of molecules is signalled by the appearance of a second pole in the boson-fermion propagator, which marks the access to a regime where bosons, fermions and molecules cohexist, and by the presence of a Fermi step for the composite fermions, which is related to the density of molecules. Finally, we find quite a good agreement between our results for the condensate fraction and Quantum Monte Carlo calculations [5].
Trapped ultracold Fermi gases provide a system that can be tuned between the BCS and Bose-Einstein condensation regimes by means of a magnetic-field Feshbach resonance. Condensation of fermionic atom pairs in a 40K^{40}\mathrm{K}40K gas was demonstrated experimentally by a sweep technique that pairwise projects fermionic atoms onto molecules. In this paper, we examine previous data obtained with this technique that probed the phase boundary in the temperature-magnetic field plane. Comparison of the 40K^{40}\mathrm{K}40K data to a theoretically computed phase diagram demonstrates good agreement between the two.
We investigate the Bose-Einstein condensation of fermionic pairs in a uniform two-component Fermi gas, obtaining an explicit formula for the condensate density as a function of the chemical potential and the energy gap. We analyze the condensate fraction in the crossover from the Bardeen-Cooper-Schrieffer (BCS) state of weakly interacting Cooper pairs to the Bose-Einstein condensate of molecular dimers. By using the local-density approximation we study confined Fermi vapors of alkali-metal atoms for which there is experimental evidence of condensation also on the BCS side of the Feshbach resonance. Our theoretical results are in agreement with these experimental data and give the behavior of the condensate on both sides of the Feshbach resonance at zero temperature.