Zero-temperature or quantum phase transitions in itinerant electronic systems both with and without quenched disordered are discussed. Phase transitions considered include, the ferromagnetic transition, the antiferromagnetic transition, the superconductor-metal transition, and various metal-insulator transitions. Emphasis is placed on how to determine the universal properties that characterize these quantum phase transitions. For the first three of the phase transitions listed above, one of the main physical ideas established is that in zero-temperature systems there are soft or slow modes that exist in addition to the soft order parameter fluctuations, and that these modes can couple to the critical modes. These extra soft modes are shown to have a profound effect on the quantum critical properties. For quantum phase transitions involving zero wavenumber order parameters, i.e., the ferromagnetic and superconductor-metal transitions, these extra modes effectively lead to long-ranged effective interactions between order parameter fluctuations, which in turn lead to exactly soluble critical behaviors. For the antiferromagnetic case, we argue that while in low enough dimensions disorder fluctuation effects tend to destroy long-range order, quantum fluctuations counteract this effect and in some parameter regions manage to re-establish antiferromagnetic long-range order. For the metal-insulator transition, some recent new ideas are reviewed. In particular, it is pointed out that for interacting disordered electrons, one expects that in high dimensions the metal-insulator transition is related to the phase transition that occurs in random-field magnets in high dimensions. If the analogy also holds in three dimensions this suggests that the metal-insulator transition might have glassy characteristics.
In recent years, quantum phase transitions have attracted the interest of both theorists and experimentalists in condensed matter physics. These transitions, which are accessed at zero temperature by variation of a non-thermal control parameter, can influence the behaviour of electronic systems over a wide range of the phase diagram. Quantum phase transitions occur as a result of competing ground state phases. The cuprate superconductors which can be tuned from a Mott insulating to a d -wave superconducting phase by carrier doping are a paradigmatic example. This review introduces important concepts of phase transitions and discusses the interplay of quantum and classical fluctuations near criticality. The main part of the article is devoted to bulk quantum phase transitions in condensed matter systems. Several classes of transitions will be briefly reviewed, pointing out, e.g., conceptual differences between ordering transitions in metallic and insulating systems. An interesting separate class of transitions is boundary phase transitions where only degrees of freedom of a subsystem become critical; this will be illustrated in a few examples. The article is aimed at bridging the gap between high-level theoretical presentations and research papers specialized in certain classes of materials. It will give an overview on a variety of different quantum transitions, critically discuss open theoretical questions, and frequently make contact with recent experiments in condensed matter physics.
We derive an order-parameter field theory for a quantum phase transition between a disordered metal and an exotic (non-
s-wave) superconductor. Mode coupling effects between the order parameter and other fermionic soft modes lead to an effective long-range interaction between the anomalous density fluctuations which is reflected in singularities in the free energy functional. However, this long-range interaction is not strong enough to suppress disorder fluctuations. The asymptotic critical region is characterized by run-away flow to large disorder. For weak coupling, this asymptotic region is very narrow. It is preempted by a wide crossover regime with mean-field critical behavior and, in the
p-wave case, logarithmic corrections to scaling in all dimensions.
Introduction The quantum phase transitions considered so far in this book are mostly continuous, second order. They are associated with the divergence of a correlation length and of a characteristic time that renders the quantum critical point scale invariant. However, there are many important phase transitions at which the order parameter goes abruptly to zero and, more important, at which the characteristics of length and critical time do not diverge. In general there is also a latent heat , or work required, to transform one phase into another. In this and the next chapter we study these discontinuous quantum phase transitions. We proceed by considering initially some important cases of what is known as fluctuation induced quantum phase transitions to next treat a more general case of a first-order quantum phase transition. We will show through the study of these problems that the concepts of critical exponents and scaling remain useful, even though these systems do not exhibit scale invariance at their critical point. In Chapter 15 we present the scaling theory of first-order quantum phase transitions and use its results to treat some general problems. One of the most interesting cases of fluctuation-induced transitions occurs in superconductors due to the coupling of the charged carriers to the electromagnetic field. We consider initially a wider class of systems with macroscopic wave functions, the superfluids, of which superconductors are the charged version. We adopt a macroscopic approach to this problem and describe the superfluid by a complex order parameter φ , such that | φ | 2 is proportional to the density of condensed particles. The zero temperature phase diagram is expressed in terms of a control parameter, m 2 , such that, at m 2 = 0, the system presents a quantum phase transition from a superfluid state, for m 2 < 0, φ ≠ 0, to a normal state for m 2 > 0 where φ = 0. In the case of the superconductor with particles of charge q = 2 e , we will include the coupling of these particles to the electromagnetic field and study its effect in the phase diagram of these systems. We show that in the neutral superfluid, the zero temperature transition to the normal state is continuous and occurs at a quantum critical point.
This paper proposes an approach to the study of critical phenomena in quantum-mechanical systems at zero or low temperatures, where classical free-energy functionals of the Landau-Ginzburg-Wilson sort are not valid. The functional integral transformations first proposed by Stratonovich and Hubbard allow one to construct a quantum-mechanical generalization of the Landau-Ginzburg-Wilson functional in which the order-parameter field depends on (imaginary) time as well as space. Since the time variable lies in the finite interval [$0,\ensuremath{-}i\ensuremath{\beta}$], where $\ensuremath{\beta}$ is the inverse temperature, the resulting description of a
d-dimensional system shares some features with that of a (
d+1)-dimensional classical system which has finite extent in one dimension. However, the analogy is not complete, in general, since time and space do not necessarily enter the generalized free-energy functional in the same way. The Wilson renormalization group is used here to investigate the critical behavior of several systems for which these generalized functionals can be constructed simply. Of these, the itinerant ferromagnet is studied in greater detail. The principal results of this investigation are (i) at zero temperature, in situations where the ordering is brought about by changing a coupling constant, the dimensionality which separates classical from nonclassical critical-exponent behavior is not 4, as is usually the case in classical statistics, but $4\ensuremath{-}z$ dimensions, where
z depends on the way the frequency enters the generalized free-energy functional. When it does so in the same way that the wave vector does, as happens in the case of interacting magnetic excitons, the effective dimensionality is simply increased by 1;
z=1. It need not appear in this fashion, however, and in the examples of itinerant antiferromagnetism and clean and dirty itinerant ferromagnetism, one finds
z=2,3,and4, respectively. (ii) At finite temperatures, one finds that a classical statistical-mechanical description holds (and nonclassical exponents, for
d<4) very close to the critical value of the coupling
Uc, when $\frac{(U\ensuremath{-}{U}_{c})}{{U}_{c}}\ensuremath{\ll}{(\frac{T}{{U}_{c}})}^{\frac{2}{z}}$.
2z is therefore the quantum-to-classical crossover exponent.