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Physical review. B, Solid state

Quantum critical phenomena

John Hertz

Published Aug 1, 1976• 2,141 citations
Publisher

Abstract

This paper proposes an approach to the study of critical phenomena in quantum-mechanical systems at zero or low temperatures, where classical free-energy functionals of the Landau-Ginzburg-Wilson sort are not valid. The functional integral transformations first proposed by Stratonovich and Hubbard allow one to construct a quantum-mechanical generalization of the Landau-Ginzburg-Wilson functional in which the order-parameter field depends on (imaginary) time as well as space. Since the time variable lies in the finite interval [$0,\ensuremath{-}i\ensuremath{\beta}$], where $\ensuremath{\beta}$ is the inverse temperature, the resulting description of a $d$-dimensional system shares some features with that of a ($d+1$)-dimensional classical system which has finite extent in one dimension. However, the analogy is not complete, in general, since time and space do not necessarily enter the generalized free-energy functional in the same way. The Wilson renormalization group is used here to investigate the critical behavior of several systems for which these generalized functionals can be constructed simply. Of these, the itinerant ferromagnet is studied in greater detail. The principal results of this investigation are (i) at zero temperature, in situations where the ordering is brought about by changing a coupling constant, the dimensionality which separates classical from nonclassical critical-exponent behavior is not 4, as is usually the case in classical statistics, but $4\ensuremath{-}z$ dimensions, where $z$ depends on the way the frequency enters the generalized free-energy functional. When it does so in the same way that the wave vector does, as happens in the case of interacting magnetic excitons, the effective dimensionality is simply increased by 1; $z=1$. It need not appear in this fashion, however, and in the examples of itinerant antiferromagnetism and clean and dirty itinerant ferromagnetism, one finds $z=2, 3, \mathrm{and} 4$, respectively. (ii) At finite temperatures, one finds that a classical statistical-mechanical description holds (and nonclassical exponents, for $d<4$) very close to the critical value of the coupling ${U}_{c}$, when $\frac{(U\ensuremath{-}{U}_{c})}{{U}_{c}}\ensuremath{\ll}{(\frac{T}{{U}_{c}})}^{\frac{2}{z}}$. $\frac{z}{2}$ is therefore the quantum-to-classical crossover exponent.

DOI
10.1103/physrevb.14.1165

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This paper proposes an approach to the study of critical phenomena in quantum-mechanical systems at zero or low temperatures, where classical free-energy functionals of the Landau-Ginzburg-Wilson sort are not valid. The functional integral transformations first proposed by Stratonovich and Hubbard allow one to construct a quantum-mechanical generalization of the Landau-Ginzburg-Wilson functional in which the order-parameter field depends on (imaginary) time as well as space. Since the time variable lies in the finite interval [0,- iβ ], where β is the inverse temperature, the resulting description of a d -dimensional system shares some features with that of a ( d + 1)-dimensional classical system which has finite extent in one dimension. However, the analogy is not complete, in general, since time and space do not necessarily enter the generalized free-energy functional m the same way. The Wilson renormalization group is used here to investigate the critical behavior of several systems for which these generalized functionals can be constructed simply. Of these, the itinerant ferromagnet is studied in greater detail. The principal results of this investigation are (i) at zero temperature, in situations where the ordering is brought about by changing a coupling constant, the dimensionality which separates classical from nonclassical critical-exponent behavior is not 4, as is usually the case in classical statistics, but 4 − z dimensions, where z depends on the way the frequency enters the generalized free-energy functional. When it does so m the same way that the wave vector does, as happens in the case of interacting magnetic excitons, the effective dimensionality is simply increased by 1; z = 1. It need not appear in this fashion, however, and in the examples of itinerant antiferromagnetism and clean and dirty itinerant ferromagnetism, one finds z = 2, 3, and 4, respectively, (ii) At finite temperatures, one finds that a classical statistical-mechanical description holds (and nonclassical exponents, for d < 4) very close to the critical value of the coupling U c , when ( U − U c ) / U c ≪ ( T / U c ) 2 / z z / 2 https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9780429494116/afa305c7-7e11-4618-94aa-661e4acf5b1d/content/eq2970.tif"/> is therefore the quantum-to-classical crossover exponent.

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This paper proposes an approach to the study of critical phenomena in quantum-mechanical systems at zero or low temperatures, where classical free-energy functionals of the Landau-Ginzburg-Wilson sort are not valid. The functional integral transformations first proposed by Stratonovich and Hubbard allow one to construct a quantum-mechanical generalization of the Landau-Ginzburg-Wilson functional in which the order-parameter field depends on (imaginary) time as well as space. Since the time variable lies in the finite interval [0,\ensuremath−i\ensuremathβ0,\ensuremath{-}i\ensuremath{\beta}0,\ensuremath−i\ensuremathβ], where \ensuremathβ\ensuremath{\beta}\ensuremathβ is the inverse temperature, the resulting description of a ddd-dimensional system shares some features with that of a (d+1d+1d+1)-dimensional classical system which has finite extent in one dimension. However, the analogy is not complete, in general, since time and space do not necessarily enter the generalized free-energy functional in the same way. The Wilson renormalization group is used here to investigate the critical behavior of several systems for which these generalized functionals can be constructed simply. Of these, the itinerant ferromagnet is studied in greater detail. The principal results of this investigation are (i) at zero temperature, in situations where the ordering is brought about by changing a coupling constant, the dimensionality which separates classical from nonclassical critical-exponent behavior is not 4, as is usually the case in classical statistics, but 4\ensuremath−z4\ensuremath{-}z4\ensuremath−z dimensions, where zzz depends on the way the frequency enters the generalized free-energy functional. When it does so in the same way that the wave vector does, as happens in the case of interacting magnetic excitons, the effective dimensionality is simply increased by 1; z=1z=1z=1. It need not appear in this fashion, however, and in the examples of itinerant antiferromagnetism and clean and dirty itinerant ferromagnetism, one finds z=2,3,and4z=2, 3, \mathrm{and} 4z=2,3,and4, respectively. (ii) At finite temperatures, one finds that a classical statistical-mechanical description holds (and nonclassical exponents, for d<4d<4d<4) very close to the critical value of the coupling Uc{U}_{c}Uc​, when (U\ensuremath−Uc)Uc\ensuremath≪(TUc)2z\frac{(U\ensuremath{-}{U}_{c})}{{U}_{c}}\ensuremath{\ll}{(\frac{T}{{U}_{c}})}^{\frac{2}{z}}Uc​(U\ensuremath−Uc​)​\ensuremath≪(Uc​T​)z2​. z2\frac{z}{2}2z​ is therefore the quantum-to-classical crossover exponent.
This paper proposes an approach to the study of critical phenomena in quantum-mechanical systems at zero or low temperatures, where classical free-energy functionals of the Landau-Ginzburg-Wilson sort are not valid. The functional integral transformations first proposed by Stratonovich and Hubbard allow one to construct a quantum-mechanical generalization of the Landau-Ginzburg-Wilson functional in which the order-parameter field depends on (imaginary) time as well as space. Since the time variable lies in the finite interval [0,- iβ ], where β is the inverse temperature, the resulting description of a d -dimensional system shares some features with that of a ( d + 1)-dimensional classical system which has finite extent in one dimension. However, the analogy is not complete, in general, since time and space do not necessarily enter the generalized free-energy functional m the same way. The Wilson renormalization group is used here to investigate the critical behavior of several systems for which these generalized functionals can be constructed simply. Of these, the itinerant ferromagnet is studied in greater detail. The principal results of this investigation are (i) at zero temperature, in situations where the ordering is brought about by changing a coupling constant, the dimensionality which separates classical from nonclassical critical-exponent behavior is not 4, as is usually the case in classical statistics, but 4 − z dimensions, where z depends on the way the frequency enters the generalized free-energy functional. When it does so m the same way that the wave vector does, as happens in the case of interacting magnetic excitons, the effective dimensionality is simply increased by 1; z = 1. It need not appear in this fashion, however, and in the examples of itinerant antiferromagnetism and clean and dirty itinerant ferromagnetism, one finds z = 2, 3, and 4, respectively, (ii) At finite temperatures, one finds that a classical statistical-mechanical description holds (and nonclassical exponents, for d < 4) very close to the critical value of the coupling U c , when ( U − U c ) / U c ≪ ( T / U c ) 2 / z z / 2 https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9780429494116/afa305c7-7e11-4618-94aa-661e4acf5b1d/content/eq2970.tif"/> is therefore the quantum-to-classical crossover exponent.
At temperatures low compared with characteristic atomic frequencies, classical free energy functionals where the order parameter field ψ which depends only on position are inadequate to describe fluctuation phenomena; the noncommutativity of quantum‐mechanical operators leads to a ψ which also depends on time. We show how to generalize the renormalization group to such functionals. For phase transitions at T=0 caused by variation of a coupling parameter, the boundary between classical and nonclassical exponent behavior is at 4‐z, not 4 dimensions, where z≳1 depends on the dynamics of the system: z=1 for van Vleck ferromagnets, z=2 for itinerant antiferomagnets, z=3 for clean and z=4 for dirty itinerant ferromagnets. For small Tc there is a crossover region where the renormalization group equations go from their T=0 form to a Wilson form, implying a large precritical region where classical exponents are correct and a small true critical region. One also has an explicit construction of the Wilson free energy functional valid in the critical region.
Classical and quantum criticality In most cases the phases of quantum field theories, in particular those of interest in condensed matter physics, can be described in terms of the behavior of local observables, such as order parameters or currents that transform properly under the symmetries of the theory. Quantum and thermal phase transitions are characterized by the behavior of these observables as a function of temperature and of the coupling constants of the theory. The phase transitions themselves, quantum or thermal, are classified into universality classes, which are represented by the critical exponents which specify the scaling laws of the expectation values of the observables. Historically, the development of this approach to critical behavior goes back to the Landau theory of critical behavior. It acquired its most complete form with the development of the renormalization group (RG) in the late 1960s and early 1970s. It is the centerpiece of Wilson’s approach to quantum field theory, in which all local quantum field theories are defined by the scaling regime of a physical system near a continuous phase transition. From this point of view there is no fundamental difference between classical (or thermal) phase transitions, which are described by the theory of classical critical behavior, and quantum phase transitions. For example, the expectation value of a local order parameter M as the thermal phase transition is approached from below behaves as M ~ (Tc − T) β . Here T c is the critical temperature and β is a critical exponent that depends on the universality class of the thermal phase transition and on the dimensionality of space. While quantum mechanics can play a key role in the existence of the ordered phase, e.g. superfluidity and superconductivity are macroscopic manifestations of essentially quantum-mechanical phenomena, the thermal transition itself is governed entirely by classical statistical mechanics, and quantum mechanics plays a role in setting the value of non-universal quantities such as the critical temperature, etc. On the other hand, in the case of a quantum phase transition, the order parameter M has a similar scaling behavior as a function of the coupling constant, M~(gc−g)β˜, where g is the coupling constant, g c is the critical coupling constant, and β˜ is a critical exponent that depends on the universality class of the quantum phase transition. Here we assume that M has a non-vanishing expectation value only for g < g c .
In this thesis I investigate several aspects of local quantum criticality, a concept of key importance in a number of physical contexts ranging from critical heavy fermion compounds to quantum dot systems. Quantum critical points are associated with second order phase transitions at zero temperature. In contrast to their finite-temperature counterparts, the zero-point motion cannot be neglected near a quantum critical point. As a result, the incorporation of quantum dynamics leads to an effective dimension larger than the spatial dimension of the system for the order parameter fluctuations within the Ginzburg-Landau-Wilson treatment of criticality. This so-called quantum-to-classical mapping works well for the critical properties in insulating systems but apparently fails in systems containing gapless fermions. This has been experimentally most clearly been demonstrated within a particular class of intermetallic compounds called heavy fermions. A particular way in which the Ginzburg-Landau-Wilson paradigm fails is for critical Kondo destruction that seems to underlie the unconventional quantum criticality seen in the heavy fermions. I focus on studying the properties of critical Kondo destruction and the emergence of energy-over-temperature-scaling in systems without spatial degrees of freedom, i.e., so-called quantum impurity systems. In particular, I employ large-N techniques to address critical properties of this class of quantum phase transitions in and out of equilibrium. As quantum critical systems are characterized by a scale-invariant spectrum with many low-lying excitations, it may appear that any perturbation can lead to a response beyond the linear response regime. Understanding what governs the non-linear response regime near quantum criticality is an interesting area. Here, I first present a path integral version of the Schrieffer-Wolff transformation which relates the functional integral form of the partition function of the Anderson model to that of its effective low-energy model. The equivalence between the low-energy sector of the Anderson model in the Kondo regime and the spin-isotropic Kondo model is usually established via a canonical transformation performed on the Hamiltonian, followed by a projection. The resulting functional integral assumes the form of a spin path integral and includes a geometric phase factor, i.e. a Berry phase. The approach stresses the underlying symmetries of the model and allows for a straightforward generalization of the transformation to more involved models. As an example of the efficiency of the approach I apply it to a single electron transistor attached to ferromagnetic leads and derive the effective low-energy model of such a magnetic transistor. As Kondo screening is a local phenomenon, it and its criticality can be studied using the appropriate impurity model. A general impurity model to study critical Kondo destruction is the pseudogap Bose-Fermi Kondo model. Here, I concentrate on the multi-channel version of the model using the dynamical large-N study. This model allows to study the non-trivial interplay between two different mechanisms of critical Kondo destruction. The interplay of two processes that can each by itself lead to critical Kondo destruction. The zero-temperature residual entropy at various fixed points for the model is also discussed. The two channel Anderson model exhibits several continuous quantum phase transitions between weak- and strong-coupling phases. The non-crossing approximation (NCA) is believed to give reliable results for the standard two-channel Anderson model of a magnetic impurity in a metal. I revisit the reliability of the NCA for the standard two channel Anderson model (constant conduction electron density of states) and investigate its reliability for the two-channel pseudogap Anderson model. This is done by comparing finite-temperature, finite-frequency solutions of the NCA equations and asymptotically exact zero-temperature NCA solutions with numerical renormalization-group calculations. The phase diagram of this model is well established. The focus here will be on the dynamical scaling properties obtained within the NCA. Finally, I study the thermal and non-thermal steady state scaling functions and the steady-state dynamics of the pseudogap Kondo model. This model allows us to study the concept of effective temperatures near fully interacting as well as weak-coupling fixed points and compare the out-of-equilibrium scaling properties of critical Kondo destruction to those of the traditional spin-density wave (SDW) scenario. The differences I identify can be experimentally probed. This may be helpful in identifying the nature of the quantum critical points observed in certain heavy fermion compounds.
A nonconventional renormalization-group (RG) treatment close to and below four dimensions is used to explore, in a unified and systematic way, the low-temperature properties of a wide class of systems in the influence domain of their quantum critical point. The approach consists in a preliminary averaging over quantum degrees of freedom and a successive employment of the Wilsonian RG transformation to treat the resulting effective classical Ginzburg-Landau free energy functional. This allows us to perform a detailed study of criticality of the quantum systems under study. The emergent physics agrees, in many aspects, with the known quantum critical scenario. However, a richer structure of the phase diagram appears with additional crossovers which are not captured by the traditional RG studies. In addition, in spite of the intrinsically static nature of our theory, predictions about the dynamical critical exponent, which parametrizes the link between statics and dynamics close to a continuous phase transition, are consistently derived from our static results.
Using the generalized Ginzburg-Landau-Wilson Hamiltonian with a random field, we have shown the absence of classical to quantum crossover near zero temperature. Our finding suggests that the critical exponents of a quantum system with a random field at T=0T=0T=0 can be obtained from those of the corresponding pure system by a dimensionality shift from ddd to $d\ensuremath{-}(\ensuremath{\sigma}+z)$, where $\ensuremath{\sigma}$ is related to the range of interaction and zzz is the characteristic exponent of a given quantum system.