This thesis presents experiments probing physics in the crossover between Bose-Einstein condensation (BEC) and BCS superconductivity using an ultracold gas of atomic fermions. Scattering resonances in these ultracold gases (known as Feshbach resonances) provide the unique ability to tune the fermion-fermion interactions. The work presented here pioneered the use of fermionic Feshbach resonances as a highly controllable and tunable system ideal for studying the cusp of the BCS-BEC crossover problem. Here pairs of fermionic atoms have some properties of diatomic molecules and some properties of Cooper pairs. I present studies of a normal Fermi gas at a Feshbach resonance and the work required to cool the gas to temperatures where superfluidity in the crossover is predicted. These studies culminated in our observation of a phase transition at the cusp of the BCS-BEC crossover through condensation of fermionic atom pairs. I also discuss subsequent work that confirmed the crossover nature of the pairs in these condensates.
The quantum mechanical phenomenon of Bose-Einstein condensation appears throughout physics with manifestations ranging from superconductivity in metals to superfluidity in nuclei and neutron stars. In most cases the condensation emerges due to correlations or pairing of fermionic particles. We explore this quantum behavior in a uniquely controllable and clean system consisting of an ultracold gas of atoms. In particular, by tuning the interactions between the fermionic atoms that make up our ultracold gas we can create condensates consisting of pairs of correlated atoms. These experiments introduce the ability to access the intriguing crossover regime where the quantum behavior of fermions becomes intertwined with that of bosons.
The paper gives an overview of the recent developments in the field of ultracold fermionic quantum gases. In particular, results obtained on an ultracold spin-mixture of /sup 6/Li atoms in a series of experiments performed in Innsbruck is presented . Bose-Einstein condensation of strongly bound atom pairs (molecules) , the reversible crossover to a degenerate Fermi gas, measurements of collective excitation modes, and spectroscopic observation of pairing in a strongly interacting Fermi gas of atoms are also discussed. The experimental results provide strong evidence for superfluidity.
Atomic Feshbach resonances have recently been used to produce a strongly interacting Fermi gas, where the BCS/BEC crossover can be explored. We have used both narrow and broad Feshbach resonances to convert a quantum degenerate Fermi gas of 6Li atoms into an ultracold gas of Li2 molecules. For the narrow resonances, the molecules are formed by coherent adiabatic passage through the resonance. We find that 50% of the atoms are converted to molecules. Furthermore, the lifetime of these molecules was measured to be surprisingly long, 1 s. We will discuss these measurements in the context of the present theoretical understanding. Molecules can also be formed using static fields near the broad Feshbach resonance. The lifetime of these molecules is again long, and sufficient to enable their evaporation to a Bose‐Einstein condensate. Phase contrast images of the molecular condensate are presented. The BCS/BEC crossover may be explored by starting with a pure molecular condensate on the low‐field side of the Feshbach resonance, and adiabatically changing the field to any final value around resonance. We combine this ability with optical spectroscopy on a bound‐bound molecular transition to probe the nature of the many‐body wavefunction in the crossover regime.
Preparation of molecular quantum gas promises novel applications including quantum control of chemical reactions, precision measurements, quantum simulation and quantum information processing. Experimental preparation of colder and denser molecular samples, however, is frequently hindered by fast inelastic collisions that heat and deplete the population. Here we report the formation of two-dimensional Bose-Einstein condensates (BECs) of spinning
g−wave molecules by inducing pairing interactions in an atomic condensate. The trap geometry and the low temperature of the molecules help reducing inelastic loss to ensure thermal equilibrium. We determine the molecular scattering length to be
+220(30)~Bohr and investigate the unpairing dynamics in the strong coupling regime. Our work confirms the long-sought transition between atomic and molecular condensates, the bosonic analog of the BEC-BCS (Bardeen-Cooper-Schieffer superfluid) crossover in a Fermi gas.
The year 2015 marks the 20th anniversary of the achievement of Bose–Einstein condensation (BEC) in atomic vapors. Atomic BEC, realized by Eric Cornell, Carl Wieman and Wolfgang Ketterle in 1995, commenced an exciting wave to explore quantum few- and many-body physics. Different from solid state matter and helium superfluids, atomic condensates in the gas phase come with drastically lower densities and temperatures, which place the systems in a unique regime where the atomic interactions are simple and precisely known. Furthermore, the condensates are typically weakly interacting: the interaction length scale of few nanometers is much shorter than the interatomic separation of hundreds of nanometers. Thus many early experimental observations can be well understood based on mean-field theory. One celebrated model is the Gross-Pitaevskii equation which provides a precise and quantitative description of weakly interacting Bose condensates [1]. Opportunities to extend cold atom research beyond the weak interaction regime emerged in the early 2000s. Several experimental schemes were developed to prepare atoms in the strong correlation and interaction regimes. One approach is loading atoms into an optical lattice, the interference pattern of laser beams. The lattice potential enhances the interactions of localized atoms and quenches their kinetic energy. A variety of lattice configurations are realized that promise novel quantum phases of ultracold atoms. Another route to strong interaction is based on Feshbach resonance, typically induced by magnetically shifting a molecular state near the scattering continuum of atoms. The resonant coupling between scattering atoms and the molecular state leads to a divergence of the atomic interaction length scale. Exactly on Feshbach resonance, the collision cross section reaches the quantum mechanical limit, and the system becomes strongly hydrodynamic with mean-free path as short as interparticle separation. Fascinating observations in the strong coupling regime soon followed: prominent examples include the superfluid-Mott insulator transition in optical lattices [2], resonantly interacting Fermi gases in the BEC–BCS (Bardeen–Cooper–Schieffer superfluid) crossover [3] and Efimov three-body states [4], and they lead to tremendous research interest into novel quantum states and quantum dynamics. One of the key motivations in these explorations is to uncover new, universal principles that underpin the physics of strongly correlated quantum systems. A well-studied universal behavior in many-body physics manifests in the critical phenomena near a continuous phase transition. Near the critical point, the system develops a diverging correlation length, which suppresses the dependence on other microscopic length scales. The systems are thus scale invariant and can be universally characterized by a few critical exponents. In cold atoms, divergence of correlation lengthes has been observed near the superfluid phase transition [5,6], as well as the superfluid-Mott insulator quantum phase transition in optical lattices. In the lattice experiments, scale invariance can be tested based on the equation of state measurements [7]. These works complement the transport measurements in condensed matter experiments. Has a new class of universal physics been discovered in atomic quantum gases? Yes, it turns out that a special class of strongly interacting quantum gas with ‘intrinsic’ scaling symmetry emerges near a Feshbach resonance [8]. Near the resonance, the scattering length scale diverges a → ∞ [9], unimaginable in classical systems, and the interaction length reaches the maximum value allowed by quantum mechanics as 1/k, called the ‘unitarity limit’ and k is the momentum of the scattering state. A famous example is the strongly interacting Fermi gas in the BEC–BCS crossover regime, where the resonant interactions lead to strong pairing and and universal hydrodynamic behavior. An exciting development in the study of the BEC–BCS crossover focuses on the Fermi gas exactly on Feshbach resonance. Here the system, also called a ‘unitary Fermi gas’, is the most complex and strongly correlated. The resonant interaction, however, implies a special scaling symmetry of the system. To understand the symmetry, we consider a scale transformation: x → Λx that stretches the coordinates of all atoms by a factor of Λ, and thus reduces the atomic density n by a factor of Λ3 in a 3D gas and the kinetic energy Ek ∝ −∇2 by Λ2. One can see that both kinetic energy Ek and interaction energy in the unitarity limit na → n/k are reduced by the same factor Λ2. The system is thus hypothesized to be invariant under the scale transformation [8]. Remarkably, similar scaling symmetry also holds for 2D quantum gas with a constant coupling g = const. [10]. Here stretching the size of the 2D gas by a factor of Λ also reduces both the kinetic Ek and interaction energy gσ by Λ2, where σ is the 2D density. Since the scaling symmetry in these systems comes directly from the form of the interactions, intrinsic scale invariance is robust at all temperatures T and chemical potentials μ and does not rely on the proximity to a phase transition. The scaling symmetry suggests that the only independent variables are the ratios of the length scales or the equivalent energy scales. In a grand canonical ensemble, the independent ratio can be chosen as μ/kBT. This realization greatly simplifies theoretical description as well as the experimental characterization of the system. Theoretically, a new set of universal thermodynamic relations are expected to be insensitive to the microscopic details; experimentally, measurements are expected to collapse into universal functions that only depend on μ/kBT. Measurements on unitary Fermi gas and the 2D Bose gas are consistent with the scaling hypothesis, shown in Fig. 1(a) and (b). Remarkable quantitative agreement between measurements and calculations has greatly advanced our understanding of the ‘unitary Fermi gas’ and 2D atomic gas. Ultracold atomic gases which are intrinsically scale invariant: (a) unitary Fermi gas, (b) 2D Bose gas and (c) unitary Bose gas. The scaling symmetry suggests that thermodynamic observables only depend on the ratio of chemical potential and thermal energy |
μ~=μ/kBT|. In (a), thermodynamic pressure of a unitary Fermi gas is compared with calculations and other measurements. Figure courtesy of M. Zwierlein [11]. In (b), the collapse of the density measurement at various temperatures (inset) confirms the scaling symmetry. Figure adopted from [12]. Panel (c) shows the three-body loss spectrum in a 6Li133Cs mixture. The geometric progression of the Efimov resonance positions at B = B1, B2 and B3 toward the Feshbach resonance at B0 results from the discrete scaling symmetry of Efimov physics. Figure adopted from [13]. We may expect the same scaling symmetry for a resonantly interacting Bose gas. Here, however, the scaling symmetry is more subtle because of the presence of three-body physics. Predicted by Vitaly Efimov in the context of nuclear physics [14], an infinite number of three-body bound states exist for resonantly interacting bosons and their energies follow a discrete scaling law, breaking the otherwise continuous scaling symmetry. Identical fermions do not form such three-body states due to Pauli's exclusion principle. Theoretically the three-body bound states are supported by the ‘Efimov potential’ V(R)∝ − 1/R2, where R is the characteristic length scale of the three interacting atoms. While the Efimov potential does not break the continuous scaling symmetry, the presence of discrete three-body states does break the symmetry. An alternative picture based on renormalization group limited cycles [15] also explains the discrete scaling symmetry of the system, a scenario that rarely happens in electronic systems. Experimentally, Efimov states have been observed in cold gases of alkali atoms, as well as in helium-4. The geometric scaling symmetry of Efimov states is reported in a recent experiment, shown in Fig. 1(c). The same discrete scaling symmetry is expected for unitary quantum gas of bosons, which, if confirmed, will establish a unique and fascinating class of strongly interacting quantum systems. While in this article, we focus on atoms in optical lattices and unitary atomic gases as primary examples of universal physics that have been actively investigated, efforts in many new research frontiers have shown promising prospects to uncover new universal physics in the strongly correlated and interacting systems. Non-equilibrium dynamics is one of the hottest directions. Ultracold atoms are particularly suited for the study of quantum dynamics due to their slow evolution time scales of miniseconds to seconds. Dynamics near a quantum phase transition and the thermalization of isolated quantum systems are two research topics with many unanswered questions. Cold atom experiments may provide new universal insights that go beyond current theoretical framework. Another exciting direction is quantum many-body systems with long range or very strong interactions. Examples include trapped ions, and condensates of exotic atoms with huge magnetic dipole moments, polar molecules, as well as those with Rydberg excitations. These systems possess various long range interactions. Novel universal dynamics, for example, propagation of information and entanglement, are predicted to depend solely on the asymptotic form of the interaction and the dimension of the systems. The author thanks Yijun Wang for discussion and careful reading of the article. This work was supported by National Science Foundation (PHY-0747907) and Army Research Office-Multiple University Research Initiative (W911NF-14-1-0003).