Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:cond-mat/0309244 · Physical Review Letters

Exact Results for the Thermal and Magnetic Properties of Strong Coupling Ladder Compounds

Murray T. Batchelor, Xi-Wen Guan, N. Oelkers, Kazumitsu Sakai, Zengo Tsuboi, Angela Foerster

Published Nov 19, 2003• 25 citations
arXivHTMLPDF

Abstract

We investigate the thermal and magnetic properties of the integrable $su(4)$ ladder model by means of the quantum transfer matrix method. The magnetic susceptibility, specific heat, magnetic entropy, and high field magnetization are evaluated from the free energy derived via the recently proposed method of high temperature expansion for exactly solved models. We show that the integrable model can be used to describe the physics of the strong coupling ladder compounds. Excellent agreement is seen between the theoretical results and the experimental data for the known ladder compounds $(5\mathrm{I}\mathrm{A}\mathrm{P}{)}_{2}{\mathrm{C}\mathrm{u}\mathrm{B}\mathrm{r}}_{4}\ifmmode\cdot\else\textperiodcentered\fi{}2{\mathrm{H}}_{2}\mathrm{O}$, ${\mathrm{C}\mathrm{u}}_{2}({\mathrm{C}}_{5}{\mathrm{H}}_{12}{\mathrm{N}}_{2}{)}_{2}{\mathrm{C}\mathrm{l}}_{4}$, etc.

DOI
10.1103/physrevlett.91.217202

Related papers

Integrable models and quantum spin ladders: comparison between theory and experiment for the strong coupling ladder compounds

Murray T. Batchelor, X. W. Guan, N. Oelkers +1 more

This article considers recent advances in the investigation of the thermal and magnetic properties of integrable spin ladder models and their applicability to the physics of strong coupling ladder compounds. For this class of compounds the rung coupling J ⊥ is much stronger than the coupling J ∥ along the ladder legs. The ground state properties of the integrable two-leg spin- and the mixed spin-() ladder models at zero temperature are analysed by means of the Thermodynamic Bethe Ansatz (TBA). Solving the TBA equations yields exact results for the critical fields and critical behaviour. The thermal and magnetic properties of the models are discussed in terms of the recently introduced High Temperature Expansion (HTE) method, which is reviewed in detail. In the strong coupling region the integrable spin- ladder model exhibits three quantum phases: (i) a gapped phase in the regime , (ii) a fully polarized phase for , and (iii) a Luttinger liquid magnetic phase in the regime H c1<H<H c2. The critical behaviour in the vicinity of the critical points H c1 and H c2 is of Pokrovsky-Talapov type. The temperature-dependent thermal and magnetic properties are directly evaluated from the exact free energy expression and compared to known experimental results for the strong coupling ladder compounds (5IAP)2CuBr4· 2H2O, Cu2(C5H12N2)2Cl4, (C5H12N)2CuBr4, BIP-BNO and [Cu2(C2\O 2)(C10H8N2)2)](NO3)2. Similar analysis of the mixed spin-() ladder model reveals a rich phase diagram, with a and a full saturation magnetization plateau within the strong antiferromagnetic rung coupling regime. For weak rung coupling, the fractional magnetization plateau is diminished and a new quantum phase transition occurs. The phase diagram can be directly deduced from the magnetization curve obtained from the exact result derived from the TBA and HTE. The results are applied to the mixed ferrimagnetic ladder compound PNNBNO. The thermodynamics of the spin-orbital model with different single-ion anisotropies is also discussed. For this model single-ion anisotropy can trigger different quantum phase transitions within the spin and orbital degrees of freedom, with magnetization plateaux arising from different spin and orbit Landé g-factors.

arXiv:cond-mat/0512489•Advances In Physics•May 1, 2007•63 citations

Thermal and magnetic properties of spin-1 magnetic chain compounds with large single-ion and in-plane anisotropies

Murray T. Batchelor, Xi‐Wen Guan, N. Oelkers

The thermal and magnetic properties of spin-1 magnetic chain compounds with large single-ion and in-plane anisotropies are investigated via the integrable $su(3)$ model in terms of the quantum transfer matrix method and the recently developed high temperature expansion method for exactly solved models. It is shown that large single-ion anisotropy may result in a singlet gapped phase in the spin-$1$ chain which is significantly different from the standard Haldane phase. A large in-plane anisotropy may destroy the gapped phase. On the other hand, in the vicinity of the critical point a weak in-plane anisotropy leads to a different phase transition than the Pokrovsky-Talapov transition. The magnetic susceptibility, specific heat, and magnetization evaluated from the free energy are in excellent agreement with the experimental data for the compounds ${\mathrm{Ni}(\mathrm{C}}_{2}{\mathrm{H}}_{8}{\mathrm{N}}_{2}{)}_{2}\mathrm{Ni}{(\mathrm{CN})}_{4}$ and ${\mathrm{Ni}(\mathrm{C}}_{10}{\mathrm{H}}_{8}{\mathrm{N}}_{2}{)}_{2}\mathrm{Ni}{(\mathrm{CN})}_{4}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{H}}_{2}\mathrm{O}$.

arXiv:cond-mat/0409310•Physical Review B•Nov 5, 2004•18 citations

Note on the thermodynamic Bethe ansatz approach to the quantum phase diagram of the strong coupling ladder compounds

Murray T. Batchelor, Xi‐Wen Guan, Angela Foerster +1 more

We investigate the low-temperature phase diagram of the exactly solved su (4) two-leg spin ladder as a function of the rung coupling and magnetic field H by means of the thermodynamic Bethe ansatz (TBA). In the absence of a magnetic field the model exhibits three quantum phases, while in the presence of a strong magnetic field there is no singlet ground state for ferromagnetic rung coupling. For antiferromagnetic rung coupling, there is a gapped phase in the regime H < H c1 , a fully polarized gapped phase for H > H c2 and a Luttinger liquid magnetic phase in the regime H c1 < H < H c2 . The critical behaviour derived using the TBA is consistent with the existing experimental, numerical and perturbative results for the strong coupling ladder compounds. This includes the spin excitation gap and the critical fields H c1 and H c2 , which are in excellent agreement with the experimental values for the known strong coupling ladder compounds (5IAP) 2 CuBr 4 ·2H 2 O, Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 and (C 5 H 12 N) 2 CuBr 4 . In addition we predict the spin gap for the weak coupling compounds with , such as (VO) 2 P 2 O 7 , and also show that the gap opens for arbitrary .

arXiv:cond-mat/0305633•New Journal of Physics•Aug 11, 2003•12 citations

Thermal and magnetic properties of integrable spin-1 and spin-3/2chains with applications to real compounds

Murray T. Batchelor, X-W Guan, N. Oelkers +1 more

The ground state and thermodynamic properties of spin-1 and spin- chains are investigated via exactly solved su (3) and su (4) models with physically motivated chemical potential terms. The analysis involves the thermodynamic Bethe ansatz and the high temperature expansion (HTE) methods. For the spin-1 chain with large single-ion anisotropy, a gapped phase occurs which is significantly different from the valence-bond-solid Haldane phase. The theoretical curves for the magnetization, susceptibility and specific heat are favourably compared with experimental data for a number of spin-1 chain compounds. For the spin- chain a degenerate gapped phase exists starting at zero external magnetic field. A middle magnetization plateau can be triggered by the single-ion anisotropy term. Overall, our results lend further weight to the applicability of integrable models to the physics of low-dimensional quantum spin systems. They also highlight the utility of the exact HTE method.

arXiv:cond-mat/0409311•Journal of Statistical Mechanics Theory and Experiment•Oct 30, 2004•12 citations

Quantum phase transitions and magnetization of an integrable spin ladder with new parameters in bridging to real compounds

Zu‐Jian Ying, I. Roditi, Huan-Qiang Zhou

We study the field-induced quantum phase transitions (QPT) and the relevant magnetic properties of a spin-1/2 two-leg integrable spin ladder (ISL), of which the system parameters in bridging to the real compounds are determined by setting the extra interactions in the Hamiltonian of the ISL relative to the Heisenberg spin ladder to vanish in the expectation in the ground state (GS). Such an ISL analytically has the correct leading terms of both the critical fields of the two QPT's as in the real strongly-coupled compounds: gμ_BH_{c1}=J_{\perp}-J_{\parallel} and gμ_BH_{c2}=J_{\perp}+2J_{\parallel} in terms of the experimental leg (J_{\parallel}) and rung (J_{\perp}) interactions. The symmetric magnetization inflection point is located at gμ_BH_{IP}=J_{\perp}+J_{\parallel}/2. The magnetizations for the GS and at finite temperatures, as well as the susceptibility, show good agreements in various comparisons with the finite-site exact diagonalization, the transfer-matrix renormalization group numerical result, the perturbation theory, and the compounds (5IAP)_2CuBr_4\cdot 2H_2O, Cu_2(C_5H_{12}N_2)_2Cl_4 and (C_5H_{12}N)_2CuBr_4.

arXiv:cond-mat/0405274•May 13, 2004•0 citations

Magnetic susceptibility of an exactly solvable anisotropic spin ladder system

Arlei Prestes Tonel, Sílvio R. Dahmen, Angela Foerster +1 more

We investigate the thermodynamics of an integrable spin ladder model which possesses a free parameter besides rung and leg couplings. The model is exactly solvable by means of the Bethe ansatz and exhibits a phase transition between a gapped and a gapless spin excitation spectrum. The magnetic susceptibility is obtained numerically and its dependence on the anisotropy parameter is determined. The spin gap obtained from the susceptibility curve and the one obtained from the Bethe ansatz equations are in very good agreement. Our results for the magnetic susceptibility fit well the experimental data for the organometallic compounds (5IAP) 2 CuBr 4 ·2H 2 O (Landee C. P. et al. , Phys. Rev. B , 63 (2001) 100402(R)) Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 (Hayward C. A., Poilblanc D. and Lèvy L. P., Phys. Rev. B , 54 (1996) R12649, Chaboussant G. et al. , Phys. Rev. Lett. , 19 (1997) 925; Phys. Rev. B , 55 (1997) 3046.) and (C 5 H 12 N) 2 CuBr 4 (Watson B. C. et al. , Phys. Rev. Lett. , 86 (2001) 5168) in the strong-coupling regime.

arXiv:cond-mat/0302336•Europhysics Letters (EPL)•Oct 1, 2003•2 citations
We investigate the thermal and magnetic properties of the integrable su(4)su(4)su(4) ladder model by means of the quantum transfer matrix method. The magnetic susceptibility, specific heat, magnetic entropy, and high field magnetization are evaluated from the free energy derived via the recently proposed method of high temperature expansion for exactly solved models. We show that the integrable model can be used to describe the physics of the strong coupling ladder compounds. Excellent agreement is seen between the theoretical results and the experimental data for the known ladder compounds (5IAP)2CuBr4\ifmmode⋅\else\textperiodcentered\fi2H2O(5\mathrm{I}\mathrm{A}\mathrm{P}{)}_{2}{\mathrm{C}\mathrm{u}\mathrm{B}\mathrm{r}}_{4}\ifmmode\cdot\else\textperiodcentered\fi{}2{\mathrm{H}}_{2}\mathrm{O}(5IAP)2​CuBr4​\ifmmode⋅\else\textperiodcentered\fi2H2​O, Cu2(C5H12N2)2Cl4{\mathrm{C}\mathrm{u}}_{2}({\mathrm{C}}_{5}{\mathrm{H}}_{12}{\mathrm{N}}_{2}{)}_{2}{\mathrm{C}\mathrm{l}}_{4}Cu2​(C5​H12​N2​)2​Cl4​, etc.
This article considers recent advances in the investigation of the thermal and magnetic properties of integrable spin ladder models and their applicability to the physics of strong coupling ladder compounds. For this class of compounds the rung coupling J ⊥ is much stronger than the coupling J ∥ along the ladder legs. The ground state properties of the integrable two-leg spin- and the mixed spin-() ladder models at zero temperature are analysed by means of the Thermodynamic Bethe Ansatz (TBA). Solving the TBA equations yields exact results for the critical fields and critical behaviour. The thermal and magnetic properties of the models are discussed in terms of the recently introduced High Temperature Expansion (HTE) method, which is reviewed in detail. In the strong coupling region the integrable spin- ladder model exhibits three quantum phases: (i) a gapped phase in the regime , (ii) a fully polarized phase for , and (iii) a Luttinger liquid magnetic phase in the regime H c1<H<H c2. The critical behaviour in the vicinity of the critical points H c1 and H c2 is of Pokrovsky-Talapov type. The temperature-dependent thermal and magnetic properties are directly evaluated from the exact free energy expression and compared to known experimental results for the strong coupling ladder compounds (5IAP)2CuBr4· 2H2O, Cu2(C5H12N2)2Cl4, (C5H12N)2CuBr4, BIP-BNO and [Cu2(C2\O 2)(C10H8N2)2)](NO3)2. Similar analysis of the mixed spin-() ladder model reveals a rich phase diagram, with a and a full saturation magnetization plateau within the strong antiferromagnetic rung coupling regime. For weak rung coupling, the fractional magnetization plateau is diminished and a new quantum phase transition occurs. The phase diagram can be directly deduced from the magnetization curve obtained from the exact result derived from the TBA and HTE. The results are applied to the mixed ferrimagnetic ladder compound PNNBNO. The thermodynamics of the spin-orbital model with different single-ion anisotropies is also discussed. For this model single-ion anisotropy can trigger different quantum phase transitions within the spin and orbital degrees of freedom, with magnetization plateaux arising from different spin and orbit Landé g-factors.
The thermal and magnetic properties of spin-1 magnetic chain compounds with large single-ion and in-plane anisotropies are investigated via the integrable su(3)su(3)su(3) model in terms of the quantum transfer matrix method and the recently developed high temperature expansion method for exactly solved models. It is shown that large single-ion anisotropy may result in a singlet gapped phase in the spin-111 chain which is significantly different from the standard Haldane phase. A large in-plane anisotropy may destroy the gapped phase. On the other hand, in the vicinity of the critical point a weak in-plane anisotropy leads to a different phase transition than the Pokrovsky-Talapov transition. The magnetic susceptibility, specific heat, and magnetization evaluated from the free energy are in excellent agreement with the experimental data for the compounds Ni(C2H8N2)2Ni(CN)4{\mathrm{Ni}(\mathrm{C}}_{2}{\mathrm{H}}_{8}{\mathrm{N}}_{2}{)}_{2}\mathrm{Ni}{(\mathrm{CN})}_{4}Ni(C2​H8​N2​)2​Ni(CN)4​ and ${\mathrm{Ni}(\mathrm{C}}_{10}{\mathrm{H}}_{8}{\mathrm{N}}_{2}{)}_{2}\mathrm{Ni}{(\mathrm{CN})}_{4}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{H}}_{2}\mathrm{O}$.
We investigate the low-temperature phase diagram of the exactly solved su (4) two-leg spin ladder as a function of the rung coupling and magnetic field H by means of the thermodynamic Bethe ansatz (TBA). In the absence of a magnetic field the model exhibits three quantum phases, while in the presence of a strong magnetic field there is no singlet ground state for ferromagnetic rung coupling. For antiferromagnetic rung coupling, there is a gapped phase in the regime H < H c1 , a fully polarized gapped phase for H > H c2 and a Luttinger liquid magnetic phase in the regime H c1 < H < H c2 . The critical behaviour derived using the TBA is consistent with the existing experimental, numerical and perturbative results for the strong coupling ladder compounds. This includes the spin excitation gap and the critical fields H c1 and H c2 , which are in excellent agreement with the experimental values for the known strong coupling ladder compounds (5IAP) 2 CuBr 4 ·2H 2 O, Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 and (C 5 H 12 N) 2 CuBr 4 . In addition we predict the spin gap for the weak coupling compounds with , such as (VO) 2 P 2 O 7 , and also show that the gap opens for arbitrary .
The ground state and thermodynamic properties of spin-1 and spin- chains are investigated via exactly solved su (3) and su (4) models with physically motivated chemical potential terms. The analysis involves the thermodynamic Bethe ansatz and the high temperature expansion (HTE) methods. For the spin-1 chain with large single-ion anisotropy, a gapped phase occurs which is significantly different from the valence-bond-solid Haldane phase. The theoretical curves for the magnetization, susceptibility and specific heat are favourably compared with experimental data for a number of spin-1 chain compounds. For the spin- chain a degenerate gapped phase exists starting at zero external magnetic field. A middle magnetization plateau can be triggered by the single-ion anisotropy term. Overall, our results lend further weight to the applicability of integrable models to the physics of low-dimensional quantum spin systems. They also highlight the utility of the exact HTE method.
We study the field-induced quantum phase transitions (QPT) and the relevant magnetic properties of a spin-1/2 two-leg integrable spin ladder (ISL), of which the system parameters in bridging to the real compounds are determined by setting the extra interactions in the Hamiltonian of the ISL relative to the Heisenberg spin ladder to vanish in the expectation in the ground state (GS). Such an ISL analytically has the correct leading terms of both the critical fields of the two QPT's as in the real strongly-coupled compounds: gμ_BH_{c1}=J_{\perp}-J_{\parallel} and gμ_BH_{c2}=J_{\perp}+2J_{\parallel} in terms of the experimental leg (J_{\parallel}) and rung (J_{\perp}) interactions. The symmetric magnetization inflection point is located at gμ_BH_{IP}=J_{\perp}+J_{\parallel}/2. The magnetizations for the GS and at finite temperatures, as well as the susceptibility, show good agreements in various comparisons with the finite-site exact diagonalization, the transfer-matrix renormalization group numerical result, the perturbation theory, and the compounds (5IAP)_2CuBr_4\cdot 2H_2O, Cu_2(C_5H_{12}N_2)_2Cl_4 and (C_5H_{12}N)_2CuBr_4.
We investigate the thermodynamics of an integrable spin ladder model which possesses a free parameter besides rung and leg couplings. The model is exactly solvable by means of the Bethe ansatz and exhibits a phase transition between a gapped and a gapless spin excitation spectrum. The magnetic susceptibility is obtained numerically and its dependence on the anisotropy parameter is determined. The spin gap obtained from the susceptibility curve and the one obtained from the Bethe ansatz equations are in very good agreement. Our results for the magnetic susceptibility fit well the experimental data for the organometallic compounds (5IAP) 2 CuBr 4 ·2H 2 O (Landee C. P. et al. , Phys. Rev. B , 63 (2001) 100402(R)) Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 (Hayward C. A., Poilblanc D. and Lèvy L. P., Phys. Rev. B , 54 (1996) R12649, Chaboussant G. et al. , Phys. Rev. Lett. , 19 (1997) 925; Phys. Rev. B , 55 (1997) 3046.) and (C 5 H 12 N) 2 CuBr 4 (Watson B. C. et al. , Phys. Rev. Lett. , 86 (2001) 5168) in the strong-coupling regime.