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arXiv:cond-mat/0304095

Kinetic Theory of a Spin-1/2 Bose-Condensed Gas

Tetsuro Nikuni, JAMES E. JUN. WILLIAMS

Published Apr 4, 2003• 1 citation
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Abstract

We derive a kinetic theory for a spin-1/2 Bose-condensed gas of two-level atoms at finite temperatures. The condensate dynamics is described by a generalized Gross-Pitaevskii equation for the two-component spinor order parameter, which includes the interaction with the uncondensed fraction. The noncondensate atoms are described by a quantum kinetic equation, which is a generalization of the spin kinetic equation for spin-polarized quantum gases to include couplings to the condensate degree of freedom. The kinetic equation is used to derive hydrodynamic equations for the noncondensate spin density. The condensate and noncondensate spins are coupled directly through the exchange mean field. Collisions between the condensate and noncondensate atoms give rise to an additional contribution to the spin diffusion relaxation rate. In addition, they give rise to mutual relaxation of the condensate and noncondensate due to lack of local equilibrium between the two components.

DOI
10.48550/arxiv.cond-mat/0304095

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We derive a kinetic theory for a spin-1/2 Bose-condensed gas of two-level atoms at finite temperatures. The condensate dynamics is described by a generalized Gross-Pitaevskii equation for the two-component spinor order parameter, which includes the interaction with the uncondensed fraction. The noncondensate atoms are described by a quantum kinetic equation, which is a generalization of the spin kinetic equation for spin-polarized quantum gases to include couplings to the condensate degree of freedom. The kinetic equation is used to derive hydrodynamic equations for the noncondensate spin density. The condensate and noncondensate spins are coupled directly through the exchange mean field. Collisions between the condensate and noncondensate atoms give rise to an additional contribution to the spin diffusion relaxation rate. In addition, they give rise to mutual relaxation of the condensate and noncondensate due to lack of local equilibrium between the two components.
We derive a kinetic theory for a spin-1/2 Bose-condensed gas of two-level atoms at finite temperatures. The condensate dynamics is described by a generalized Gross–Pitaevskii equation for the two-component spinor order parameter, which includes the interaction with the uncondensed fraction. The noncondensate atoms are described by a quantum kinetic equation, which is a generalization of the spin kinetic equation for spin-polarized quantum gases to include couplings to the condensate degree of freedom. The kinetic equation is used to derive hydrodynamic equations for the noncondensate spin density. The condensate and noncondensate spins are coupled directly through the exchange mean field. Collisions between the condensate and noncondensate atoms give rise to an additional contribution to the spin diffusion relaxation rate. In addition, they give rise to mutual relaxation of the condensate and noncondensate due to lack of local equilibrium between the two components.
We derive a nonequilibrium finite-temperature kinetic theory for a binary mixture of two interacting atomic Bose-Einstein condensates and use it to explore the degree of hydrodynamicity attainable in realistic experimental geometries. Based on the standard separation-of-time-scales argument of kinetic theory, the dynamics of the condensates of the multicomponent system are shown to be described by dissipative Gross-Pitaevskii equations self-consistently coupled to corresponding quantum Boltzmann equations for the noncondensate atoms: On top of the usual mean-field contributions, our scheme identifies a total of eight distinct collisional processes, whose dynamical interplay is expected to be responsible for the system's equilibration. In order to provide their first characterization, we perform a detailed numerical analysis of the role of trap frequency and geometry on collisional rates for experimentally accessible mixtures of $^{87}\mathrm{Rb}\ensuremath{-}^{41}\mathrm{K}$ and $^{87}\mathrm{Rb}\ensuremath{-}^{85}\mathrm{Rb}$, discussing the extent to which the system may approach the hydrodynamic regime with regard to some of those processes as a guide for future experimental investigations of ultracold Bose gas mixtures.
We extend our recent work on the two-fluid hydrodynamics of a Bose-condensed gas by including collisions involving both condensate and noncondensate atoms. These collisions are essential for establishing a state of local thermodynamic equilibrium between the condensate and noncondensate. Our theory is more general than the usual Landau two-fluid theory, to which it reduces in the appropriate limit, in that it allows one to describe situations in which a state of complete local equilibrium between the two components has not been reached. The exchange of atoms between the condensate and noncondensate is associated with a new relaxational mode of the gas.
In contrast with Chapter 2, in this chapter we include the dynamics of the thermal cloud. As noted in Chapter 1, we treat the noncondensate atoms using the simplest microscopic model approximation that captures the important physics. In particular, we consider only temperatures high enough ( T ≥ 0.4 T BEC ) that the noncondensate atoms can be described by a particle-like Hartree–Fock (HF) spectrum. To extend the analysis to very low temperatures is in principle straightforward (see Chapter 7). However, the details are more complicated since the excitations of the thermal cloud take on a collective aspect (i.e. a Bogoliubov-type quasiparticle spectrum must be used). In trapped Bose gases, the HF single-particle spectrum gives a good approximation down to much lower temperatures than in the case of uniform Bose gases, as first emphasized by Giorgini et al . (1997). In Section 3.1, we derive a generalized form of the Gross–Pitaevskii equation for the Bose order parameter Φ( r , t ) that is valid at finite temperatures. It involves terms that are coupled to the noncondensate component (the thermal cloud) and thus its solution in general requires one to know the equations of motion for the dynamics of the noncondensate atoms. In Section 3.2 we restrict ourselves to finite temperatures high enough that the noncondensate atoms can be described by a quantum kinetic equation for the single-particle distribution function f ( p, r , t ). A detailed microscopic derivation of this kind of kinetic equation is given in Chapters 6 and 7 using the Kadanoff–Baym Green's function formalism. A characteristic feature of a Bose-condensed gas is that the kinetic equation governing f ( p, r , t ) involves a collision integral C 12 [ f , Φ] describing collisions between condensate and noncondensate atoms.
We calculate the frequencies and damping rates of the low-lying collective modes of a Bose-Einstein condensed gas at nonzero temperature. We use a complex nonlinear Schr\"odinger equation to determine the dynamics of the condensate atoms, and couple it to a Boltzmann equation for the noncondensate atoms. In this manner we take into account both collisions between noncondensate-noncondensate and condensate-noncondensate atoms. We solve the linear response of these equations, using a time-dependent Gaussian trial function for the condensate wave function and a truncated power expansion for the deviation function of the thermal cloud. As a result, our calculation turns out to be characterized by two dimensionless parameters proportional to the noncondensate-noncondensate and condensate-noncondensate mean collision times. We find in general quite good agreement with experiment, both for the frequencies and damping of the collective modes.
Starting from the quantum kinetic equation for the noncondensate atoms and the generalized Gross--Pitaevskii equation for the condensate, we derive the two-fluid hydrodynamic equations of a trapped Bose gas at finite temperatures. We follow the standard Chapman--Enskog procedure, starting from a solution of the kinetic equation corresponding to the complete local equilibrium between the condensate and the noncondensate components. Our hydrodynamic equations are shown to reduce to a form identical to the well-known Landau-Khalatnikov two-fluid equations, with hydrodynamic damping due to the deviation from local equilibrium. The deviation from local equilibrium within the thermal cloud gives rise to dissipation associated with shear viscosity and thermal conduction. In addition, we show that effects due to the deviation from the diffusive local equilibrium between the condensate and the noncondensate (recently considered by Zaremba, Nikuni, and Griffin) can be described by four frequency-dependent second viscosity transport coefficients. We also derive explicit formulas for all the transport coefficients. These results are used to introduce two new characteristic relaxation times associated with hydrodynamic damping. These relaxation times give the rate at which local equilibrium is reached and hence determine whether one is in the two-fluid hydrodynamic region.