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arXiv:cond-mat/0205327

Dynamic phase transitions in diffusion-limited reactions

Uwe Claus Täuber

Published May 15, 2002• 3 citations
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Abstract

Many non-equilibrium systems display dynamic phase transitions from active to absorbing states, where fluctuations cease entirely. Based on a field theory representation of the master equation, the critical behavior can be analyzed by means of the renormalization group. The resulting universality classes for single-species systems are reviewed here. Generically, the critical exponents are those of directed percolation (Reggeon field theory), with critical dimension d_c = 4. Yet local particle number parity conservation in even-offspring branching and annihilating random walks implies an inactive phase (emerging below d_c' = 4/3) that is characterized by the power laws of the pair annihilation reaction, and leads to different critical exponents at the transition. For local processes without memory, the pair contact process with diffusion represents the only other non-trivial universality class. The consistent treatment of restricted site occupations and quenched random reaction rates are important open issues.

DOI
10.48550/arxiv.cond-mat/0205327

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Many non-equilibrium systems display dynamic phase transitions from active to absorbing states, where fluctuations cease entirely. Based on a field theory representation of the master equation, the critical behavior can be analyzed by means of the renormalization group. The resulting universality classes for single-species systems are reviewed here. Generically, the critical exponents are those of directed percolation (Reggeon field theory), with critical dimension d_c = 4. Yet local particle number parity conservation in even-offspring branching and annihilating random walks implies an inactive phase (emerging below d_c' = 4/3) that is characterized by the power laws of the pair annihilation reaction, and leads to different critical exponents at the transition. For local processes without memory, the pair contact process with diffusion represents the only other non-trivial universality class. The consistent treatment of restricted site occupations and quenched random reaction rates are important open issues.
Phase transitions from an active into an absorbing, inactive state are generically described by the critical exponents of directed percolation (DP), with upper critical dimension dc=4{d}_{c}=4dc​=4. In the framework of single-species reaction-diffusion systems, this universality class is realized by the combined processes $\stackrel{\ensuremath{\rightarrow}}{A}A+A,$ $A+\stackrel{\ensuremath{\rightarrow}}{A}A$, and $\stackrel{\ensuremath{\rightarrow}}{A}0$. We study a hierarchy of such DP processes for particle species A,B,…A,B,\dots{}A,B,…, unidirectionally coupled via the reactions $\stackrel{\ensuremath{\rightarrow}}{A}B,\dots{}$ (with rates ${\ensuremath{\mu}}_{\mathrm{AB}},\dots{})$. When the DP critical points at all levels coincide, multicritical behavior emerges, with density exponents ${\ensuremath{\beta}}_{i}$ which are markedly reduced at each hierarchy level i> 2i>~2i> 2. This scenario can be understood on the basis of the mean-field rate equations, which yield ${\ensuremath{\beta}}_{i}{=1/2}^{i\ensuremath{-}1}$ at the multicritical point. Using field-theoretic renormalization-group techniques in $d=4\ensuremath{-}\ensuremath{\epsilon}$ dimensions, we identify a new crossover exponent $\ensuremath{\varphi}$, and compute $\ensuremath{\varphi}=1+O({\ensuremath{\epsilon}}^{2})$ in the multicritical regime (for small ${\ensuremath{\mu}}_{\mathrm{AB}})$ of the second hierarchy level. In the active phase, we calculate the fluctuation correction to the density exponent on the second hierarchy level, ${\ensuremath{\beta}}_{2}=1/2\ensuremath{-}\ensuremath{\epsilon}/8+O({\ensuremath{\epsilon}}^{2})$. Outside the multicritial region, we discuss the crossover to ordinary DP behavior, with the density exponent ${\ensuremath{\beta}}_{1}=1\ensuremath{-}\ensuremath{\epsilon}/6+O({\ensuremath{\epsilon}}^{2})$. Monte Carlo simulations are then employed to confirm the crossover scenario, and to determine the values for the new scaling exponents in dimensions d< 3d<~3d< 3, including the critical initial slip exponent. Our theory is connected to specific classes of growth processes and to certain cellular automata, and the above ideas are also applied to unidirectionally coupled pair annihilation processes. We also discuss some technical as well as conceptual problems of the loop expansion, and suggest some possible interpretations of these difficulties.
It is explained how field-theoretic methods and the dynamic renormalisation group (RG) can be applied to study the universal scaling properties of systems that either undergo a continuous phase transition or display generic scale invariance, both near and far from thermal equilibrium. Part 1 introduces the response functional field theory representation of (nonlinear) Langevin equations. The RG is employed to compute the scaling exponents for several universality classes governing the critical dynamics near second-order phase transitions in equilibrium. The effects of reversible mode-coupling terms, quenching from random initial conditions to the critical point, and violating the detailed balance constraints are briefly discussed. It is shown how the same formalism can be applied to nonequilibrium systems such as driven diffusive lattice gases. Part 2 describes how the master equation for stochastic particle reaction processes can be mapped onto a field theory action. The RG is then used to analyse simple diffusion-limited annihilation reactions as well as generic continuous transitions from active to inactive, absorbing states, which
The steady-state phase diagram of the one-dimensional reaction-diffusion model $2\stackrel{\ensuremath{\rightarrow}}{A}3A,$ $2\stackrel{\ensuremath{\rightarrow}}{A}0$ is studied through the non-Hermitian density matrix renormalization group. In the absence of single-particle diffusion the model reduces to the pair-contact process, which has a phase transition in the universality class of directed percolation (DP) and an infinite number of absorbing steady states. When single-particle diffusion is added, the number of absorbing steady states is reduced to 2 and the model no longer shows DP critical behavior. The exponents $\ensuremath{\theta}={\ensuremath{\nu}}_{\ensuremath{\Vert}}/{\ensuremath{\nu}}_{\ensuremath{\perp}}$ and $\ensuremath{\beta}/{\ensuremath{\nu}}_{\ensuremath{\perp}}$ are calculated numerically. The value of $\ensuremath{\beta}/{\ensuremath{\nu}}_{\ensuremath{\perp}}$ is close to the value of the parity conserving universality class, in spite of the absence of local conservation laws.
We review the field theory approach to percolation processes. Specifically, we focus on the so-called simple and general epidemic processes that display continuous nonequilibrium active to absorbing state phase transitions whose asymptotic features are governed respectively by the directed (DP) and dynamic isotropic percolation (dIP) universality classes. We discuss the construction of a field theory representation for these Markovian stochastic processes based on fundamental phenomenological considerations, as well as from a specific microscopic reaction-diffusion model realization. Subsequently we explain how dynamic renormalization group (RG) methods can be applied to obtain the universal properties near the critical point in an expansion about the upper critical dimensions dc = 4 (DP) and 6 (dIP). We provide a detailed overview of results for critical exponents, scaling functions, crossover phenomena, finite-size scaling, and also briefly comment on the influence of long-range spreading, the presence of a boundary, multispecies generalizations, coupling of the order parameter to other conserved modes, and quenched disorder. Key words: Percolation, epidemic processes, directed percolation, dynamic isotropic percolation, active to absorbing phase transitions, renormalization group theory, dynamic critical phenomena, crossover
We generalize nonperturbative renormalization group methods to nonequilibrium critical phenomena. Within this formalism, reaction-diffusion processes are described by a scale-dependent effective action, the flow of which is derived. We investigate branching and annihilating random walks with an odd number of offspring. Along with recovering their universal physics (described by the directed percolation universality class), we determine their phase diagrams and predict that a transition occurs even in three dimensions, contrarily to what perturbation theory suggests.
We review the critical behavior of nonequilibrium systems, such as directed percolation (DP) and branching-annihilating random walks (BARW), which possess phase transitions into absorbing states. After reviewing the bulk scaling behavior of these models, we devote the main part of this review to analyzing the impact of walls on their critical behavior. We discuss the possible boundary universality classes for the DP and BARW models, which can be described by a general scaling theory which allows for two independent surface exponents in addition to the bulk critical exponents. Above the upper critical dimension d c , we review the use of mean field theories, whereas in the regime d<d c , where fluctuations are important, we examine the application of field theoretic methods. Of particular interest is the situation in d=1, which has been extensively investigated using numerical simulations and series expansions. Although DP and BARW fit into the same scaling theory, they can still show very different surface behavior: for DP some exponents are degenerate, a property not shared with the BARW model. Moreover, a "hidden" duality symmetry of BARW in d=1 is broken by the boundary and this relates exponents and boundary conditions in an intricate way.