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arXiv:cond-mat/0003331 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Critical light scattering in liquids

G. Flossmann, R. Folk

Published Aug 1, 2000• 9 citations
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Abstract

We compare theoretical results for the characteristic frequency of the Rayleigh peak calculated in one-loop order within the field theoretical method of the renormalization group theory with experiments and other theoretical results. Our expressions describe the nonasymptotic crossover in temperature, density, and wave vector. In addition we discuss the frequency dependent shear viscosity evaluated within the same model and compare our theoretical results with recent experiments in microgravity.

DOI
10.1103/physreve.62.2460

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We compare theoretical results for the characteristic frequency of the Rayleigh peak calculated in one-loop order within the field theoretical method of the renormalization group theory with experiments and other theoretical results. Our expressions describe the nonasymptotic crossover in temperature, density, and wave vector. In addition we discuss the frequency dependent shear viscosity evaluated within the same model and compare our theoretical results with recent experiments in microgravity.
We extend our previous determinations of nonasymptotic critical behavior of Phys. Rev. B 32, 7209 (1985) and 35, 3585 (1987) to accurate expressions of the complete classical-to-critical crossover (in three-dimensional field theory) in terms of the temperaturelike scaling field (i.e., along the critical isochore) for (1) the correlation length, the susceptibility, and the specific heat in the homogeneous phase for the n-vector model (n=1 to 3) and (2) the spontaneous magnetization (coexistence curve), the susceptibility, and the specific heat in the inhomogeneous phase for the Ising model (n=1). The present calculations include the seventh-loop order of Murray and Nickel and closely account for the up-to-date estimates of universal asymptotic critical quantities (exponents and amplitude combinations) provided by Guida and Zinn-Justin [J. Phys. A 31, 8103 (1998)].
We review the progress made in dynamic bulk critical behaviour in equilibrium in the last 25 years since the review of Halperin and Hohenberg. We unify the presentation of the theoretical background by restricting ourselves to the field-theoretic renormalization group method. The main results obtained in the different universality classes are presented. This contains the critical dynamics near the gas–liquid transition in pure fluids (model H), the plait point and consolute point in mixtures (model H � ), the superfluid transition in 4 He (model F) and 4 He– 3 He mixtures (model F � ), the Curie point (model J) and Neel point (model G) in Heisenberg magnets and the superconducting transition. In comparison with experimental results, it became clear that in most cases one has to consider apart from the universal asymptotic critical behaviour also the non-universal effective behaviour. Either because it turned out to be inevitable due to a small dynamical transient exponent inhibiting the system to reach the asymptotics (e.g., at the superfluid transition) or because one is interested in the region further away from the phase transition like in pure fluids and mixtures at their gas–liquid or demixing transition. The calculation of the critical dynamics is adequate in most cases only in two-loop order. We review these results and present the solution to unreasonable features found for some models. Thus, we consider model C where relaxational and diffusive dynamics are coupled and the scaling properties and the limit to a purely relaxational model (model A) have not been understood. In general for models where the order parameter couples to other conserved densities time scale ratios between the kinetic coefficients of the order parameter and the conserved densities play an important role. Their fixed-point values and the approach to the fixed point are changed considerably in two-loop order compared to their values in one-loop order. These considerations are relevant for the explanation of the dynamical critical shape functions of systems such as superfluid helium (model F) and the isotropic antiferromagnet (model G). As far as possible, the comparison of results obtained by the renormalization group theory with numerical simulations has been made.
The temperature (T)(T)(T) and frequency $(\ensuremath{\omega})$ dependent conductivity of weakly disordered Luttinger liquids is calculated in a systematic way both by perturbation theory and from a finite temperature renormalization group (RG) treatment to leading order in the disorder strength. Whereas perturbation theory results in $\ensuremath{\omega}∕T$ scaling of the conductivity, such scaling is violated in the RG treatment. We also determine the nonlinear field dependence of the conductivity, whose power law scaling is different from that of temperature and frequency dependence.
Eighty years ago Eyring proposed that the shear viscosity of a liquid, ηηη, has a quantum limit η≳nℏη\gtrsim n\hbarη≳nℏ where nnn is the density of the fluid. Using holographic duality and the AdS/CFT correspondence in string theory Kovtun, Son, and Starinets (KSS) conjectured a universal bound ηs≥ℏ4πkB\fracη{s}\geq \frac{\hbar}{4πk_{B}}sη​≥4πkB​ℏ​ for the ratio between the shear viscosity and the entropy density, sss. Using Dynamical Mean-Field Theory (DMFT) we calculate the shear viscosity and entropy density for a fermionic fluid described by a single band Hubbard model at half filling. Our calculated shear viscosity as a function of temperature is compared with experimental data for liquid 3^{3}3He. At low temperature the shear viscosity is found to be well above the quantum limit and is proportional to the characteristic Fermi liquid 1/T21/T^{2}1/T2 dependence, where TTT is the temperature. With increasing temperature and interaction strength UUU there is significant deviation from the Fermi liquid form. Also, the shear viscosity violates the quantum limit near the crossover from coherent quasi-particle based transport to incoherent transport (the bad metal regime). Finally, the ratio of the shear viscosity to the entropy density is found to be comparable to the KSS bound for parameters appropriate to liquid 3^{3}3He. However, this bound is found to be strongly violated in the bad metal regime for parameters appropriate to lattice electronic systems such as organic charge transfer salts.
Abstract The approaches described so far in this book have given a broad phenomenological understanding of critical phenomena. However, although a substantial framework of results and connections has been built up, we have, as yet, no explanations for the following: What is needed is a theory, based on the physics of what is happening at the critical point. we argued in Chapter 1 that the special feature of criticality is that the correlation length is infinite and that the critical system is invariant on all length scales. The aim is to write down a (hopefully short, elegant, and comprehensible) mathematical theory which embodies this physics and explains all the observations listed above. A useful theory will also allow the calculation of critical exponents and transition temperatures, if not exactly, then within an accurate and well-controlled approximation scheme.