We review the progress made in dynamic bulk critical behaviour in equilibrium in the last 25 years since the review of Halperin and Hohenberg. We unify the presentation of the theoretical background by restricting ourselves to the field-theoretic renormalization group method. The main results obtained in the different universality classes are presented. This contains the critical dynamics near the gas–liquid transition in pure fluids (model H), the plait point and consolute point in mixtures (model H � ), the superfluid transition in 4 He (model F) and 4 He– 3 He mixtures (model F � ), the Curie point (model J) and Neel point (model G) in Heisenberg magnets and the superconducting transition. In comparison with experimental results, it became clear that in most cases one has to consider apart from the universal asymptotic critical behaviour also the non-universal effective behaviour. Either because it turned out to be inevitable due to a small dynamical transient exponent inhibiting the system to reach the asymptotics (e.g., at the superfluid transition) or because one is interested in the region further away from the phase transition like in pure fluids and mixtures at their gas–liquid or demixing transition. The calculation of the critical dynamics is adequate in most cases only in two-loop order. We review these results and present the solution to unreasonable features found for some models. Thus, we consider model C where relaxational and diffusive dynamics are coupled and the scaling properties and the limit to a purely relaxational model (model A) have not been understood. In general for models where the order parameter couples to other conserved densities time scale ratios between the kinetic coefficients of the order parameter and the conserved densities play an important role. Their fixed-point values and the approach to the fixed point are changed considerably in two-loop order compared to their values in one-loop order. These considerations are relevant for the explanation of the dynamical critical shape functions of systems such as superfluid helium (model F) and the isotropic antiferromagnet (model G). As far as possible, the comparison of results obtained by the renormalization group theory with numerical simulations has been made.
We review the progress made in dynamic bulk critical behaviour in equilibrium in the last 25 years since the review of Halperin and Hohenberg. We unify the presentation of the theoretical background by restricting ourselves to the field-theoretic renormalization group method. The main results obtained in the different universality classes are presented. This contains the critical dynamics near the gas–liquid transition in pure fluids (model H), the plait point and consolute point in mixtures (model H � ), the superfluid transition in 4 He (model F) and 4 He– 3 He mixtures (model F � ), the Curie point (model J) and Neel point (model G) in Heisenberg magnets and the superconducting transition. In comparison with experimental results, it became clear that in most cases one has to consider apart from the universal asymptotic critical behaviour also the non-universal effective behaviour. Either because it turned out to be inevitable due to a small dynamical transient exponent inhibiting the system to reach the asymptotics (e.g., at the superfluid transition) or because one is interested in the region further away from the phase transition like in pure fluids and mixtures at their gas–liquid or demixing transition. The calculation of the critical dynamics is adequate in most cases only in two-loop order. We review these results and present the solution to unreasonable features found for some models. Thus, we consider model C where relaxational and diffusive dynamics are coupled and the scaling properties and the limit to a purely relaxational model (model A) have not been understood. In general for models where the order parameter couples to other conserved densities time scale ratios between the kinetic coefficients of the order parameter and the conserved densities play an important role. Their fixed-point values and the approach to the fixed point are changed considerably in two-loop order compared to their values in one-loop order. These considerations are relevant for the explanation of the dynamical critical shape functions of systems such as superfluid helium (model F) and the isotropic antiferromagnet (model G). As far as possible, the comparison of results obtained by the renormalization group theory with numerical simulations has been made.
We now begin our exposition of universal dynamic scaling behavior that emerges under non-equilibrium conditions. We are mainly concerned with the relaxational models A and B here, but also touch on other dynamic universality classes. First, we consider non-equilibrium critical relaxation from a disordered initial state, and compute the associated universal scaling exponents within the dynamic renormalization group framework. Related phenomena in the early-time regime, prior to reaching temporally translationally invariant asymptotics, are ‘aging’ and a non-equilibrium fluctuation-dissipation ratio, both of which have enjoyed prominence in the literature on ‘glassy’ kinetics. In this context, we derive the critical initial slip exponent for the order parameter, and briefly discuss interesting persistence properties. Second, we explore the long-time scaling laws in phase ordering kinetics and coarsening for the relaxational models, following a fast temperature ‘quench’ into the ordered phase, in systems with either non-conserved or conserved order parameters. Aside from a few explicit computations in the spherical model limit (wherein the number of order parameter components n → ∞), we largely employ phenomenological considerations and scaling theory, stressing the importance of topological defects for energy dissipation during coarsening. Next we address the question how violations of Einstein's relation that links relaxation coefficients and noise correlations might affect the asymptotic dynamic critical scaling behavior. Whereas in systems with non-conserved order parameter typically the equilibrium scaling laws are recovered in the vicinity of the critical point, in contrast genuinely novel universality classes may emerge in the case of a conserved parameter, provided it is driven out of equilibrium in a spatially anisotropic fashion.
Equipped with the field theory representation of non-linear Langevin equations, the tools of dynamic perturbation theory, and the dynamic renormalization group introduced in Chapters 4 and 5, we are now in the position to revisit models for dynamic critical behavior that entail reversible mode couplings and other conserved hydrodynamic modes. We have already encountered some of these in Section 3.3. In models C and D, respectively, a non-conserved or conserved n -component order parameter is coupled to a conserved scalar field, the energy density. Through a systematic renormalization group analysis, we may critically assess the earlier predictions from scaling theory, and discuss the stability of fixed points characterized by strong dynamic scaling, wherein the order parameter and conserved non-critical mode fluctuate with equal rates, and weak dynamic scaling regimes, where these characteristic time scales differ. Next we investigate isotropic ferromagnets (model J), with the conserved spin density subject to reversible precession in addition to diffusive relaxation. Exploiting rotational invariance, we can now firmly establish the scaling relation z = ( d + 2 − η )/2. Similar symmetry arguments yield a scaling relation for the dynamic exponents associated with the order parameter and the non-critical fields in the O ( n )-symmetric SSS model that encompasses model E for planar ferromagnets and superfluid helium 4 (for n = 2), and model G for isotropic antiferromagnets ( n = 3). There exist competing strong- and weak-scaling fixed points, with the former stable to one-loop order, and characterized by z = d /2 for all slow modes.
Originally, the term ‘dynamic critical phenomena’ was coined for time-dependent properties near second-order phase transitions in thermal equilibrium . The kinetics of phase transitions in magnets, at the gas–liquid transition, and at the normal- to superfluid phase transition in helium 4 were among the prominent examples investigated already in the 1960s. The dynamic scaling hypothesis , generalizing the scaling ansatz for the static correlation function and introducing an additional dynamic critical exponent, successfully described a variety of these experiments. Yet only the development of the systematic renormalization group (RG) approach for critical phenomena in the subsequent decade provided a solid conceptual foundation for phenomenological scaling theories. Supplemented with exact solutions for certain idealized model systems, and guided by invaluable input from computer simulations in addition to experimental data, the renormalization group now provides a general framework to explore not only the static and dynamic properties near a critical point, but also the large-scale and low-frequency response in stable thermodynamic phases. Scaling concepts and the renormalization group have also been successfully applied to phase transitions at zero temperature driven by quantum rather than thermal fluctuations. It is to be hoped that RG methods may help to classify the strikingly rich phenomena encountered in far-from-equilibrium systems as well. Recent advances in studies of simple reaction-diffusion systems, active to absorbing state phase transitions, driven lattice gases, and scaling properties of moving interfaces and growing surfaces, among others, appear promising in this respect.
In the past few years systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this ever-lasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put to the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation-dissipation relations are discussed and in particular the concept of fluctuation-dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The Renormalization-Group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular the results for Model A, B, and C dynamics of the O(N) Ginzburg-Landau Hamiltonian, and Model A dynamics of the weakly dilute Ising magnet and of a \phi^3 theory, are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of Model A dynamics is also addressed within the mean-field approximation.
In the past few years, systems with slow dynamics have attracted considerable theoretical and experimental interest. Ageing phenomena are observed during this everlasting non-equilibrium evolution. A simple instance of such a behaviour is provided by the dynamics that takes place when a system is quenched from its high-temperature phase to the critical point. The aim of this review is to summarize the various numerical and analytical results that have been recently obtained for this case. Particular emphasis is put on the field-theoretical methods that can be used to provide analytical predictions for the relevant dynamical quantities. Fluctuation–dissipation relations are discussed and in particular the concept of fluctuation–dissipation ratio (FDR) is reviewed, emphasizing its connection with the definition of a possible effective temperature. The renormalization-group approach to critical dynamics is summarized and the scaling forms of the time-dependent non-equilibrium correlation and response functions of a generic observable are discussed. From them, the universality of the associated FDR follows as an amplitude ratio. It is then possible to provide predictions for ageing quantities in a variety of different models. In particular, the results for models A, B and C dynamics of the O ( N ) Ginzburg–Landau Hamiltonian, and model A dynamics of the weakly dilute Ising magnet and of the φ 3 theory are reviewed and compared with the available numerical results and exact solutions. The effect of a planar surface on the ageing behaviour of model A dynamics is also addressed within the mean-field approximation.
This article concludes a series of papers [Folk, Holovatch, and Moser, Phys. Rev. E 78, 041124 (2008); 78, 041125 (2008); 79, 031109 (2009)] where the tools of the field theoretical renormalization group were employed to explain and quantitatively describe different types of static and dynamic behavior in the vicinity of multicritical points. Here we give the complete two-loop calculation and analysis of the dynamic renormalization-group flow equations at the multicritical point in anisotropic antiferromagnets in an external magnetic field. We find that the time scales of the order parameters characterizing the parallel and perpendicular ordering with respect to the external field scale in the same way. This holds independent whether the Heisenberg fixed point or the biconical fixed point in statics is the stable one. The nonasymptotic analysis of the dynamic flow equations shows that due to cancellation effects the critical behavior is described, in distances from the critical point accessible to experiments, by the critical behavior qualitatively found in one-loop order. Although one may conclude from the effective dynamic exponents (taking almost their one-loop values) that weak scaling for the order parameter components is valid, the flow of the time-scale ratios is quite different, and they do not reach their asymptotic values.