This is a less technical presentation of the ideas in quant-ph/9804035 [Phys Rev Lett 83 (1999), 1707-1710]. A second order phase transition induced by a rapid quench can lock out topological defects with densities far exceeding their equilibrium expectation values. This phenomenon is a generic prediction of nonequilibrium statistical mechanics, and can appear in a wide range of physical systems. We discuss it qualitatively in the context of trapped dilute Bose-Einstein condensates, outline a simple quantitative theory based on the time-dependent Ginzburg-Landau equation, and briefly compare the results of quantum kinetic theory.
This is a less technical presentation of the ideas in quant-ph/9804035 [Phys Rev Lett 83 (1999), 1707-1710]. A second order phase transition induced by a rapid quench can lock out topological defects with densities far exceeding their equilibrium expectation values. This phenomenon is a generic prediction of nonequilibrium statistical mechanics, and can appear in a wide range of physical systems. We discuss it qualitatively in the context of trapped dilute Bose-Einstein condensates, outline a simple quantitative theory based on the time-dependent Ginzburg-Landau equation, and briefly compare the results of quantum kinetic theory.
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
Phase transitions abound in the physical world, from the subatomic length scales of quark condensation to the decoupling forces in the early universe. In the Bose-Einstein condensation phase transition, a gas of trapped bosonic atoms is cooled to a critical temperature. Below this temperature, a macroscopic number of atoms suddenly starts to occupy a single quantum state; these atoms comprise the Bose-Einstein condensate (BEC). The dynamics of the BEC phase transition are the focus of this dissertation and the experiments described here have provided new information on the details of BEC formation. New theoretical developments are proving to be valuable tools for describing BEC phase transition dynamics and interpreting new experimental results. With their amenability to optical manipulation and probing along with the advent of new microscopic theories, BECs provide an important new avenue for gaining insight into the universal dynamics of phase transitions in general.Spontaneous symmetry breaking in the system's order parameter may be one result of cooling through a phase transition. A potential consequence of this is the spontaneous formation of topological defects, which in a BEC appear as vortices. We experimentally observed and characterized the spontaneous formation of vortices during BEC growth. We attribute vortex creation to coherence length limitations during the initial stages of the phase transition. Parallel to these experimental observations, theory collaborators have used the Stochastic Gross-Pitaevski Equation formalism to simulate the growth of a condensate from a thermal cloud. The experimental and theoretical statistical results of the spontaneous formation of vortex cores during the growth of the condensate are in good quantitative agreement with one another, supporting our understanding of the dynamics of the phase transition. We believe that our results are also qualitatively consistent with the Kibble-Zurek mechanism, a universal model for topological defect formation.Ultimately, our understanding of the dynamics of the BEC phase transition may lead to a broader understanding of phase transitions in general, and provide new insight into the development of coherence in numerous systems.
We investigate the dynamics of formation of topological defects in ultra-cold quantum gases. Using classical field methods, such as the truncated Wigner approximation and the stochastic Gross-Pitaevskii equation, we explore the connection between the rate of a phase transition and the number of topological defects formed as a consequence of it. We show that in various systems such defects form in number comparable with the predictions of the Kibble-Zurek theory, known for thirty years but as yet unverified experimentally. We also consider the spontaneous production of entangled vortices following a quantum phase transition in a multi-component spin-1 Bose-Einstein condensate (BEC). To begin, we provide a literature review and describe some of the background theory of multi-component condensates, stochastic methods and Kibble-Zurek theory. Part of this thesis focus on a two component Bose-Einstein condensates of the same atomic species. In particular on the quantum critical point separating the miscible from the immiscible phase of such systems. We show that such phase transition cannot only be achieved with the tuning of the interaction constants between the components, but also through changes in the intensity of the coupling between atoms in different hyperfine states. We first determine the value of the critical coupling, and also the critical exponents defining the universality class of the coupling—induced phase transition. We then proceed to simulate the dynamics of the transition in effective 1D ring and harmonically trapped condensates, and test the results against predictions of the Kibble-Zurek (KZ) mechanism. We find good agreement between the KZ theory and the numerical results in the ring geometry, and we motivate the origin of the discrepancies between the two in harmonically trapped BECs. We use the ”equivalence” of inhomogeneous phase transitions in anisotropic systems and spatially inhomogeneous quenches to engineer coupling quenches and systematically study key aspects of the inhomogeneous KZ mechanism. The coupling induced miscible—immiscible transition results in the formation of a stable pattern of domains that easily be detected and counted in current ultra-cold gases experiment, and the scheme is a viable candidate for the first experimental testing of the KZ predictions. We then examine the spontaneous formation of a superflow as result of the thermal Bose-Einstein phase transition in ring traps. According to the Kibble-Zurek theory, the fast production of a condensate in a ring trap should result in the formation of solitons, with the number depending on the rate of the temperature quench. Solitons are short-living topological defects and their observation in ultra-cold gases experiments remains challenging. We show here that even after they decay, solitons leave a signature in the variance of the final winding number of the condensate. Solitons fragment a 1D condensate into regions of random phase, hence the larger the number of solitons, the higher the probability that the resulting phase wraps around the ring by a multiple of 2π. We numerically simulate the BEC transition in this system with the stochastic Gross-Pitaevskii equation, and observe that the winding number scales with the quenching time as predicted by the KZ mechanism. We examine the effect of inhomogeneity on the expectation value of the winding number, and find that the tilting of the ring greatly suppress the spontaneous formation of vortices. This has implications for the necessary horizontal alignment of any experiment on this system. Finally, we consider the polar to anti-ferromagnetic phase transition in magnetically quenched spin-1 BEC. In this quantum phase transition a pure condensate of atoms in the mF = 0 Zeeman sublevel is converted into a three component BEC with atoms in mF = 0, ±1 through spin changing collisions. An analogous mechanism, four—wave mixing, in quantum optics produces entangled photons, and it has been proposed in ultra-cold gases as a method to obtain Einstein-Podolski-Rosen entanglement of macroscopic atomic ensembles. We begin with a rotating 1D spinor condensate of atoms in the mF = 0 component, and perform a quench of the magnetic field through the critical point. We show how the transition produces a pair of entangled components with different winding numbers, and quantify the entanglement as a function of the modes considered and of the type of magnetic quench, sudden or instantaneous. Lastly, we propose a method to use the original spin zero component as coherent source to perform homodyne detection and consider the two rotating entangled components as a resource for the sensing of rotations.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Kibble-Zurek mechanism (KZM) uses critical scaling to predict density of topological defects and other excitations created in second order phase transitions. We point out that simply inserting asymptotic critical exponents deduced from the immediate vicinity of the critical point to obtain predictions can lead to results that are inconsistent with a more careful KZM analysis based on causality - on the comparison of the relaxation time of the order parameter with the "time distance" from the critical point. As a result, scaling of quench-generated excitations with quench rates can exhibit behavior that is locally (i.e., in the neighborhood of any given quench rate) well approximated by the power law, but with exponents that depend on that rate, and that are quite different from the naive prediction based on the critical exponents relevant for asymptotically long quench times. Kosterlitz-Thouless scaling (that governs e.g. Mott insulator to superfluid transition in the Bose-Hubbard model in one dimension) is investigated as an example of this phenomenon.