The purpose of our collaboration is to study ultracold collisions in a gas sample of atomic lithium. The associated experimental context is a scheme for producing such a gas sample in conditions where Bose-Einstein condensation (BEC) should be observable in the case of the {sup 7}Li isotope or Fermi degenerate behavior for the {sup 6}Li isotope. The plan is to load 10{sup 5}-10{sup 9} Li atoms from a laser cooled atomic beam into a magnetic trap with a diameter of about 1 mm. The fundamental limitation to achieving high density will be collisions of ground state atoms. We are interested in the loss of atomic density in a magnetic trap due to two-body dipolar collisions and spin-exchange collisions. Lithium atoms offer important advantages relative to other alkali atoms from the theoretical point of view. In the first place there is the greater accuracy of the available long-range potential parameters. Secondly, one avoids a complication of the heavier alkalis connected with the unknown spin-spin term following in second order from the electronic spin-orbit couplings In this contribution we present preliminary results for the above loss-mechanisms.
The purpose of our collaboration is to study ultracold collisions in a gas sample of atomic lithium. The associated experimental context is a scheme for producing such a gas sample in conditions where Bose-Einstein condensation (BEC) should be observable in the case of the {sup 7}Li isotope or Fermi degenerate behavior for the {sup 6}Li isotope. The plan is to load 10{sup 5}-10{sup 9} Li atoms from a laser cooled atomic beam into a magnetic trap with a diameter of about 1 mm. The fundamental limitation to achieving high density will be collisions of ground state atoms. We are interested in the loss of atomic density in a magnetic trap due to two-body dipolar collisions and spin-exchange collisions. Lithium atoms offer important advantages relative to other alkali atoms from the theoretical point of view. In the first place there is the greater accuracy of the available long-range potential parameters. Secondly, one avoids a complication of the heavier alkalis connected with the unknown spin-spin term following in second order from the electronic spin-orbit couplings In this contribution we present preliminary results for the above loss-mechanisms.
Laser cooling and atom trapping techniques have enabled atomic physicists to attain temperatures on the order of 100 nK. In this regime, a trapped gas must be described within the framework of quantum statistical mechanics. In 1995, Bose-Einstein condensation (BEC) was achieved for the first time in such a system by three independent groups. The success of attaining BEC has encouraged research in quantum degenerate Fermi gases (DFG). One of the most exciting opportunities for a DFG is the prospect for Cooper pairing in a two-component gas. The experimental techniques for obtaining degenerate gases, as well as the mechanism for Cooper pairing, hinges on understanding and characterizing ultracold collisional interactions.\nThis thesis is a twofold study in this exciting field. The first section is an in-depth treatment of collisions in atomic lithium. Lithium has two isotopes, 6Li which is a fermion and 7Li which is a boson. This makes it an ideal candidate for studying quantum degenerate gases. In a series of experiments using a magneto-optical trap, we have spectroscopically measured the ground and excited state molecular potentials for both isotopes. From this work we have been able to obtain the most accurate potentials for lithium to date. These precise measurements have enabled us to extract the most accurate value to date for the 2P atomic radiative lifetime of lithium. Furthermore, we have developed a coupled-channel treatment of two-body collisions which has enabled us to calculate the scattering amplitude, elastic cross section, and rate of spin-exchange decay for any ground state collision in lithium as a function of temperature and magnetic field.\nArmed with this knowledge, we have made progress on the design and construction of an electromagnetic trap for lithium. This trap will enable the study of a degenerate Fermi gas of 6Li as well as the possibility of observing a Cooper pairing transition. The trap performance has been characterized for each isotope and current work is focussed on cooling lithium down to degeneracy. Measurements of spin-exchange decay have been made and compare well with the collisional theory that has been developed.
Collisions between ultracold neutral atoms have for some time been the subject of investigation, initially with hydrogen and more recently with laser cooled alkali atoms. Advances in laser cooling and trapping of neutral atoms in a Magneto-Optic Trap (MOT) have made cold atoms available as the starting point for many laser cooled atomic physics investigations. The most spectacularly successful of these, the observation of Bose-Einstein Condensation (BEC) in a dilute ultra-cold spin polarized atomic vapor, has accelerated the study of cold collisions. Experimental and theoretical studies of BEC and the long range interaction between cold alkali atoms is at the boundary of atomic and low temperature physics. Such studies have been difficult and would not have been possible without the development and advancement of laser cooling and trapping of neutral atoms. By contrast, ion-atom interactions at low temperature, also very difficult to study prior to modern day laser cooling, have remained largely unexplored. But now, many laboratories worldwide have almost routine access to cold neutral atoms. The combined technologies of ion trapping, together with laser cooling of neutrals has made these studies experimentally feasible and several very important, novel applications might come out of such investigations . This paper is an investigation of ion-atom interactions in the cold and ultra-cold temperature regime. Some of the collisional ion-atom interactions present at room temperature are very much reduced in the low temperature regime. Reaction rates for charge transfer between unlike atoms, A + B(+) approaches A(+) + B, are expected to fall rapidly with temperature, approximately as T(sup 5/2). Thus, cold mixtures of atoms and ions are expected to coexist for very long times, unlike room temperature mixtures of the same ion-atom combination. Thus, it seems feasible to cool ions via collisions with laser cooled atoms. Many of the conventional collisional interactions, exploited as a useful tool at room temperature and higher, are greatly enhanced at low energy. For example, collisional spin transfer from one species of polarized atoms to another has long been a useful method for polarizing a sample of atoms where no other means was available. Because optical pumping cannot be used to polarize the nuclear spin of Xe-129 or He-3 (for use in nmr imaging of the lungs), the nuclear spins are polarized via collisions with an optically pumped Rb vapor in a cell containing both gases. In another case, a spin polarized thermal Cs beam was used to polarize the hyperfine states of trapped He(+)-3 ions in order to measure their hyperfine clock transition frequency. The absence of an x-ray light source to optically pump the ground state of the He(+)-3 ion necessitated this alternative state preparation. Similarly, Cd(+) and Sr(+) ions were spin-oriented via collisions in a cell with optically pumped Rb vapor. Resonant RF spin changing transitions in the ground state of the ions were detected by changes in the Rb resonance light absorption. Because cold collision spin exchange rates scale with temperature as T(sup -1/2) this technique is expected to be a far more powerful tool than the room temperature counterpart. This factor of 100 or more enhancement in spin exchange reaction rates at low temperatures is the basis for a novel trapped ion clock where laser cooled neutrals will cool, state select and monitor the ion clock transition. The advantage over conventional direct laser cooling of trapped ions is that the very expensive and cumbersome UV laser light sources, required to excite the ionic cooling transition, are effectively replaced by simple diode lasers.
Summary form only given. Laser cooling and trapping of atoms has enabled some of the most exciting recent advances in atomic physics, including the achievement of Bose-Einstein condensation (BEC). Efforts are now underway to trap ultracold molecules in order to study chemical reactions and to investigate BEC of larger particles. In the atomic BEC experiments, the atoms are cooled to sub-/spl mu/K temperatures so the energy spread of the atoms which are not in the condensate is small (/spl les/20 kHz) and that of the condensate itself is zero. Therefore, a quantum degenerate gas enables an unprecedented level of spectroscopic precision. We report two-photon photoassociation of quantum degenerate /sup 7/Li atoms into the least-bound vibrational level of the ground-state triplet potential of /sup 7/Li/sub 2/. These molecules are magnetically trappable by virtue of their electronic magnetic moment.
This thesis presents studies of quantum degenerate atomic gases of fermionic 6Li and bosonic 7Li. Degeneracy is reached by evaporative cooling of 7Li in a strongly confining magnetic trap. Since at low temperatures direct evaporative cooling is not possible for a polarized fermionic gas, 6Li is sympathetically cooled by thermal contact with 7Li. In a first series of experiments both isotopes are trapped in their low-field seeking higher hyperfine states. A Fermi degeneracy of is achieved for 105 fermions. For more than ~300 atoms, the 7Li condensate collapses, due to the attractive interatomic interaction in this state. This limits the degeneracy reached for both species. To overcome this limit, in a second series of experiments 7Li and 6Li atoms are transferred to their low field seeking lower hyperfine states, where the boson-boson interaction is repulsive but weak. The inter-isotope collisions are used to thermalize the mixture. A 7Li Bose-Einstein condensate (BEC) of 104 atoms immersed in a Fermi sea is produced. The BEC is quasi-one-dimensional and the thermal fraction can be negligible. The measured degeneracies are . The temperature is measured using the bosonic thermal fraction, which vanishes at the lowest temperatures, limiting our measurement sensitivity. In a third series of experiments, the bosons are transferred into an optical trap and their internal state is changed to , the lowest energy state. A Feshbach resonance is detected and used to produce a BEC with tunable atomic interactions. When the effective interaction between atoms is tuned to be small and attractive, we observe the formation of a matter-wave bright soliton. Propagation of the soliton without spreading over a macroscopic distance of 1.1~mm is observed.
We are attempting to produce an atomic vapor that is so cold that the de Broglie wavelength is larger than the interparticle spacing. This is the condition needed to obtain Bose-Einstein condensation of a noninteracting gas. Our approach is to optically trap and cool atomic cesium and then load it into a purely magnetic trap for further cooling. In the course of this work we have investigated a number of magnetic traps and very low temperature collisions that are relevant to the success of this approach. In other work we are developing optical trapping techniques for the efficient collection of radioactive alkali isotopes. This work is aimed at measuring parity violation in these isotopes and thereby stringently testing the standard model of elementary particle physics. We have studied how to optimize the capture efficiency of atoms in an atomic vapor. We are currently developing cells that will allow the atoms to bounce off the walls until they are captured in the optical trap. The efficiency of this capture scheme will be discussed.
Collisions between ultra-cold (T << 1K) atoms confined in a magneto- optical trap (MOT) may result in the ejection of atoms from the trap. These collisional loss processes, which involve ground state/excited state collisions, fundamentally limit the density attainable in MOT traps. Although accurate calculations of collision rates between ultra-cold atoms require precise knowledge of the molecular potentials over a long range, the loss rate for Li was recently predicted to be significantly less than for the other alkali metals. Motivated by this result, we are measuring the collisional loss rate of Li in a vapor-cell MOT using a red-detuned laser beam to catalyze the collisions, similar to recent experiments using Rb and Cs. We will report our progress to measure the trap loss rate for {sup 6}Li and {sup 7}Li, which will be compared to investigate an isotopic dependence, as was recently observed for Rb.