Laser cooling and atom trapping techniques have enabled atomic physicists to attain temperatures on the order of 100 nK. In this regime, a trapped gas must be described within the framework of quantum statistical mechanics. In 1995, Bose-Einstein condensation (BEC) was achieved for the first time in such a system by three independent groups. The success of attaining BEC has encouraged research in quantum degenerate Fermi gases (DFG). One of the most exciting opportunities for a DFG is the prospect for Cooper pairing in a two-component gas. The experimental techniques for obtaining degenerate gases, as well as the mechanism for Cooper pairing, hinges on understanding and characterizing ultracold collisional interactions.\nThis thesis is a twofold study in this exciting field. The first section is an in-depth treatment of collisions in atomic lithium. Lithium has two isotopes, 6Li which is a fermion and 7Li which is a boson. This makes it an ideal candidate for studying quantum degenerate gases. In a series of experiments using a magneto-optical trap, we have spectroscopically measured the ground and excited state molecular potentials for both isotopes. From this work we have been able to obtain the most accurate potentials for lithium to date. These precise measurements have enabled us to extract the most accurate value to date for the 2P atomic radiative lifetime of lithium. Furthermore, we have developed a coupled-channel treatment of two-body collisions which has enabled us to calculate the scattering amplitude, elastic cross section, and rate of spin-exchange decay for any ground state collision in lithium as a function of temperature and magnetic field.\nArmed with this knowledge, we have made progress on the design and construction of an electromagnetic trap for lithium. This trap will enable the study of a degenerate Fermi gas of 6Li as well as the possibility of observing a Cooper pairing transition. The trap performance has been characterized for each isotope and current work is focussed on cooling lithium down to degeneracy. Measurements of spin-exchange decay have been made and compare well with the collisional theory that has been developed.
Laser cooling and atom trapping techniques have enabled atomic physicists to attain temperatures on the order of 100 nK. In this regime, a trapped gas must be described within the framework of quantum statistical mechanics. In 1995, Bose-Einstein condensation (BEC) was achieved for the first time in such a system by three independent groups. The success of attaining BEC has encouraged research in quantum degenerate Fermi gases (DFG). One of the most exciting opportunities for a DFG is the prospect for Cooper pairing in a two-component gas. The experimental techniques for obtaining degenerate gases, as well as the mechanism for Cooper pairing, hinges on understanding and characterizing ultracold collisional interactions.\nThis thesis is a twofold study in this exciting field. The first section is an in-depth treatment of collisions in atomic lithium. Lithium has two isotopes, 6Li which is a fermion and 7Li which is a boson. This makes it an ideal candidate for studying quantum degenerate gases. In a series of experiments using a magneto-optical trap, we have spectroscopically measured the ground and excited state molecular potentials for both isotopes. From this work we have been able to obtain the most accurate potentials for lithium to date. These precise measurements have enabled us to extract the most accurate value to date for the 2P atomic radiative lifetime of lithium. Furthermore, we have developed a coupled-channel treatment of two-body collisions which has enabled us to calculate the scattering amplitude, elastic cross section, and rate of spin-exchange decay for any ground state collision in lithium as a function of temperature and magnetic field.\nArmed with this knowledge, we have made progress on the design and construction of an electromagnetic trap for lithium. This trap will enable the study of a degenerate Fermi gas of 6Li as well as the possibility of observing a Cooper pairing transition. The trap performance has been characterized for each isotope and current work is focussed on cooling lithium down to degeneracy. Measurements of spin-exchange decay have been made and compare well with the collisional theory that has been developed.
This thesis presents studies of quantum degenerate atomic gases of fermionic 6Li and bosonic 7Li. Degeneracy is reached by evaporative cooling of 7Li in a strongly confining magnetic trap. Since at low temperatures direct evaporative cooling is not possible for a polarized fermionic gas, 6Li is sympathetically cooled by thermal contact with 7Li. In a first series of experiments both isotopes are trapped in their low-field seeking higher hyperfine states. A Fermi degeneracy of is achieved for 105 fermions. For more than ~300 atoms, the 7Li condensate collapses, due to the attractive interatomic interaction in this state. This limits the degeneracy reached for both species. To overcome this limit, in a second series of experiments 7Li and 6Li atoms are transferred to their low field seeking lower hyperfine states, where the boson-boson interaction is repulsive but weak. The inter-isotope collisions are used to thermalize the mixture. A 7Li Bose-Einstein condensate (BEC) of 104 atoms immersed in a Fermi sea is produced. The BEC is quasi-one-dimensional and the thermal fraction can be negligible. The measured degeneracies are . The temperature is measured using the bosonic thermal fraction, which vanishes at the lowest temperatures, limiting our measurement sensitivity. In a third series of experiments, the bosons are transferred into an optical trap and their internal state is changed to , the lowest energy state. A Feshbach resonance is detected and used to produce a BEC with tunable atomic interactions. When the effective interaction between atoms is tuned to be small and attractive, we observe the formation of a matter-wave bright soliton. Propagation of the soliton without spreading over a macroscopic distance of 1.1~mm is observed.
The work described in this thesis can be divided into two parts. The first part is concerned with the production of degenerate Fermi gases and Bose-Fermi mixtures. The second part of the thesis describes studies of strongly interacting spin-mixtures of ultracold fermions. We have cooled a magnetically trapped spin-polarized 6Li Fermi gas into quantum degeneracy by sympathetic cooling with bosonic 23Na. In order to do this, we have converted our previously developed apparatus for Bose-Einstein condensation of 23Na into a two-species cooling facility. We have produced 6Li samples with up to 7 × 107 atoms at temperatures below 0.5TF , and up to 3× 107 atoms at temperatures as low as 0.05TF . Further, we have also produced stable quantum degenerate mixtures of 23Na and 6Li, with several million atoms of each species. In a second set of experiments, we have studied strongly interacting spin-mixtures of 6Li. The strength of interactions was resonantly controlled by applying a magnetic field and tuning to “Feshbach resonances”, which occur when the total energy of the colliding particles coincides with the energy of a bound molecular state. These studies are relevant for the continuing quest for a superfluid transition in a Fermi gas. By studying the inelastic decay of the cloud, we have experimentally identified two Feshbach resonances for the inter-state interactions of the two lowest ground states of 6Li. Most importantly, we found that the lifetime of the strongly interacting system is long enough to observe a superfluid transition in the future. The effects of the coherent collisions in 6Li spin-mixtures were studied using radiofrequency (RF) spectroscopy. We demonstrated the absence of mean field “clock shifts” in a two-state mixture of fermions, and have introduced a three-level method to observe the interaction energy shifts. In the strongly interacting regime, near a Feshbach resonance, we have observed universal behavior of the interaction energy, independent of the value of the scattering length. Finally, we have theoretically studied the effects of Pauli blocking during a free expansion of a degenerate Fermi gas. We have concluded that a strongly interacting normal gas will undergo a hydrodynamic expansion even at zero temperature, due to inefficiency of the Pauli suppression of collisions. Therefore, the already observed hydrodynamic expansion cannot be conclusively interpreted as a signature of superfluidity. Thesis Supervisor: Wolfgang Ketterle Title: John D. MacArthur Professor of Physics
The purpose of our collaboration is to study ultracold collisions in a gas sample of atomic lithium. The associated experimental context is a scheme for producing such a gas sample in conditions where Bose-Einstein condensation (BEC) should be observable in the case of the {sup 7}Li isotope or Fermi degenerate behavior for the {sup 6}Li isotope. The plan is to load 10{sup 5}-10{sup 9} Li atoms from a laser cooled atomic beam into a magnetic trap with a diameter of about 1 mm. The fundamental limitation to achieving high density will be collisions of ground state atoms. We are interested in the loss of atomic density in a magnetic trap due to two-body dipolar collisions and spin-exchange collisions. Lithium atoms offer important advantages relative to other alkali atoms from the theoretical point of view. In the first place there is the greater accuracy of the available long-range potential parameters. Secondly, one avoids a complication of the heavier alkalis connected with the unknown spin-spin term following in second order from the electronic spin-orbit couplings In this contribution we present preliminary results for the above loss-mechanisms.
The pairing of fermionic particles is an essential ingredient of superconductivity and of the superfluidity of 3He. While such phenomena are accurately described by BCS theory in the limit of weak pairing strength, a complete understanding remains elusive when pairing strength is increased, such as in high temperature superconductors. We create ultracold gases of trapped fermionic 6Li atoms, through which we directly observe fermionic pairing. In our system, there are no impurities whatsoever, and parameters such as the number and temperature of the trapped atoms are precisely and independently controlled. In addition, a Feshbach resonance enables the continuous tuning of interaction strength and sign between the paired atoms. This control allows us to observe the smooth crossover of a molecular Bose Einstein condensate (MBEC) to a superfluid of weakly interacting Cooper pairs. With these tools, we have performed several fundamental measurements of pairing in fermionic systems.\nWe use optical molecular spectroscopy to precisely measure the closed-channel contribution to the many body state of paired 6Li atoms within a broad Feshbach resonance. The magnitude of this contribution is small, and supports the concept of universality for the description of broad Feshbach resonances. Moreover, the dynamics of the excitation provide clear evidence for pairing across the BEC-BCS crossover, and for the first time, into the weakly interacting BCS regime.\nWe also prepare a polarized Fermi gas with unequal numbers of two spin states of 6Li atoms. The real-space densities of the polarized, strongly-interacting, two-component Fermi gas reveal two low temperature regimes. At the lowest temperatures, the gas separates into a phase with a uniformly paired superfluid core surrounded by a shell of normal, unpaired atoms. This phase separation is accompanied by a spatial deformation of the core. At higher temperatures, the uniformly paired core persists, though it does not deform. This temperature dependence is consistent with a tri-critical point in the phase diagram. These measurements of pairing in a polarized Fermi gas are relevant to predictions of exotic phases of quark matter and magnetized superconductors.
The research described in this thesis is part of an international effort with the aim of studying ultracold quantum degenerate gas samples like Bose-Einstein condensates and Fermi degenerate systems, consisting of atoms confined in magnetic or optical traps. The behavior of such samples is governed by the inter-atomic interactions and the resulting properties of the atom-atom scattering. At the relevant temperatures of 1nK to 10µK a key property is the atom-atom scattering length a. In chapter 2 a theoretical method is presented which enables one to describe the interaction and scattering of (ultra)cold atoms to unprecedented precision. It is also unparalleled in comprehensiveness: it allows the prediction of a large and varied set of experimental data for all isotopes of the same element. The method relies on the extraction from experiments of a few (phase) parameters which completely summarize the behavior of the atoms in the (ultra)cold regime. In chapter 3 the method is applied to the "workhorses" of cold-atom physics: the atomic species 85Rb and 87Rb. We extract the foregoing parameters to a very high precision from several recent high precision experiments, allowing us to predict e.g. the 87Rb spinor condensate to be ferromagnetic: a prediction for which the scattering length has to be calculated with a precision better than 1%. We also predict Feshbach resonances at experimentally accessible magnetic field strengths; resonances searched for and found by the experimental group of Rempe. In close collaboration with his group we "fine-tune" the interaction parameters found previously, by making use of only one of the observed resonances. We then obtain agreement with 42 out of the observed 43 resonance field strengths and are able to identify bound states inducing the Feshbach resonances at these locations. Chapter 4 describes the results of this research. With a thorough understanding of the rubidium interactions, we then switch to lithium which has a fermionic (6Li) and a bosonic (7Li) isotope. Both are being used in cold-atom experiments. In chapter 5 we evaluate the interaction parameters for lithium allowing us to predict magnetic field strengths for which a sample of fermionic 6Li atoms can be regarded as strongly interacting. Furthermore, a three-level method for measuring mean-field shifts, based on radio-frequency techniques, is introduced. For weak interactions we find proportionality of resonance shifts to interaction strengths. In the strongly interacting regime, however, these shifts become very small reflecting the quantum unitarity limit and many-body effects. Most interesting is the fact that in this regime the shifts are small both for large positive a and for large negative a, likely reflecting the universality of the interaction energy. In chapters 6 and 7 the interactions between lithium atoms are reinvestigated, making use of newly available experimental data and with the updated interaction parameters special attention is paid to locating field strengths at which magnetically tunable Feshbach resonances occur in the scattering of lithium atoms. In chapter 6 scattering events in a gas of (fermionic) 6Li atoms are studied. In chapter 7 we show that a consistent description of the 6Li+6Li system can be given. We discuss theoretical uncertainties for the position of the wide 6Li Feshbach resonance and present an analytic scattering model for this resonance, based on the inclusion of a field-dependent virtual open-channel state. We predict new Feshbach resonances for the 6Li-7Li system, and their importance for different types of crossover superfluidity models is discussed. Molecules created by magnetically sweeping over these resonances will have a fermionic character. One magnetic field strength is predicted at which two different fermionic molecules can be created simultaneously.
Ultracold mixture experiments hold the promise of providing new insights into many-body quantum systems as well as ultracold chemistry and few-body phenomena. The work presented in this thesis dealt with the construction of a new apparatus for the production and study of ultracold gases of fermionic lithium-6 and bosonic caesium-133. These isotopes offer a wide tunability in their interaction strength, both in inter-species and intra-species collisions, through magnetic Feshbach resonances. Additionally, the widely different resonance frequencies of lithium and caesium enables independent control of each of the species. With this apparatus, Bose-Einstein condensates (BEC) containing 10^4 lithium Feshbach molecules are routinely produced. The cooling system for caesium has been developed in parallel and important steps towards producing ultracold caesium gases have been made. An optical dipole trap has been loaded with 2x10^6 caesium atoms and evaporative cooling towards quantum degeneracy can now be pursued. Laser, vacuum, magnetic and control systems have been developed for the implementation of this experiment. Light produced with this laser system was used to laser cool atoms, create conservative dipole traps as well as to provide means of imaging atomic clouds. Additionally, a system to produce strong magnetic fields of up to 1400 G has been established in order to exploit the wide tunability in the atomic interactions. Software that was developed for the computerised control system facilitated the coordination of all the components involved in the experimental sequence. Measurements and calculations that showcase the functionality of relevant parts of the setup are presented in this thesis. In this experiment, lithium and caesium atoms are obtained from a novel type of Zeeman slower and are loaded into a magneto-optical trap (MOT). The system is capable of doing this independently for each of the atomic species as well as sequentially. After the MOT has been loaded with atoms, they are transferred into a conservative far-off-resonance optical dipole trap. By adjusting the interactions between atoms and lowering the depth of the dipole trap, efficient evaporative cooling of lithium was carried out from which a molecular BEC was obtained. Time-of-flight measurements were used to characterise the condensate and study its expansion dynamics.