Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Hg-201 (+) CO-Magnetometer for HG-199(+) Trapped Ion Space Atomic Clocks

Eric A. Burt, S. Taghavi-Larigani, Robert L. Tjoelker

Published Sep 27, 2011• 0 citations
OpenAlex

Abstract

Local magnetic field strength in a trapped ion atomic clock is measured in real time, with high accuracy and without degrading clock performance, and the measurement is used to compensate for ambient magnetic field perturbations. First and second isotopes of an element are co-located within the linear ion trap. The first isotope has a resonant microwave transition between two hyperfine energy states, and the second isotope has a resonant Zeeman transition. Optical sources emit ultraviolet light that optically pump both isotopes. A microwave radiation source simultaneously emits microwave fields resonant with the first isotope's clock transition and the second isotope's Zeeman transition, and an optical detector measures the fluorescence from optically pumping both isotopes. The second isotope's Zeeman transition provides the measure of magnetic field strength, and the measurement is used to compensate the first isotope's clock transition or to adjust the applied C-field to reduce the effects of ambient magnetic field perturbations.

Related papers

Cycle Time Reduction in Trapped Mercury Ion Atomic Frequency Standards

Eric A. Burt, Robert L. Tjoelker, S. Taghavi-Larigani

The use of the mercury ion isotope (201)Hg(+) was examined for an atomic clock. Taking advantage of the faster optical pumping time in (201)Hg(+) reduces both the state preparation and the state readout times, thereby decreasing the overall cycle time of the clock and reducing the impact of medium-term LO noise on the performance of the frequency standard. The spectral overlap between the plasma discharge lamp used for (201)Hg(+) state preparation and readout is much larger than that of the lamp used for the more conventional (199)Hg(+). There has been little study of (201)Hg(+) for clock applications (in fact, all trapped ion clock work in mercury has been with (199)Hg(+); however, recently the optical pumping time in (201)Hg(+) has been measured and found to be 0.45 second, or about three times faster than in (199)Hg(+) due largely to the better spectral overlap. This can be used to reduce the overall clock cycle time by over 2 seconds, or up to a factor of 2 improvement. The use of the (201)Hg(+) for an atomic clock is totally new. Most attempts to reduce the impact of LO noise have focused on reducing the interrogation time. In the trapped ion frequency standards built so far at JPL, the optical pumping time is already at its minimum so that no enhancement can be had by shortening it. However, by using (201)Hg(+), this is no longer the case. Furthermore, integrity monitoring, the mechanism that determines whether the clock is functioning normally, cannot happen faster than the clock cycle time. Therefore, a shorter cycle time will enable quicker detection of failure modes and recovery from them.

•Feb 1, 2011•0 citations

Performance of Micro Mercury Trapped Ion Clock

Thai M. Hoang, Sang Kun Chung, Thanh Le +4 more

Trapped mercury ion is a promising candidate for portable and operational atomic clocks. It operates at the 40.5GHz ground state hyperfine transition of 199Hg ions. Mercury ions are confined in a linear RF trap, buffer-gas cooled, with a long ion storage lifetime in an ultra-high vacuum enclosure without an active pump. The clock transition is optically-pumped and detected with a Hg discharge lamp without need of a laser light source. This approach has proven to provide simplicity in design and implementation and robustness in operation. In this paper, we report our recently effort on developing a micro and low-power mercury trapped ion clock in the DARPA ACES program. In a 5 mm x 10 mm linear trap (0.25 cc), we have achieved the clock fractional frequency stability of .7 × 10-12τ-1/2and reached down to 7 × 10-14after 1000 seconds of averaging. We will discuss the clock performance under different conditions and implications toward a micro mercury trapped ion clock with low power and high stability.

Joint Conference of the European Frequency and Time Forum and IEEE International Frequency Control Symposium (EFTF/IFCS)•Apr 1, 2019•10 citations

A high-performance Hg(+) trapped ion frequency standard

John D. Prestage, Robert L. Tjoelker, G.J. Dick +1 more

A high-performance frequency standard based on (199)Hg(+) ions confined in a hybrid radio frequency (RF)/dc linear ion trap is demonstrated. This trap permits storage of large numbers of ions with reduced susceptibility to the second-order Doppler effect caused by the RF confining fields. A 160-mHz-wide atomic resonance line for the 40.5-GHz clock transition is used to steer the output of a 5-mHz crystal oscillator to obtain a stability of 2 x 10(exp -15) for 24,000-second averaging times. Measurements with a 37-mHz line width for the Hg(+) clock transition demonstrate that the inherent stability for this frequency standard is better than 1 x 10(exp -15) at 10,000-second averaging times.

The Telecommunications and Data Acquisition Report•Feb 15, 1992•1 citation

Characterization of rf field-induced a.c. Zeeman shift in multi-level highly charged ions

Shuying Chen, Lukas J. Spieß, Alexander Wilzewski +3 more

Characterization of the trap rf induced a.c. Zeeman shift is essential for achieving high accuracy in optical ion clocks. In this work, we demonstrate the experimental characterization of this shift using highly charged $\mathrm{Ca}^{14+}$. The transverse component of the a.c. magnetic field is measured using the Autler-Townes splitting of the equally-spaced Zeeman components of the $^{3}\mathrm{P}_1$ when the Zeeman splitting is close to resonance with the trap rf drive frequency. We observe the resulting modulation by performing quantum logic spectroscopy using the co-trapped $\mathrm{Be}^{+}$. The longitudinal component is measured from probing the $\mathrm{Be}^{+}$ magnetic field-insensitive hyperfine transition $|F=2,m_F=0 \rangle \rightarrow | F=1,m_F=0 \rangle$. We confirm the small influence of the a.c. Zeeman shift in highly charged ions. The employed techniques can easily be transferred to other multi-level atomic systems.

arXiv:2604.09481•Apr 10, 2026•0 citations

Progress towards a dual-isotope trapped mercury ion atomic clock: Further studies of background gas collision shifts

L. Yi, S. Taghavi-Larigani, Eric A. Burt +1 more

As part of an on-going effort to build a dual-isotope ion trap clock based on the199Hg+and201Hg+ground state hyperfine transitions, we continue to characterize the systematic sensitivities of the201Hg+29.9GHz clock transition. Here we present an extension to the previous201Hg+collision shift measurement for helium[1] to other background gases. We also measured the collision shifts in the199Hg+40.5GHz clock transition in the same physical system. We find that frequency sensitivities to collisions with background gas for the two isotopes agree within a factor of two. We will also discuss planned collision shift measurements with co-trapped199Hg+and201Hg+, as an important step towards a dual-isotope atomic clock.

Joint Conference of the European Frequency and Time Forum and IEEE International Frequency Control Symposium (EFTF/IFCS)•May 1, 2012•7 citations

Al+ Optical Clocks for Fundamental Physics and Geodesy

James Chin-wen Chou

Laser-cooled trapped atoms have long been recognized as potentially very accurate frequency standards for clocks. Ultimate accuracies of 10-18 to 10-19 appear possible, limited by the time-dilation of trapped ions that move at laser-cooled velocities. The Al+ ion is an attractive candidate for high accuracy, owing to its narrow electronic transition in the optical regime and low sensitivity to ambient field perturbations. Precision spectroscopy on Al+ is enabled by quantum information techniques. With Al+ “quantum-logic” clocks, the current accuracy of 8.6×10-18 has enabled a geo-potential-difference measurement that detected a height change of 37±17 cm due to the gravitational red-shift. We have also observed quantum coherence between two Al+ ions with a record Q-factor of 3.4×1016, and compared the Al+ resonance frequency to that of a single Hg+ ion to place limits on the temporal variation of the fine-structure constant.

•Jul 13, 2011•0 citations
Local magnetic field strength in a trapped ion atomic clock is measured in real time, with high accuracy and without degrading clock performance, and the measurement is used to compensate for ambient magnetic field perturbations. First and second isotopes of an element are co-located within the linear ion trap. The first isotope has a resonant microwave transition between two hyperfine energy states, and the second isotope has a resonant Zeeman transition. Optical sources emit ultraviolet light that optically pump both isotopes. A microwave radiation source simultaneously emits microwave fields resonant with the first isotope's clock transition and the second isotope's Zeeman transition, and an optical detector measures the fluorescence from optically pumping both isotopes. The second isotope's Zeeman transition provides the measure of magnetic field strength, and the measurement is used to compensate the first isotope's clock transition or to adjust the applied C-field to reduce the effects of ambient magnetic field perturbations.
The use of the mercury ion isotope (201)Hg(+) was examined for an atomic clock. Taking advantage of the faster optical pumping time in (201)Hg(+) reduces both the state preparation and the state readout times, thereby decreasing the overall cycle time of the clock and reducing the impact of medium-term LO noise on the performance of the frequency standard. The spectral overlap between the plasma discharge lamp used for (201)Hg(+) state preparation and readout is much larger than that of the lamp used for the more conventional (199)Hg(+). There has been little study of (201)Hg(+) for clock applications (in fact, all trapped ion clock work in mercury has been with (199)Hg(+); however, recently the optical pumping time in (201)Hg(+) has been measured and found to be 0.45 second, or about three times faster than in (199)Hg(+) due largely to the better spectral overlap. This can be used to reduce the overall clock cycle time by over 2 seconds, or up to a factor of 2 improvement. The use of the (201)Hg(+) for an atomic clock is totally new. Most attempts to reduce the impact of LO noise have focused on reducing the interrogation time. In the trapped ion frequency standards built so far at JPL, the optical pumping time is already at its minimum so that no enhancement can be had by shortening it. However, by using (201)Hg(+), this is no longer the case. Furthermore, integrity monitoring, the mechanism that determines whether the clock is functioning normally, cannot happen faster than the clock cycle time. Therefore, a shorter cycle time will enable quicker detection of failure modes and recovery from them.
Trapped mercury ion is a promising candidate for portable and operational atomic clocks. It operates at the 40.5GHz ground state hyperfine transition of 199Hg ions. Mercury ions are confined in a linear RF trap, buffer-gas cooled, with a long ion storage lifetime in an ultra-high vacuum enclosure without an active pump. The clock transition is optically-pumped and detected with a Hg discharge lamp without need of a laser light source. This approach has proven to provide simplicity in design and implementation and robustness in operation. In this paper, we report our recently effort on developing a micro and low-power mercury trapped ion clock in the DARPA ACES program. In a 5 mm x 10 mm linear trap (0.25 cc), we have achieved the clock fractional frequency stability of .7 × 10-12τ-1/2and reached down to 7 × 10-14after 1000 seconds of averaging. We will discuss the clock performance under different conditions and implications toward a micro mercury trapped ion clock with low power and high stability.
A high-performance frequency standard based on (199)Hg(+) ions confined in a hybrid radio frequency (RF)/dc linear ion trap is demonstrated. This trap permits storage of large numbers of ions with reduced susceptibility to the second-order Doppler effect caused by the RF confining fields. A 160-mHz-wide atomic resonance line for the 40.5-GHz clock transition is used to steer the output of a 5-mHz crystal oscillator to obtain a stability of 2 x 10(exp -15) for 24,000-second averaging times. Measurements with a 37-mHz line width for the Hg(+) clock transition demonstrate that the inherent stability for this frequency standard is better than 1 x 10(exp -15) at 10,000-second averaging times.
Characterization of the trap rf induced a.c. Zeeman shift is essential for achieving high accuracy in optical ion clocks. In this work, we demonstrate the experimental characterization of this shift using highly charged Ca14+\mathrm{Ca}^{14+}Ca14+. The transverse component of the a.c. magnetic field is measured using the Autler-Townes splitting of the equally-spaced Zeeman components of the 3P1^{3}\mathrm{P}_13P1​ when the Zeeman splitting is close to resonance with the trap rf drive frequency. We observe the resulting modulation by performing quantum logic spectroscopy using the co-trapped Be+\mathrm{Be}^{+}Be+. The longitudinal component is measured from probing the Be+\mathrm{Be}^{+}Be+ magnetic field-insensitive hyperfine transition ∣F=2,mF=0⟩→∣F=1,mF=0⟩|F=2,m_F=0 \rangle \rightarrow | F=1,m_F=0 \rangle∣F=2,mF​=0⟩→∣F=1,mF​=0⟩. We confirm the small influence of the a.c. Zeeman shift in highly charged ions. The employed techniques can easily be transferred to other multi-level atomic systems.
As part of an on-going effort to build a dual-isotope ion trap clock based on the199Hg+and201Hg+ground state hyperfine transitions, we continue to characterize the systematic sensitivities of the201Hg+29.9GHz clock transition. Here we present an extension to the previous201Hg+collision shift measurement for helium[1] to other background gases. We also measured the collision shifts in the199Hg+40.5GHz clock transition in the same physical system. We find that frequency sensitivities to collisions with background gas for the two isotopes agree within a factor of two. We will also discuss planned collision shift measurements with co-trapped199Hg+and201Hg+, as an important step towards a dual-isotope atomic clock.
Laser-cooled trapped atoms have long been recognized as potentially very accurate frequency standards for clocks. Ultimate accuracies of 10-18 to 10-19 appear possible, limited by the time-dilation of trapped ions that move at laser-cooled velocities. The Al+ ion is an attractive candidate for high accuracy, owing to its narrow electronic transition in the optical regime and low sensitivity to ambient field perturbations. Precision spectroscopy on Al+ is enabled by quantum information techniques. With Al+ “quantum-logic” clocks, the current accuracy of 8.6×10-18 has enabled a geo-potential-difference measurement that detected a height change of 37±17 cm due to the gravitational red-shift. We have also observed quantum coherence between two Al+ ions with a record Q-factor of 3.4×1016, and compared the Al+ resonance frequency to that of a single Hg+ ion to place limits on the temporal variation of the fine-structure constant.