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CRC Press eBooks

Quantum-classical correspondence for the kinetic energy

Ian P. Hamilton, Ricardo Antonio Mosna, Luigi Delle Site

Published Oct 27, 2006• 0 citations
Publisher
DOI
10.1201/b12066-63

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We propose an approach to quantum–classical correspondence based on a deformation of the momentum and kinetic operators of quantum mechanics. Making use of the factorization method, we construct classical versions of the momentum and kinetic operators which, in addition to the standard quantum expressions, contain terms that are functionals of the N -particle density. We show that this implementation of quantum–classical correspondence is related to Witten's deformation of the exterior derivative and Laplacian, introduced in the context of supersymmetric quantum mechanics. The corresponding deformed action is also shown to be related to the Fisher information. Finally, we briefly consider the possible relevance of our approach to the construction of kinetic-energy density functionals.

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arXiv:1512.05083•European Journal of Physics•May 16, 2016•12 citations
We propose an approach to quantum–classical correspondence based on a deformation of the momentum and kinetic operators of quantum mechanics. Making use of the factorization method, we construct classical versions of the momentum and kinetic operators which, in addition to the standard quantum expressions, contain terms that are functionals of the N -particle density. We show that this implementation of quantum–classical correspondence is related to Witten's deformation of the exterior derivative and Laplacian, introduced in the context of supersymmetric quantum mechanics. The corresponding deformed action is also shown to be related to the Fisher information. Finally, we briefly consider the possible relevance of our approach to the construction of kinetic-energy density functionals.
Quantum-classical correspondence is affirmed via performing Wigner function and a classical-quantum chaotic system containing random variables. The classical-quantum system is transformed into a Kolmogorov model for force and energy analysis. Combining different forces, the system is divided into two categories: conservative and non-conservative, revealing the mechanical characteristic of the classical-quantum system. The Casimir power, an analysis tool, is employed to find the key factors governing the orbital trajectory and the energy cycle of the system. Detailed analyses using the Casimir power and an energy transformation uncover the causes of the different dynamic behaviors, especially chaos. For the corresponding classical Hamiltonian system when Planck’s constant ħ → 0, the supremum bound of the system is derived analytically. Difference between the classical-quantum system and the classical Hamiltonian system is displayed through trajectories and energies. Quantum-classical correspondences are further demonstrated by comparing phase portrait, kinetic, potential and Casimir energies of the two systems.