I start by briefly overviewing quantum mechanics as it is standardly formulated and by discussing the question of whether this standard formulation needs to be supplemented by an interpretation. The overview is based mainly on Von Neumann (1932, 1955) and its aim is not to give the reader a crash course in quantum mechanics, but to present those parts of the standard formalism which I use in this book. For a more complete treatment, the reader may consult the standard textbooks on quantum mechanics or, for instance, Sudbery (1986) or Redhead (1987). The standard formulation The standard formulation of quantum mechanics can be introduced in four steps. The first step is that in quantum mechanics one describesthe physics of a system by means of a Hilbert space ℋ. This Hilbert space is a complex linear vector space on which an inner product is defined. Let's adopt the convention (please consult the Glossary at the end of the book for notational conventions) that α refers to a system and that is the Hilbert space that is associated with this system. Let ∣ℋ α 〉 denote a vector in ℋ α and let 〈ψ α ∣φ α 〉 be the inner product between the vectors ∣ψ α 〉 and ∣φ α 〉.
I start by briefly overviewing quantum mechanics as it is standardly formulated and by discussing the question of whether this standard formulation needs to be supplemented by an interpretation. The overview is based mainly on Von Neumann (1932, 1955) and its aim is not to give the reader a crash course in quantum mechanics, but to present those parts of the standard formalism which I use in this book. For a more complete treatment, the reader may consult the standard textbooks on quantum mechanics or, for instance, Sudbery (1986) or Redhead (1987). The standard formulation The standard formulation of quantum mechanics can be introduced in four steps. The first step is that in quantum mechanics one describesthe physics of a system by means of a Hilbert space ℋ. This Hilbert space is a complex linear vector space on which an inner product is defined. Let's adopt the convention (please consult the Glossary at the end of the book for notational conventions) that α refers to a system and that is the Hilbert space that is associated with this system. Let ∣ℋ α 〉 denote a vector in ℋ α and let 〈ψ α ∣φ α 〉 be the inner product between the vectors ∣ψ α 〉 and ∣φ α 〉.
Quantum mechanics is like a pot: it is almost indestructible and extremely rigid, but also very flexible because you can use any ingredients for your soup. Göran Lindblad Quantum mechanics Although our first four chapters have been very mathematical, quantum mechanics has never been very far away. Let us recall how the mathematical structure of quantum mechanics is usually summarized at the end of a first course in the subject. First of all the pure states are given by vectors in a Hilbert space. If that Hilbert space is finite dimensional it is simply the vector space equipped with a scalar product of the particular kind that we called a Hermitian form in Eq. (3.82). Actually a pure state corresponds to an entire equivalence class of vectors; this is usually treated in such a way that the vectors are normalized to have length one and afterwards vectors differing by an overall phase e iø are regarded as physically equivalent. In effect then the space of pure states is the complex projective space; as always in this book n = N – 1. The notation used in quantum mechanics differs from what we have used so far. We have denoted vectors in by Z α , while in quantum mechanics they are usually denoted by a ket vector. We can think of the index α as just a label telling us that Z α is a vector, and then these two notations are in fact exactly equivalent.
The mathematical formalism of quantum theory in terms of vectors and operators in infinite-dimensional complex vector spaces is very abstract. The definitions of many mathematical quantities used do not seem to have an intuitive meaning, which makes it difficult to appreciate the mathematical formalism and understand quantum mechanics. This book provides intuition and motivation to the mathematics of quantum theory, introducing the mathematics in its simplest and familiar form, for instance, with three-dimensional vectors and operators, which can be readily understood. Feeling confident about and comfortable with the mathematics used helps readers appreciate and understand the concepts and formalism of quantum mechanics. This book is divided into four parts. Part I is a brief review of the general properties of classical and quantum systems. A general discussion of probability theory is also included which aims to help in understanding the probability theories relevant to quantum mechanics. Part II is a detailed study of the mathematics for quantum mechanics. Part III presents quantum mechanics in a series of postulates. Six groups of postulates are presented to describe orthodox quantum systems. Each statement of a postulate is supplemented with a detailed discussion. To make them easier to understand, the postulates for discrete observables are presented before those for continuous observables. Part IV presents several illustrative applications, which include harmonic and isotropic oscillators, charged particle in external magnetic fields and the Aharonov–Bohm effect. For easy reference, definitions, theorems, examples, comments, properties and results are labelled with section numbers. Various symbols and notations are adopted to distinguish different quantities explicitly and to avoid misrepresentation. Self-contained both mathematically and physically, the book is accessible to a wide readership, including astrophysicists, mathematicians and philosophers of science who are interested in the foundations of quantum mechanics.
Abstract This book provides the reader with a contemporary and comprehensive introduction to Quantum Mechanics. It is suitable for beginners as well as for more advanced university students. Quantum mechanics is presented in a pedagogical fashion, with a clear logical organization. The various concepts and methods are introduced first in elementary terms, and later developed into more precise formulations. Systematic studies of approximation methods and the discussion of a wide class of physical applications follow. Part I of the book, together with the opening sections of Part II, provide adequate material for an introductory course of one semester at most universities. The rest of the book might be used in an advanced course on Quantum Mechanics. The basic material is fairly standard, even though some discussions such as those on general systems with time-dependent Hamiltonians, on metastable systems, as well as the discussions in some of the Complement sections, may not be found in other textbooks. The book also contains many original observations or new ways of illustrating even well-known subjects. In fact, the authors wish to convey in this book the sense of wonder in the logical simplicity and at the same time the beauty of subtle and far-reaching consequences of Quantum Mechanics, to young physics students in particular. Problem sets are provided at the end of each chapter, to be solved either analytically or by numerical methods. The solutions to both types of problems are given as separate pdf files or as Mathematica notebooks (there are 88 of them), all together on a CD accompanying the textbook. The presence of such a collection of numerical analyses enriches the main text and is one of the characteristic features of the book. With the many interesting systems discussed, the book will also be a useful reference for researchers and teachers. It provides the reader with a unique, enjoyable and rather complete textbook of Quantum Mechanics, destined to set a new standard for many years to come.
The aim of this chapter is to present (in a compact way) the fundamentals of conventional quantum theory. We select the for- mulation of QM as an axiomatic theory in the complete accordance with the Hilbert’s program on axiomatization of physical theories. We remark that the first step toward the present formulation of QM was done in the seminal work of Hilbert, Nordheim, and von Neumann [112]. This work was substantially extended, completed, and clarified in the book of von Neumann [296]. Another version of the rigorous mathematical approach to QM was presented in the book of Dirac [74]. From the mathematical viewpoint, the main difference between the approaches of von Neumann and Dirac is that the first one is based on the theory of self-adjoint operators in complex Hilbert space and the second one is based on the theory of self-adjoint operators acting (by using the modern mathematical terminology) in rigged Hilbert spaces. This theory operates with generalized eigenvectors belonging to the spaces of distributions. Although the von Neumann’s formalization of QM became dominant in quantum mathematical physics, the Dirac’s formalization is widely used in the works on the physical level of rigorousness. Moreover, the Dirac’s terminology, bra-and ket- vectors, became the standard for quantum information theory. However, since quantum information is based on the castrated version of QM, namely, QM in finite-dimensional Hilbert spaces, the so-called n-qubit spaces, the basic tool of the Dirac’s formalism, usage of generalized eigenvectors, is useless (since in the finite- dimensional case everything is reduced to manipulation with matrices). During the last 80 years, there were written hundreds of books on QM enlightening its foundational aspects. Unfortunately, the majority of these writings advertise exotic (and some of them really esoteric) views on QM and, in particular, on interpretation of the wave function. They are full of such terms as the collapse of the wave function, quantumnonlocality, manyworlds, thewave function of universe, the preparation of Schro¨dinger cats, influence of the future on the past, quantum teleportation. Of course, manipulations with such terminology create an atmosphere of mystery and a feeling that something unusual and impossible can happen. And this atmosphere plays a positive role in attracting young people to QM and especially to quantum foundations.
From here, we take up the task of reformulating quantum mechanics in the language of inner product space. We start by introducing vector space through the familiar example of a set of finite dimensional, complex, column matrices under addition and multiplication by scalars. The inner product is then introduced as a dot product generalized to complex vectors leading to the idea of an inner product space . This is adequate to show how the concept of a quantum state can be described by a normalized vector in an inner product space so that the state space can be identified with the inner product space. Amplitudes are associated with inner products , and observables with orthonormal bases in this space. Hence the laws of quantum mechanics are reformulated. We then point out that the now reformulated laws are independent of the space of description and the reader is urged to contemplate an universality which would reflect the independence with respect to the representation space . This creates the stage for the introduction of the abstract inner product space and the formulation of quantum mechanics in this setting. The chapter concludes with this description. The transformed laws are now called postulatesof quantum mechanics .
We summarize below some of the postulates and definitions basic to our formalism, and present some important results based on these postulates. The formalism is purely mathematical in nature with very little physics input, but it provides the structure within which the physical concepts that will be discussed in the later chapters will be framed. State vectors It is important to realize that the Quantum Theory is a linear theory in which the physical state of a system is described by a vector in a complex, linear vector space. This vector may represent a free particle or a particle bound in an atom or a particle interacting with other particles or with external fields. It is much like a vector in ordinary three-dimensional space, following many of the same rules, except that it describes a very complicated physical system. We will be elaborating further on this in the following. The mathematical structure of a quantum mechanical system will be presented in terms of the notations developed by Dirac. A physical state in this notation is described by a “ket” vector, |〉, designated variously as |α〉 or |ψ〉 or a ket with other appropriate symbols depending on the specific problem at hand. The kets can be complex. Their complex conjugates, |〉 * , are designated by 〈| which are called “bra” vectors. Thus, corresponding to every ket vector there is a bra vector. These vectors are abstract quantities whose physical interpretation is derived through their so-called “representatives” in the coordinate or momentum space or in a space appropriate to the problem under consideration.