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A century of Bose-Einstein condensation

Nick P. Proukakis

Published Jul 1, 2025• 0 citations
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Abstract

© The Author(s) 2025.Bose-Einstein Condensation is a phenomenon at the heart of many of the past century’s most intriguing and fundamental manifestations, such as superfluidity and superconductivity: it was discovered theoretically some 100 years ago, and unequivocally experimentally demonstrated in the context of weakly-interacting gases 30 years ago. Since then, it has revolutionised our understanding of the collective quantum behaviour of matter. Such a phenomenon manifests itself across all physical scales, from the nuclear and atomic, all the way to the astrophysical, and has paved the way for novel technological applications.

DOI
10.25405/ncl.34530735

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© The Author(s) 2025.Bose-Einstein Condensation is a phenomenon at the heart of many of the past century’s most intriguing and fundamental manifestations, such as superfluidity and superconductivity: it was discovered theoretically some 100 years ago, and unequivocally experimentally demonstrated in the context of weakly-interacting gases 30 years ago. Since then, it has revolutionised our understanding of the collective quantum behaviour of matter. Such a phenomenon manifests itself across all physical scales, from the nuclear and atomic, all the way to the astrophysical, and has paved the way for novel technological applications.
Bose-Einstein Condensation is a phenomenon at the heart of many of the past century's most intriguing and fundamental manifestations, such as superfluidity and superconductivity: it was discovered theoretically some 100 years ago, and unequivocally experimentally demonstrated in the context of weakly-interacting gases 30 years ago. Since then, it has revolutionised our understanding of the collective quantum behaviour of matter. Such a phenomenon manifests itself across all physical scales, from the nuclear and atomic, all the way to the astrophysical, and has paved the way for novel technological applications.
As was shown by Einstein in 1924, Bose-Einstein statistics gives rise to a phase transition in which a macroscopic part of a gaseous state condenses into a phase with ground state properties, offering a unique view on the behavior of matter at zero temperature. From the very start the nature of Bose-Einstein condensation (BEC) has provoked statements concerning its relation with respect to superconductivity in electron gases (Einstein 1925) and the superfluidity of liquid helium (London 1938), but this connection is not easily grasped experimentally. Remarkably, although the concept of BEC appears routinely in very different contexts, ranging from excitons in semiconductors to nuclear matter, it had never been observed in its pure form, i.e., in a gaseous phase, until in 1995 BEC in ultracold Rb vapor was reported by Cornell and Wieman. Bose-Einstein condensation is probably the most exciting phenomenon currently under experimental investigation in ultracold atomic gases. In the tutorial the physics will be addressed which is at the roots of the current interest of BEC in atomic gases.
The study of Bose-Einstein condensation has undergone a remarkable expansion during the last twenty years. Observations of this phenomenon have been reported in a number of diverse atomic, optical, and condensed matter systems, facilitated by remarkable experimental advances. The synergy of experimental and theoretical work in this broad research area is unique, leading to the establishment of Bose-Einstein condensation as a universal interdisciplinary area of modern physics. This chapter reviews the broad expansion of Bose-Einstein condensation physics in the past two decades. Introduction The field of Bose-Einstein condensation (BEC) has undergone an explosive expansion during the past twenty years. Newcomers to this field are now often introduced to this as a universal phenomenon, which nonetheless exhibits diverse (and sometimes strikingly different) manifestations. Despite such differences, the common underlying theme creates a unique identity across many different energy and length scales. The study of BEC as a universal phenomenon was highlighted in a focused conference in 1993, leading to the publication of the well-known “green book” [1], which surveyed the breadth of the field of condensate physics at that time. The success of the conference led to a second meeting in 1995, at which Eric Cornell and Carl Wieman announced the achievement of Bose-Einstein condensation of ultracold 87 Rb atoms in a harmonic trap. That work began an explosion of new research in the field of cold atoms, which has continued to this day, and this very success inevitably led many of those studying cold atoms to pay less attention to other types of condensates. Wolfgang Ketterle gives a historical overview of this exciting period of time in Chapter 3. Recently, various scientific meetings have worked to re-establish the physical connections across different BEC systems, and in 2013 a workshop was held with the focused goal of improving communications across disciplines. This present book is an outgrowth of that meeting. The Situation Before the Revolution Because of the great success of the cold atom BEC and other BEC systems in the past twenty years, it may be hard for young scientists to understand the climate of BEC research in the early 1990s. At that time, there was only one known example of BEC, namely liquid helium-4, and there was a small but vocal minority of scientists who questioned whether BEC was established even in that system.
Bose–Einstein condensation was predicted in 1925 [Ein24, Ein25] but, except for its indirect manifestation in the superfluidity of He 4 [Lon38, Kap38, AllMis38], it remained a purely theoretical construct until 1995, when condensation in alkali gases was achieved in the laboratory [CorWie02, Ket02]. Since then, a great deal of the theoretical work in the previous 70 years has been put to the experimental test, while new avenues have been opening up, such as the superfluid-insulator or Mott transition [FWGF89, GMEHB02, CaHuRe06], the BEC-BCS cross-over [Leg06, Reg04] and the Tonks gas regime [Gir60, Par04]. Because of the great experimental control over the relevant parameters and the deep understanding of the fundamental physics, BECs have become a field of choice to perform experiments of interest not just in atomic and molecular physics, but also in quantum optics, condensed matter physics, quantum critical dynamics, even field theory, gravitation, cosmology and black hole physics [CoEnWi99, PetSmi02, Sou02, BonSen04, ParZha93, ParZha95, UnrSch07, BaLiVi05]. Moreover, cold Bose gases on optical lattices have been proposed as a possible implementation of a quantum information processing (QIP) device [JakZo104], boosting new interest in these systems. As introductions and reviews on this fast evolving subject abound, it is perhaps more fitting for us to focus on certain aspects of the nonequilibrium field theory of BEC, specifically [And04] the application of quantum field theoretic methods described in this book to the description of nonequilibrium evolution of condensed gases in magneto-optical traps [ChCoPh95].
The phenomenon of Bose-Einstein condensation (BEC), first predicted by Einstein 70 years ago, has finally been observed in the laboratory. In this elusive state of matter the concept of individual particles ceases to have meaning: the atoms condense into the same quantum state and act as a single entity that displays quantum mechanical behaviour on a macroscopic scale. The condensate was observed when Eric Cornell, Carl Wieman and colleagues at the Joint Institute for Laboratory Astrophysics in Boulder, Colorado, cooled a dilute gas of rubidium atoms, confined in a magnetic trap, to a temperature of just a few nanoKelvin (M H Anderson et al. 1995 Science 269 198).
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.