Abstract Rydberg states have become essential in neutral-atom quantum computing as a way of coupling otherwise weakly interacting qubits. Storing information in relatively stable, compact ground states while using large excited states as temporary interaction resources is one of the key lessons that atomic Rydberg physics offers to other quantum platforms. Semiconductor spin qubits provide a very different route to quantum information processing. Their appeal lies in their small footprint, long spin coherence, compatibility with mature fabrication techniques, and potential integration with classical electronics. However, semiconductor architectures also face challenges: interactions are often short-ranged, individual addressing and wiring become increasingly complex at scale, and devices are sensitive to disorder, interfaces, strain, and charge noise. These difficulties motivate the search for other mechanisms that can enhance coupling or provide new readout and control channels without sacrificing advantages. Dopant-bound Rydberg states offer one such possibility. Shallow donors and acceptors in semiconductors possess hydrogenic excited states whose spatial extent and electric-dipole moments are much larger than those of their ground states. These states can be accessed by THz radiation and have already been studied extensively through impurity spectroscopy and, more recently, coherent-control experiments. In analogy with neutral-atom platforms, they need not serve as long-lived qubits themselves. Rather, they may act as auxiliary states that temporarily enhance interactions or provide new qubit control and readout pathways. In this chapter, we review dopant-bound Rydberg states from this perspective.
Abstract Rydberg states have become essential in neutral-atom quantum computing as a way of coupling otherwise weakly interacting qubits. Storing information in relatively stable, compact ground states while using large excited states as temporary interaction resources is one of the key lessons that atomic Rydberg physics offers to other quantum platforms. Semiconductor spin qubits provide a very different route to quantum information processing. Their appeal lies in their small footprint, long spin coherence, compatibility with mature fabrication techniques, and potential integration with classical electronics. However, semiconductor architectures also face challenges: interactions are often short-ranged, individual addressing and wiring become increasingly complex at scale, and devices are sensitive to disorder, interfaces, strain, and charge noise. These difficulties motivate the search for other mechanisms that can enhance coupling or provide new readout and control channels without sacrificing advantages. Dopant-bound Rydberg states offer one such possibility. Shallow donors and acceptors in semiconductors possess hydrogenic excited states whose spatial extent and electric-dipole moments are much larger than those of their ground states. These states can be accessed by THz radiation and have already been studied extensively through impurity spectroscopy and, more recently, coherent-control experiments. In analogy with neutral-atom platforms, they need not serve as long-lived qubits themselves. Rather, they may act as auxiliary states that temporarily enhance interactions or provide new qubit control and readout pathways. In this chapter, we review dopant-bound Rydberg states from this perspective.
In any physical platform, two ingredients are essential for quantum information processing: single-qubit control, and entangling interactions between qubits. Neutral atoms can be individually controlled with high fidelity and are resilient to environmental noise, making them attractive candidates for implementing quantum information protocols. However, achieving strong interactions remains a major obstacle. One way to increase the interaction strength between neutral atoms is to excite them into high-lying Rydberg states, which exhibit large electric dipole moments (and by extension, strong electric dipole-dipole interactions). By slowly ramping up the Rydberg level coupling in a system, one can "dress'' the atomic ground states with some Rydberg character; this maps the Rydberg dipole interaction to an effective interaction between ground states. Such Rydberg-dressed interaction is the focus of this dissertation. After describing the physics of the Rydberg-dressed interaction, we propose three protocols that demonstrate its versatility and provide a framework for considering some of the details of realistic implementation. In all three cases, Rydberg dressing --- along with some form of single-atom control --- is used to generate highly entangled states of interest. Our first proposal relates to the adiabatic model of quantum computing, in which solutions to problems are encoded in the ground states of carefully engineered Hamiltonians. The Rydberg-dressed interaction can provide nonlinear Hamiltonian terms, allowing us to encode NP-hard and other interesting problems. We model this protocol in the presence of decoherence, and find that computational fidelities of ~0.98 for four atoms should be possible with currently realistic experimental parameters. Our second proposal is also related to quantum computing, this time in the circuit model. The Rydberg-dressed interaction can be used to generate a controlled-NOT logic gate which, when interwoven with single-qubit gates, can perform universal quantum computation. Experimentally, noise due to atomic thermal motion has been a primary limitation on the fidelities of these gates. We show that a Doppler-free setup, with counterpropagating lasers, effectively suppresses this type of noise, allowing simulated fidelities of up to ~0.998 per gate. Such strong suppression is only possible because the Doppler-free configuration can harness the natural robustness of adiabatic dressing; other gate schemes using, e.g., resonant pulses, do not exhibit the same degree of improvement. Finally, we consider exploiting the many-body character of the Rydberg-dressed interaction to generate collective entanglement in mesoscopic ensembles of neutral atoms. An atomic ensemble uniformly illuminated by a single Rydberg-exciting laser is isomorphic to the well-known Jaynes-Cummings model. In addition to adapting generic Jaynes-Cummings entanglement protocols developed in other platforms, one can apply microwaves to drive entanglement in a way that is unique to the atomic platform. We prove that by allowing the microwave phase to vary in time, one can generate arbitrary symmetric states of the ensemble. While this method compares favorably with other entanglement protocols in many ways, the required frequency of phase switching presents a fundamental limitation on its effectiveness. To mitigate this, we propose a variant scheme in which parameters are chosen to only allow excitations within the system's dressed-ground subspace; this effectively cuts phase switching demands in half. All three protocols serve to illustrate the power of the Rydberg-dressed interaction and suggest directions for future study.
Introduction Series of atomic spectral lines had been studied by emission from excited vapors even before Balmer described the regularity of the visible lines of hydrogen in 1884. However, direct excitation had been restricted to the few lowest-lying levels, particularly those accessible by electric dipole transitions from the ground state using classical light sources. The advent of tunable lasers in the 1970s changed such spectroscopic limitations enormonsly, allowing excitation to a very much larger number of states. Atoms in highly excited states, typically with principal quantum numbers n ≥ 10, are called Rydberg atoms. They are oversize, fragile states of significant intrinsic interest. They are very rare in nature because of their size and fragility, but they are found in interstellar space (H I regions). One of the best sources for comprehensive descriptions of Rydberg atoms and references to the literature describing their exploration is Ref. [120]. It describes their characteristic properties and behavior both classically and quantum mechanically, and especially their strongly enhanced interactions with external fields. The first thing to note is that Rydberg atoms are usually characterized by a single, highly excited electron while all the other electrons remain in their original states. Thus their properties are very nearly classical, and the atoms are much closer to the ideal hydrogen-like model of Chap. 7, along with appropriate quantum defects (see Chap. 10). The spectroscopy of such states is especially interesting because the active electron is much less perturbed by the other electrons in the atom than when it is in lower states. Moreover, there are some special circumstances in which the energy of a Rydberg state is degenerate with an atomic state having two electrons excited to lower levels, and such configurations yield further new information. Second, Rydberg atoms do not usually decay back to the ground state by emission of characteristic radiation, so their study is mediated by other techniques that reveal new and interesting properties. Such properties arise because Rydberg atoms have a huge dipole moment and very low binding energy resulting from the large average distance between the excited electron and the nucleus-plus-core of the rest of the atom with net charge e . Third, transitions between Rydberg states are quite different from those connecting to the ground state for at least three reasons.
One of the great successes of quantum physics is the description of the long-lived Rydberg states of atoms and ions. The Bohr model is equally applicable to donor impurity atoms in semiconductor physics, where the conduction band corresponds to the vacuum, and the loosely bound electron orbiting a singly charged core has a hydrogen-like spectrum according to the usual Bohr–Sommerfeld formula, shifted to the far-infrared because of the small effective mass and high dielectric constant. Manipulation of Rydberg states in free atoms and ions by single and multiphoton processes has been tremendously productive since the development of pulsed visible laser spectroscopy. The analogous manipulations have not been conducted for donor impurities in silicon. Here, we use the FELIX pulsed free electron laser to perform time-domain measurements of the Rydberg state dynamics in phosphorus- and arsenic-doped silicon and we have obtained lifetimes consistent with frequency domain linewidths for isotopically purified silicon. This implies that the dominant decoherence mechanism for excited Rydberg states is lifetime broadening, just as for atoms in ion traps. The experiments are important because they represent a step toward coherent control and manipulation of atomic-like quantum levels in the most common semiconductor and complement magnetic resonance experiments in the literature, which show extraordinarily long spin lattice relaxation times—key to many well known schemes for quantum computing qubits—for the same impurities. Our results, taken together with the magnetic resonance data and progress in precise placement of single impurities, suggest that doped silicon, the basis for modern microelectronics, is also a model ion trap.
Rydberg atoms with principal quantum number n⪢1 have exaggerated atomic properties including dipole-dipole interactions that scale as n4 and radiative lifetimes that scale as n3. It was proposed a decade ago to take advantage of these properties to implement quantum gates between neutral atom qubits. The availability of a strong long-range interaction that can be coherently turned on and off is an enabling resource for a wide range of quantum information tasks stretching far beyond the original gate proposal. Rydberg enabled capabilities include long-range two-qubit gates, collective encoding of multiqubit registers, implementation of robust light-atom quantum interfaces, and the potential for simulating quantum many-body physics. The advances of the last decade are reviewed, covering both theoretical and experimental aspects of Rydberg-mediated quantum information processing.
Spin qubits have emerged as a leading platform for quantum information processing due to their long coherence times, small footprint, and compatibility with the existing semiconductor industry. We first provide an introduction to the different qubit implementations currently being investigated, including single electron-spin qubits, hole-spin qubits, donor qubits, and multispin encodings. We discuss how the confinement and strain present in semiconductor heterostructures produce addressable levels whose spin degree of freedom can be used to encode a qubit. A large emphasis is placed on reviewing the theoretical foundations and recent experimental demonstrations of proposed mechanisms for long-range coupling, including hybrid approaches based on circuit QED and Andreev qubits, as well as spin shuttling. Finally, we review a recent proposal for linking spin qubits using topological spin textures.
Neutral atom quantum computing utilizes laser-trapped neutral atoms as qubits and realizes quantum logic gate operations through Rydberg-state interactions. In recent years, it has become one of the most vibrant directions in quantum computing hardware. This paper systematically reviews the working principles of neutral-atom quantum computers, including qubit encoding, atom trapping and manipulation, Rydberg states and interactions, the Rydberg blockade quantum gate mechanism, and atom rearrangement with reconfigurable architectures. The mainstream technical routes are surveyed, represented by optical tweezer arrays combined with Rydberg interactions, optical lattice schemes, and dipole trap arrays. A panoramic review is provided of domestic and international research progress from theoretical foundations in 2000 to the latest achievements in 2026, including thousand-qubit-scale systems, logical qubits, and quantum error correction experiments. Key breakthroughs are highlighted, such as the 6100-atom qubit array, continuous operation of a 3000-qubit system, quantum simulation of the Kitaev honeycomb model, toric code error correction demonstrations, encoding rates exceeding 1/2, and fault-tolerant architectures. The core bottlenecks are analyzed in depth, including the scalability--fidelity trade-off, engineering implementation of quantum error correction, atom loss and mid-circuit replenishment, laser system industrialization, control electronics scalability, and long-distance quantum interconnection. This paper aims to provide a systematic reference for academic research and technological development in this field.