The condensation of photons in a dye-filled optical microcavity represents a landmark achievement in macroscopic quantum phenomena, bridging quantum optics and statistical mechanics. While ordinary Bose-Einstein condensation (BEC) of massive particles is governed by well-established critical exponents, photon condensation occurs in an open, dissipative system where thermalization is mediated through repeated absorption and re-emission cycles by dye molecules. In this paper, we systematically investigate whether photon condensation exhibits independent critical exponents. We define the scaling of the condensed photon density as n_gamma proportional to |T - T_c|^(beta_gamma) and examine whether the critical exponent beta_gamma deviates significantly from the classical values associated with standard three-dimensional or trapped two-dimensional Bose systems. Through a rigorous theoretical formulation based on master equations, grand canonical statistical mechanics, and renormalization group techniques, we explore the universal properties of this light-matter phase transition. Establishing a distinct set of critical exponents for photon condensation could lay the foundational stone for a new universal class of non-equilibrium quantum phase transitions, offering profound implications for fundamental physics and advanced quantum technologies.
The condensation of photons in a dye-filled optical microcavity represents a landmark achievement in macroscopic quantum phenomena, bridging quantum optics and statistical mechanics. While ordinary Bose-Einstein condensation (BEC) of massive particles is governed by well-established critical exponents, photon condensation occurs in an open, dissipative system where thermalization is mediated through repeated absorption and re-emission cycles by dye molecules. In this paper, we systematically investigate whether photon condensation exhibits independent critical exponents. We define the scaling of the condensed photon density as n_gamma proportional to |T - T_c|^(beta_gamma) and examine whether the critical exponent beta_gamma deviates significantly from the classical values associated with standard three-dimensional or trapped two-dimensional Bose systems. Through a rigorous theoretical formulation based on master equations, grand canonical statistical mechanics, and renormalization group techniques, we explore the universal properties of this light-matter phase transition. Establishing a distinct set of critical exponents for photon condensation could lay the foundational stone for a new universal class of non-equilibrium quantum phase transitions, offering profound implications for fundamental physics and advanced quantum technologies.
Bose-Einstein condensation (BEC) is the transition to a macroscopic occupation of the ground state of a system of bosonic particles. In 1995 the first experimental realization of BEC was achieved by condensing a dilute atomic gas [1,2]. It was long thought only massive particles could undergo BEC. However, in 2010 it was shown that photon BEC was achieved in an optical dye-filled microcavity [3]. In 2015, we became the second group to successfully repeat these experiments.\n\nBEC is a phase transition and thus it occurs at thermal equilibrium. To achieve a thermal photon gas the cavity is filled with a fluorescent dye solution. The dye molecules thermalize the photons by means of repeated absorption-emission cycles. We optically pump the cavity. With the pump we determine the number of photons absorbed by the dye, consequently defining a nonvanishing chemical potential. This ensures a conserved photon number. The photons are trapped by the harmonic potential induced by the concave cavity mirrors. Due to the cutoff energy determined by the cavity length, the trapped photons have a dispersion similar to that of a massive particle in a quantum harmonic oscillator. The cavity length is tuned such that the free spectral range is larger than the bandwidth of the dye. Therefore, only one longitudinal mode fits inside the cavity, making the photon gas effectively two-dimensional. We end up with a thermalized two-dimensional photon gas that has the eigenenergies of a quantum harmonic oscillator. The Bose-Einstein distribution function predicts a critical photon number. Pumping the thermal photon gas beyond this critical number will lead to photon BEC.\n\nWe measure the spectral- and spatial distributions of our two-dimensional photon gas. In both distributions we observe photon BEC. Results show the characteristics of a phase transition: the appearance of a sharp peak on top of the thermal cloud that coincides with a converging chemical potential to zero. Both the spectral- and spatial distribution are in agreement with the theoretical distribution of photons with an effective mass in a quantum harmonic oscillator. Expansion of the condensate has been measured. This could indicate nonlinear optical effects such as thermal lensing or repulsive photon-photon interactions.
A theory of Bose-Einstein condensation of light in a dye-filled optical microcavity is presented. The theory is based on the hierarchical maximum entropy principle and allows one to investigate the fluctuating behavior of the photon gas in the microcavity for all numbers of photons, dye molecules, and excitations at all temperatures, including the whole critical region. The master equation describing the interaction between photons and dye molecules in the microcavity is derived and the equivalence between the hierarchical maximum entropy principle and the master equation approach is shown. The cases of a fixed mean total photon number and a fixed total excitation number are considered, and a much sharper, nonparabolic onset of a macroscopic Bose-Einstein condensation of light in the latter case is demonstrated. The theory does not use the grand canonical approximation, takes into account the photon polarization degeneracy, and exactly describes the microscopic, mesoscopic, and macroscopic Bose-Einstein condensation of light. Under certain conditions, it predicts sub-Poissonian statistics of the photon condensate and the polarized photon condensate, and a universal relation takes place between the degrees of second-order coherence for these condensates. In the macroscopic case, there appear a sharp jump in the degrees of second-order coherence, a sharp jump and kink in the reduced standard deviations of the fluctuating numbers of photons in the polarized and whole condensates, and a sharp peak, a cusp, of the Mandel parameter for the whole condensate in the critical region. The possibility of nonclassical light generation in the microcavity with the photon Bose-Einstein condensate is predicted.
Bose-Einstein condensation, the macroscopic ground state occupation of a system of bosonic particles below a critical temperature, has been observed in cold atomic gases and solid-state physics quasiparticles. In contrast, photons do not show this phase transition usually, because in Planck's blackbody radiation the particle number is not conserved and at low temperature the photons disappear in the walls of the system. Here we report on the realization of a photon Bose-Einstein condensate in a dye-filled optical microcavity, which acts as a "white-wall" photon box. The cavity mirrors provide a trapping potential and a non-vanishing effective photon mass, making the system formally equivalent to a two-dimensional gas of trapped massive bosons. Thermalization of the photon gas is reached in a number conserving way by multiple scattering off the dye molecules. Signatures for a BEC upon increased photon density are: a spectral distribution that shows Bose-Einstein distributed photon energies with a macroscopically populated peak on top of a broad thermal wing, the observed threshold of the phase transition showing the predicted absolute value and scaling with resonator geometry, and condensation appearing at the trap centre even for a spatially displaced pump spot.
The study of second-order phase transitions is a broad research theme that provides fundamental insights into the physical nature of complex systems. A central aspect deals with the concept of universal behavior. Universality governs, for example, the diverging correlated fluctuations of an order parameter, characterized by a macroscopic correlation length ξ, as well as the divergence of other thermodynamic quantities near the critical point. Extracting the critical exponents associated with these diverging quantities shows that quite different physical systems can exhibit identical scaling behavior, placing them into common universality classes. Bose-Einstein condensation of an ideal (i.e., non-interacting) gas of bosons is a second-order phase transition, and thus provides a valuable platform to investigate universal critical behavior in the quantum gas regime, driven purely by quantum statistics rather than inter-particle interactions. While historically studied in ultracold atomic and molecular gases, Bose-Einstein condensation can now be realized in a two-dimensional photonic gas at room temperature using dye-filled microcavities. The microcavity imposes a low-energy cutoff, providing a non-vanishing ground state and an effective mass for the intracavity photons, which thermalize via repeated absorption and emission processes with the dye reservoir rather than inter-particle interactions. Consequently, this platform establishes an almost perfectly ideal, two-dimensional quantum gas of light. In combination with versatile trapping techniques, it provides a highly tunable platform to explore the thermodynamics of quantum gases. This thesis presents a quantitative study of spatial correlations in a uniformly trapped two-dimensional photon gas. The uniform confinement is achieved by a custom mirror-structuring technique, resulting in box-like trapping potentials. The temporal and spatial coherence properties of the gas are validated in both the thermal and condensed regimes using an interferometric measurement technique. Because the applicability of scanning interferometry limits measurements of critical scaling behavior, an alternative method is introduced to extract the first-order spatial coherence directly from the far-field angular distribution of the cavity emission in a single experimental shot. This technique enables the extraction of the spatial correlation length ξ and a precise evaluation of its scaling behavior in the vicinity of the critical point Nc. The measurements presented here demonstrate, for the first time, the determination of a critical exponent in the (ideal) Bose gas universality class. The obtained critical exponent of ν = 0.52 ± 0.04 for the two-dimensional ideal Bose gas is consistent with theoretical expectations. Crucially, this critical exponent is found to be robust and independent of the system size within experimental uncertainties, demonstrating the universality of the scaling behavior. Finally, the limits of this universal behavior are explored by demonstrating the breakdown of critical scaling when the thermalizing coupling between the photons and dye molecules in the cavity is reduced, driving the photon gas out of thermal equilibrium.
Bose-Einstein condensation is a state of matter for which massive bosons develop a macroscopic occupation of the ground state. After the theoretical discovery by Bose and Einstein, it took approximately 70 years to be experimentally realized using Rubidium-87 atoms. Ever since, many different species have been shown to Bose condense. The key in these experiments is cooling down atoms temperatures below 200 nK, while maintaining a large density. Despite all these species, it was thought that photons could not Bose condense. This changed in 2010 when the first Bose-Einstein condensate of photons (phBEC) was achieved. In a table top experiment photons are confined to a dye-filled microcavity where under the right conditions a thermalized photon gas is achieved. Using our setup, we quantitatively show from both the spectral and spatial distribution of photons in the microcavity that a macroscopic occupation of the ground state is achieved, i.e. a condensate of photons. The achievement of phBEC in a dye-filled microcavity has led to a renewed interest in the density distribution of the ideal Bose gas in a two-dimensional harmonic oscillator. We present measurements of the radial profile of photons inside the microcavity below and above the critical point for phBEC with a large signal-to-noise ratio. We obtain good agreement with theoretical profiles obtained using exact summation of eigenstates. An interesting open question is, whether the photons in the condensate are interacting or non-interacting and as a consequence, whether the condensate is also a superfluid or only forms a macroscopically occupied ground state, as predicted by Einstein. When increasing the photon density, we observe an increase in the radius of the condensate which we attribute to effective repulsive interactions. For several dye concentrations we accurately determine the radius of the condensate as a function of the number of condensate photons, and derive from the measurements an effective interaction strength. In many systems ranging from condensed matter physics and particle physics to cosmology, phase transitions and spontaneous symmetry breaking play a crucial role. The information of a polarized condensate from an unpolarized thermal cloud constitutes a directly observable prototype of spontaneous symmetry breaking. For every single-shot of the pump laser, we determine the Stokes parameters of the photons inside the microcavity which fully characterizes the polarization state of the sample. By varying experimental parameters, we investigate if the polarization is randomly chosen from shot-to-shot of the experiment. The dye-filled microcavity is a beautiful tool to achieve phBEC. However, it cannot provide the periodic potential required to achieve quantum phase transitions, such as the Mott insulator that have been so successfully exploited in the field of ultra-cold atoms. We use a local density approach to simulate large-area photonic crystal cavities. Clever interplay with both the electronic and photonic bandgap of these cavities has the potential of achieving phBEC in a periodic potential. We show that when the hole radius varies quadratically as a function of position, the eigenmodes of the photonic crystal can be described by the corresponding eigenmodes of the quantum harmonic oscillator.
A theory of Bose-Einstein condensation (BEC) of light in a dye microcavity is developed. The photon polarization degeneracy and the interaction between dye molecules and photons in all of the cavity modes are taken into account. The theory goes beyond the grand canonical approximation and allows one to determine the statistical properties of the photon gas for all numbers of dye molecules and photons at all temperatures, thus describing the microscopic, mesoscopic, and macroscopic light BEC from a general perspective. A universal relation between the degrees of second-order coherence for the photon condensate and the polarized photon condensate is obtained. The photon Bose-Einstein condensate can be used as a new source of nonclassical light.