Feshbach resonances, first studied in the context of nuclear reactions, have since become a cornerstone of modern atomic physics. They offer a remarkable degree of control over interatomic (and even intermolecular) interactions by tuning external magnetic fields. This tunability arises from the interplay between quantum scattering and the internal structure of atoms or nuclei. In this work, we explore the essential physics of Feshbach resonances using only basic quantum mechanics, aiming to make this powerful concept accessible to educators and students alike.
Feshbach resonances, first studied in the context of nuclear reactions, have since become a cornerstone of modern atomic physics. They offer a remarkable degree of control over interatomic (and even intermolecular) interactions by tuning external magnetic fields. This tunability arises from the interplay between quantum scattering and the internal structure of atoms or nuclei. In this work, we explore the essential physics of Feshbach resonances using only basic quantum mechanics, aiming to make this powerful concept accessible to educators and students alike.
Feshbach resonances, first studied in the context of nuclear reactions, have since become a cornerstone of modern atomic physics. They offer a remarkable degree of control over interatomic (and even intermolecular) interactions by tuning external magnetic fields. This tunability arises from the interplay between quantum scattering and the internal structure of atoms or nuclei. In this work, we explore the essential physics of Feshbach resonances using only basic quantum mechanics, aiming to make this powerful concept accessible to educators and students alike.
The research described in this thesis is part of an international effort with the aim of studying ultracold quantum degenerate gas samples like Bose-Einstein condensates and Fermi degenerate systems, consisting of atoms confined in magnetic or optical traps. The behavior of such samples is governed by the inter-atomic interactions and the resulting properties of the atom-atom scattering. At the relevant temperatures of 1nK to 10µK a key property is the atom-atom scattering length a. In chapter 2 a theoretical method is presented which enables one to describe the interaction and scattering of (ultra)cold atoms to unprecedented precision. It is also unparalleled in comprehensiveness: it allows the prediction of a large and varied set of experimental data for all isotopes of the same element. The method relies on the extraction from experiments of a few (phase) parameters which completely summarize the behavior of the atoms in the (ultra)cold regime. In chapter 3 the method is applied to the "workhorses" of cold-atom physics: the atomic species 85Rb and 87Rb. We extract the foregoing parameters to a very high precision from several recent high precision experiments, allowing us to predict e.g. the 87Rb spinor condensate to be ferromagnetic: a prediction for which the scattering length has to be calculated with a precision better than 1%. We also predict Feshbach resonances at experimentally accessible magnetic field strengths; resonances searched for and found by the experimental group of Rempe. In close collaboration with his group we "fine-tune" the interaction parameters found previously, by making use of only one of the observed resonances. We then obtain agreement with 42 out of the observed 43 resonance field strengths and are able to identify bound states inducing the Feshbach resonances at these locations. Chapter 4 describes the results of this research. With a thorough understanding of the rubidium interactions, we then switch to lithium which has a fermionic (6Li) and a bosonic (7Li) isotope. Both are being used in cold-atom experiments. In chapter 5 we evaluate the interaction parameters for lithium allowing us to predict magnetic field strengths for which a sample of fermionic 6Li atoms can be regarded as strongly interacting. Furthermore, a three-level method for measuring mean-field shifts, based on radio-frequency techniques, is introduced. For weak interactions we find proportionality of resonance shifts to interaction strengths. In the strongly interacting regime, however, these shifts become very small reflecting the quantum unitarity limit and many-body effects. Most interesting is the fact that in this regime the shifts are small both for large positive a and for large negative a, likely reflecting the universality of the interaction energy. In chapters 6 and 7 the interactions between lithium atoms are reinvestigated, making use of newly available experimental data and with the updated interaction parameters special attention is paid to locating field strengths at which magnetically tunable Feshbach resonances occur in the scattering of lithium atoms. In chapter 6 scattering events in a gas of (fermionic) 6Li atoms are studied. In chapter 7 we show that a consistent description of the 6Li+6Li system can be given. We discuss theoretical uncertainties for the position of the wide 6Li Feshbach resonance and present an analytic scattering model for this resonance, based on the inclusion of a field-dependent virtual open-channel state. We predict new Feshbach resonances for the 6Li-7Li system, and their importance for different types of crossover superfluidity models is discussed. Molecules created by magnetically sweeping over these resonances will have a fermionic character. One magnetic field strength is predicted at which two different fermionic molecules can be created simultaneously.
Scattering resonances are fundamental to many areas of physics, occurring across a wide range of energy scales. In ultracold quantum gases, magnetic Feshbach resonances have transformed quantum many-body research by enabling precise interaction control between atoms. Here, we demonstrate unprecedented control to engineer Feshbach resonances at tunable positions via Floquet driving in a lithium-6 (^{6}Li) atom gas, achieved through strong magnetic field modulation at megacycles per second frequencies. This periodic modulation creates scattering resonances whenever dressed molecular levels cross the atomic threshold. By adding a second modulation at twice the base frequency, we tune the asymmetry of resonance loss profiles and suppress two-body losses from Floquet heating. This technique enhances control over atomic interactions, expanding possibilities for quantum simulations of complex systems and studies of exotic quantum phases.
Feshbach resonance is a fundamental phenomenon in cold atomic physics, where interatomic interactions can be precisely changed into a scattering resonance by varying an external magnetic field. This effect plays a crucial role in ultracold atomic experiments, enabling the control of interaction strength, the formation of molecular bound states, and the realization of strongly correlated quantum systems. With the rapid development of cold atom experiments, numerous Feshbach resonances corresponding to different partial waves, such as s-wave, p-wave, and even higher partial wave ones, have been experimentally identified. While s-wave resonances have been widely utilized due to their isotropic nature and strong coupling, and higher partial-wave resonances (including p-wave and d-wave resonances), provide unique opportunities for exploring anisotropic interactions and novel quantum phases. In this study, by using the multichannel quantum defect theory (MQDT), we predict that two d-wave Feshbach resonances are existent in 7Li at 1039.24 G and 1055.64 G, repectively. Physical properties of the two resonances are presented, such as the resonance width and closed channel dimer energy. In addition, we optimize the computational parameters by using the Nelder-Mead algorithm and investigate the possible resonance splitting induced by dipole-dipole interactions in higher partial waves. The presence of these d-wave resonances at high magnetic fields provides a new platform for investigating the interplay between higher-order partial wave interactions and quantum many-body effects. Our results provide opportunities for investigating the effects of higher partial wave Feshbach resonances in high magnetic fields. Our theoretical predictions thus serve as a useful reference for future experimental studies of higher-order resonance phenomena in lithium and other atomic species.
Magnetically tunable Feshbach resonances exist in ultracold collisions between atoms in 2S and 3P0 states, such as an alkali-metal atom colliding with Yb or Sr in a clock state. We investigate the mechanisms of these resonances and identify the terms in the collision Hamiltonian responsible for them. They involve indirect coupling between the open and closed channels, via intermediate channels involving atoms in 3P1 states. The resonance widths are generally proportional to the square of the magnetic field and are strongly enhanced when the magnitude of the background scattering length is large. For any given pair of atoms, the scattering length can be tuned discretely by choosing different isotopes of the 3P0 atom. For each combination of an alkali-metal atom and either Yb or Sr, we consider the prospects of finding an isotopic combination that has both a large background scattering length and resonances at a high but experimentally accessible field. We conclude that 87Rb+Yb, Cs+Yb, and 85Rb+Sr are particularly promising combinations.
We present a simple technique for studying the collisions of ultracold atoms in the presence of a magnetic field and radiofrequency (rf) radiation. Resonant control of scattering properties can be achieved by using rf to couple a colliding pair of atoms to a bound state. We show, using the example of 6 Li, that in some ranges of rf frequency and magnetic field this can be done without giving rise to losses. We also show that halo molecules of large spatial extent allow resonant control with much less rf power than deeply bound states. Another way to exert resonant control is with a set of rf-coupled bound states, linked to the colliding pair through the molecular interactions that give rise to magnetically tunable Feshbach resonances. This was recently demonstrated for 87 Rb (Kaufman et al 2009 Phys. Rev. A 80 050701) [1]. We examine the underlying atomic and molecular physics that made this possible. Lastly, we consider the control that may be exerted over atomic collisions by placing atoms in superpositions of Zeeman states, and suggest that it could be useful where small changes in scattering length are required. We suggest other species for which rf and magnetic field control could together provide a useful tuning mechanism.