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arXiv:2503.05454 · Science Advances

Floquet engineering of Feshbach resonances in ultracold gases

Alexander Guthmann, Felix Lang, Louisa Marie Kienesberger, Sian Barbosa, Artur Widera

Published Oct 3, 2025• 3 citations
arXivHTMLPDF

Abstract

Scattering resonances are fundamental to many areas of physics, occurring across a wide range of energy scales. In ultracold quantum gases, magnetic Feshbach resonances have transformed quantum many-body research by enabling precise interaction control between atoms. Here, we demonstrate unprecedented control to engineer Feshbach resonances at tunable positions via Floquet driving in a lithium-6 (^{6}Li) atom gas, achieved through strong magnetic field modulation at megacycles per second frequencies. This periodic modulation creates scattering resonances whenever dressed molecular levels cross the atomic threshold. By adding a second modulation at twice the base frequency, we tune the asymmetry of resonance loss profiles and suppress two-body losses from Floquet heating. This technique enhances control over atomic interactions, expanding possibilities for quantum simulations of complex systems and studies of exotic quantum phases.

DOI
10.1126/sciadv.adw3856

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Scattering resonances are fundamental to many areas of physics, occurring across a wide range of energy scales. In ultracold quantum gases, magnetic Feshbach resonances have transformed quantum many-body research by enabling precise interaction control between atoms. Here, we demonstrate unprecedented control to engineer Feshbach resonances at tunable positions via Floquet driving in a lithium-6 (^{6}Li) atom gas, achieved through strong magnetic field modulation at megacycles per second frequencies. This periodic modulation creates scattering resonances whenever dressed molecular levels cross the atomic threshold. By adding a second modulation at twice the base frequency, we tune the asymmetry of resonance loss profiles and suppress two-body losses from Floquet heating. This technique enhances control over atomic interactions, expanding possibilities for quantum simulations of complex systems and studies of exotic quantum phases.
Quantum emulation of extreme non-equilibrium phenomena is a natural application of the precision and control of ultracold atomic physics experiments. In particular, ``Floquet engineering" with an explicitly time-dependent Hamiltonian enables the creation of states of matter that can only exist in the presence of strong driving. In this work, we create and study such tunable strongly driven quantum systems. We use quantum degenerate lithium as a platform because of its light mass, fast tunneling rates, and broadly tunable Feshbach resonance, which allow the study of a wide variety of systems: noninteracting Bosons, strongly interacting many body systems, and bright solitons, to name a few. We describe the experimental setup used to create a 7Li Bose-Einstein condensate as an archetypal quantum platform, and then discuss three key results: the first direct measurement of position-space Bloch oscillations in a cold atom system, the creation of a massive relativistic harmonic oscillator, and finally the demonstration of a new method for controlled long-range quantum coherent transport enabled by Floquet band engineering.
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Ultracold chemistry operates in a regime where thermal motion is suppressed to the microkelvin scale, allowing quantum mechanics to dictate every aspect of molecular interaction. This paper reviews the theoretical foundations and experimental breakthroughs that now make coherent control of ultracold reactions possible. It first outlines the separation of short- and long-range physics through quantum defect theory, emphasizing why short-range dynamics remain intractable and why universal loss emerges naturally. It then examines how long-range potentials, resonances, and quantum interference enable tunable scattering behavior. Two major milestones anchor this discussion: phase-coherent atom–atom–molecule coupling, which confirms the transfer and control of reaction phase, and the experimental resolution of long-range atom–molecule Feshbach resonances using a Fabry–P´erot interferometer model. Finally, it highlights the recent observation of a magnetically tunable molecule–molecule Feshbach resonance in NaLi, overturning long-held assumptions about the impossibility of resonance control in complex molecular systems. Together, these results demonstrate that ultracold molecules can be engineered to undergo fully coherent, interference-driven reactions, establishing a framework for quantum-controlled chemistry and laying the groundwork for applications in quantum simulation and computation.
This Thesis describes new mechanisms for controlling elastic and inelastic collisions of ultracold atoms and molecules with static electromagnetic and laser fields. The dynamical properties of ultracold atoms are usually tuned in experiments by applying an external magnetic field to induce a Feshbach resonance. The work presented in this Thesis demonstrates the possibility of inducing and manipulating Feshbach resonances with electric fields. We discuss in detail the mechanisms of electric-field-induced resonances in ultracold mixtures of alkali metal atoms and demonstrate that electric fields may shift and split the magnetic resonances. We show that electric fields may spin up the collision complex of ultracold atoms and induce anisotropic scattering which may be exploited in experiments on many-body dynamics of ultracold gaseous mixtures. The mechanisms of electric-field-induced resonances described in this Thesis allow for two-dimensional control of inter-particle interactions, leading to total control over ultracold gases. To guide future experiments, we generate accurate interaction potentials for ultracold Li--Rb mixtures by fitting positions and widths of experimentally measured Feshbach resonances. Ultracold atomic and molecular gases can be confined by laser fields in one or two dimensions which produces an optical lattice of ultracold particles. We develop a multichannel scattering theory for collisions of atoms and molecules in two dimensions and explore the effects of the confining laser potential on inelastic and reactive collisions of ultracold atoms and molecules in a 1D optical lattice. We show that ultracold collisions can be controlled in a quasi-2D geometry by varying the orientation of a magnetic field with respect to the confinement plane normal and demonstrate that the threshold energy dependence of cross sections for inelastic collisions in an optical lattice can be tuned by varying the confining potential and the magnetic field. Our results show that applying laser confinement in one dimension may stabilize ultracold systems with large scattering lengths, which may open up interesting opportunities for studies of ultracold controlled chemistry and might lead to a new research direction of ultracold chemistry in restricted geometries.
We describe two-field optical techniques to control interactions in Feshbach resonances for two-body scattering in ultracold gases. These techniques create a molecular dark state in the closed channel of a magnetically tunable Feshbach resonance, greatly suppressing optical scattering compared to single optical field methods. The dark-state method enables control of the effective range, by creating narrow features that modify the energy dependence of the scattering phase shift, as well as control of the elastic and inelastic parts of the zero-energy sss-wave scattering amplitude. We determine the scattering length and the effective range from an effective range expansion, by calculating the momentum-dependent scattering phase shift from the two-body scattering state.
We propose a general method for optical control of magnetic Feshbach resonances in ultracold atomic gases with more than one molecular state in an energetically closed channel. Using two optical frequencies to couple two states in the closed channel, inelastic loss arising from spontaneous emission is greatly suppressed by destructive quantum interference at the two-photon resonance, i.e., dark-state formation, while the scattering length is widely tunable by varying the frequencies and/or intensities of the optical fields. This technique is of particular interest for a two-component atomic Fermi gas, which is stable near a Feshbach resonance.