In conventional balanced-detection measurements, sensitivity can generally be improved by increasing the optical power. However, in many systems this approach reaches an upper bound beyond which increasing the probe power can damage the sample or degrade the measurement. In THz time-domain spectroscopy, this bound is set by nonlinear noise and measurement back-action. When this ceiling is reached by classical techniques, a potential avenue to improve the signal-to-noise ratio is by using quantum metrological resources. This work reports the development of a bright, ultrafast twin-beam source, exhibiting more than 6 dB of noise suppression up to microwatt optical power levels, together with an ultra-low-noise balanced photoreceiver with sub-shot-noise performance. Integrating these technologies into a THz-TDS system developed in collaboration with colleagues we demonstrate, for the first time to our knowledge, a measurable enhancement in sensitivity by harnessing quantum correlations when compared with a classical source under identical conditions. Although the implemented THz-TDS setup deviates from conventional polarimetric schemes, which typically achieve higher sensitivity, these results show that quantum methods can provide a sensitivity enhancement in field-resolved THz spectroscopy. Beyond this demonstration, the developed twin-beam source has clear potential for wider use as its brightness, stability and correlation strength make it an attractive candidate for ultrafast, differential transient absorption measurements.
In conventional balanced-detection measurements, sensitivity can generally be improved by increasing the optical power. However, in many systems this approach reaches an upper bound beyond which increasing the probe power can damage the sample or degrade the measurement. In THz time-domain spectroscopy, this bound is set by nonlinear noise and measurement back-action. When this ceiling is reached by classical techniques, a potential avenue to improve the signal-to-noise ratio is by using quantum metrological resources. This work reports the development of a bright, ultrafast twin-beam source, exhibiting more than 6 dB of noise suppression up to microwatt optical power levels, together with an ultra-low-noise balanced photoreceiver with sub-shot-noise performance. Integrating these technologies into a THz-TDS system developed in collaboration with colleagues we demonstrate, for the first time to our knowledge, a measurable enhancement in sensitivity by harnessing quantum correlations when compared with a classical source under identical conditions. Although the implemented THz-TDS setup deviates from conventional polarimetric schemes, which typically achieve higher sensitivity, these results show that quantum methods can provide a sensitivity enhancement in field-resolved THz spectroscopy. Beyond this demonstration, the developed twin-beam source has clear potential for wider use as its brightness, stability and correlation strength make it an attractive candidate for ultrafast, differential transient absorption measurements.
The optical shot-noise limit of a laser beam represents the classical limit in precision and signal to noise ratio achievable in optical sensors and imaging systems. It is known that quantum states of light, such as squeezed light and quantum correlated twin beams can be used to enhance precision and signal to noise ratio to beyond this limit. This promises optical sensors with fundamentally superior performance to the state of the art. While quantum-enhanced signal to noise ratio has been demonstrated with macroscopic powers of squeezed probe beam, demonstrations of quantum enhanced precision have remained at extremely low powers of light (femto-Watts). Here we will give examples where increasing SNR with quantum light is not sufficient to increase precision and we will review proof of principle experiments that have demonstrated sub shot noise precision, including for absorption spectroscopy and imaging. We will also report our efforts to achieve this sub-shot-noise precision performance for transmission measurement with ~0.1mW of average probe power, equating to ~10W peak power in a pulsed experiment. Time permitting, we will discuss how integrated optics and integrated electronics enables 10s GHz bandwidth in the detection of squeezed light, for integrated quantum sensor technology.
Quantum metrology leverages quantum resources to surpass classical limits in measurement sensitivity, enabling new capabilities across fields ranging from fundamental physics to sensing, imaging, and navigation. As these techniques mature, an increasing emphasis is being placed on translating quantum-enhanced performance into practical, robust systems that can operate outside controlled laboratory environments. The overarching objective of the work presented in this dissertation is to develop sensing platforms that achieve improved performance by leveraging quantum resources in realistic, noisy environments. In particular, this work focuses on the use of squeezed states of light, and investigates how two-mode squeezed states generated through four-wave mixing can be developed into compact sources and integrated with practical fiber-optic and plasmonic sensing platforms. Squeezed states of light, and in particular two-mode squeezed states (twin beams), constitute a powerful resource in quantum metrology. Their reduced quantum noise enables measurements below the noise level that can be achieved with classical resources, know as the shot-noise limit, offering genuine quantum advantages in precision sensing and measurement. Beyond their fundamental interest, such states provide a pathway toward practical quantum technologies capable of outperforming classical approaches in real-world applications. For many practical implementations, it is therefore highly advantageous to demonstrate squeezed light sources that are compact, stable, and compatible with existing photonic infrastructures. This is needed to lower the barrier to incorporate quantum resources into experiments and sensing platforms, particularly in environments where bulky or delicate optical setups are impractical. To demonstrate a pathway toward practical quantum sensing with squeezed light, this dissertation presents experimental studies spanning both the development of deployable squeezed-light sources and their application in practical or real-world sensing platforms. We present the development of a compact, narrowband, fiber-coupled source of squeezed light based on four-wave mixing in hot Rb 85 vapor. The system achieves more than 4 dB of intensity-difference squeezing after propagation through polarization-maintaining fibers, demonstrating that strong quantum correlations can be preserved even when fiber coupled. This platform serves as a standalone proof-of-principle demonstration of a deployable, low–size, weight, and power (low-SWaP) squeezed-light source that is well suited for applications where fiber delivery of quantum-correlated light can be readily integrated into existing experimental and sensing platforms. In addition to this source development, the dissertation investigates two distinct applications of twin-beam for quantum-enhanced sensing. The first one focuses on fiber Bragg grating (FBG) sensors, which are widely used to monitor strain, vibration, and temperature in applications ranging from civil infrastructure and aerospace systems to oil and gas pipeline monitoring. By coupling the squeezed light into separate FBGs and employing differential detection, common-mode noise is suppressed while localized perturbations are retained. This work provides a feasibility study for using twin-beams to enhance the sensitivity of FBG-based sensors beyond classical limits while providing robustness against environmental noise. The second application examines plasmonic sensors based on surface plasmon resonances in metallic nanostructures, which enable highly sensitive detection of small changes in refractive index. Such plasmonic sensors are particularly useful for applications in chemical and biological sensing, environmental monitoring, and lab-on-chip platforms, where compactness and high sensitivity to refractive index changes are critical. A dual-probing scheme is introduced in which both beams of a two-mode squeezed state interact with a polarization-dependent plasmonic nanostructure. By exploiting opposite spectral response for orthogonal polarizations, this approach improves measurement sensitivity relative to our previous technique of using one beam to probe the plasmonic sensor and the other to serve as a reference. This new technique takes advantage of transducing information into both the beams while preserving the benefits of differential detection for noise cancellation. Taken together, these studies illustrate complementary approaches for leveraging quantum correlations for practical sensing problems. Through the development of a compact, fiber-compatible squeezed-light source and independent demonstrations of enhanced performance in both fiber-optic and plasmonic sensors, this dissertation advances pathways for translating quantum sensing approaches based on quantum states of light from laboratory demonstrations into deployable metrology tools.
The time-resolved detection of mid- to far-infrared electric fields absorbed and emitted by molecules is among the most sensitive spectroscopic approaches and has the potential to transform sensing in fields such as security screening, quality control, and medical diagnostics. However, the sensitivity of the standard detection approach, which relies on encoding the far-infrared electric field into amplitude modulation of a visible or near-infrared probe laser pulse, is limited by the shot noise of the latter. This constraint cannot be overcome without using a quantum resource. Here, we show that this constraint can be overcome using a two-mode squeezed state. Quantum-correlated ultrashort pulses, generated by parametric down-conversion, enhance the sensitivity of far-infrared detection beyond the classical limit, achieving a twofold reduction in measured noise. This advancement paves the way for further development of ultrafast quantum metrology, moving toward quantum-enhanced time-resolved electric field spectroscopy with sensitivities beyond the standard quantum limit.
Dual-comb spectroscopy (DCS) is a powerful technique for spectroscopic sensing, offering exceptional spectral bandwidth, resolution, precision, and speed. However, its performance is fundamentally limited by quantum noise inherent to coherent-state optical combs. Here, we overcome this barrier by introducing quantum correlation-enhanced DCS using correlated twin combs generated via seeded four-wave mixing. One comb acts as a local oscillator to decode molecular signals, while the twin suppresses shot noise through intensity-difference squeezing, achieving a 2 dB signal-to-noise ratio improvement beyond the shot-noise limit-equivalent to a 2.6× measurement speed enhancement. Notably, when coupled with up-conversion spectroscopy, our technique records comb-line-resolved, high-resolution (7.5 pm) spectra in the critical 3 μm region for molecular fingerprinting. These results bridge quantum optics and frequency comb spectroscopy, offering great potential for trace gas detection, precision metrology, and chemical analysis. Future developments in detector efficiency and nanophotonic integration could further enhance its scalability and impact.
Abstract Dual-comb spectroscopy (DCS) is a powerful technique for spectroscopic sensing, offering exceptional resolution, precision, and speed. However, its performance is fundamentally limited by quantum noise inherent to coherent-state optical combs. Here, we overcome this barrier by introducing quantum correlation-enhanced DCS using correlated twin combs generated via seeded four-wave mixing. One comb acts as a local oscillator to decode molecular signals, while the twin suppresses shot noise through intensity-difference squeezing, achieving a 2 dB signal-to-noise ratio improvement beyond the shot-noise limit—equivalent to a 2.6× measurement speed enhancement. Notably, when paired with up-conversion spectroscopy, our approach achieves comb-line-resolved, high-resolution spectra (0.0067 cm⁻¹, 7.5 pm) in the critical 3 μm region for molecular fingerprinting. These results bridge quantum optics and frequency comb spectroscopy, offering great potential for trace gas detection, precision metrology, and chemical analysis. Future developments in detector efficiency and nanophotonic integration could further enhance its scalability and impact.