This paper develops a mathematical foundation for probability-time, an ordering parameter that measures irreversible progression along quantum state-space trajectories distinct from chronological time. In the setting of finite-dimensional CPTP dynamics with nonnegative entropy production, probability-time is defined as the accumulated information-geometric arc length of the entropy-producing component of the system’s progression. The paper describes an axiomatic characterization that isolates the invariant content of the construction: monotonicity on dissipative trajectories, stationarity under reversible evolution, and equivalence under strictly monotone reparameterizations. Within this framework, admissible contractive monotone metrics are shown to generate a common irreversible ordering while producing generally distinct numerical parameterizations. For commuting trajectories, the metrics yield only metric-dependent scalings, whereas the noncommuting trajectories exhibit genuinely nonlinear metric dependence. In detailed-balance regimes the relation between probability-time and Spohn entropy production is analyzed, demonstrating the failure of global strong canonicality but establishing a near-equilibrium quadratic relation under the Kubo–Mori metric. We thereby clarify in what sense probability-time provides a geometric measure of irreversible progression.
This paper develops a mathematical foundation for probability-time, an ordering parameter that measures irreversible progression along quantum state-space trajectories distinct from chronological time. In the setting of finite-dimensional CPTP dynamics with nonnegative entropy production, probability-time is defined as the accumulated information-geometric arc length of the entropy-producing component of the system’s progression. The paper describes an axiomatic characterization that isolates the invariant content of the construction: monotonicity on dissipative trajectories, stationarity under reversible evolution, and equivalence under strictly monotone reparameterizations. Within this framework, admissible contractive monotone metrics are shown to generate a common irreversible ordering while producing generally distinct numerical parameterizations. For commuting trajectories, the metrics yield only metric-dependent scalings, whereas the noncommuting trajectories exhibit genuinely nonlinear metric dependence. In detailed-balance regimes the relation between probability-time and Spohn entropy production is analyzed, demonstrating the failure of global strong canonicality but establishing a near-equilibrium quadratic relation under the Kubo–Mori metric. We thereby clarify in what sense probability-time provides a geometric measure of irreversible progression.
We extend the probability-time framework—defined as the information-geometric arc-length of irreversible trajectories in state space— to a two-qubit open-system setting and sharpen its interpretation using a cross-metric amplitude-damping simulation. Probability-time is defined as the accumulated information-geometric arc-length of the irreversible component of a trajectory in density-operator space. For a Bell-state initial condition evolved under local dephasing and local amplitude damping, the dephasing case shows approximate collapse of concurrence curves when expressed against probability-time, whereas amplitude damping does not. The latest simulation further shows that, for the same two-qubit amplitude-damping trajectory, both the Bures--Helstrom and Kubo--Mori constructions produce monotone probability-time while yielding different numerical parameterizations. This supports a more precise claim: the metric-independent content of probability-time is the induced irreversible ordering, while the numerical parameterization remains metric-dependent.
Abstract We consider the temporal evolution of an isolated system of N particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy, S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to dS/dt = 0: The entropy S does not change in time t. Thereby it is irrelevant, whether we consider a non-equilibrium state or an equilibrium state. Consequently, the system cannot irreversibly change by entropy production dS/dt > 0 from S′ to S max. This is a paradoxial result, which contradicts the experience. It can be traced back to the von Neumann equation, which in principle describes reversible processes and hence is unsuitable for calculating the irreversible evolution of the entropy S in time t. Each irreversible process is accompanied by a positive entropy production P = dS/dt ≥ 0 inside the system, which only vanishes in case of the equilibrium state. In order to overcome the above mentioned difficulties, we assign an operator P to the entropy production P, which is defined by the eigenvalue equation P |u〉 = P|u〉 with the state vector |u〉 of the N-particle system. There was an extensive discussion about the relation between the production of entropy P on one hand and the progression of time t on the other. Making use of this concept, we combine the operator of entropy production P with the time-development operator U (t, t 0) of the system and finally deduce the infinitesimal unitary operator U (t+τ,t) = 1 + (i/k)τ P by means of very general assumptions. Here P means the generator of the infinitesimal progression of time τ = t − t 0 and k the Boltzmann constant, representing the atomic entropy unit. Similarly to P we also treat the time t as an observable, defined by t |u〉 = t|u〉. We apply the infinitesimal time-evolution operator U (t+τ,t) to the operator of time t and finally obtain the P – t commutation relation i[ P , t ] = k, which is independent of τ. It shows that the operators P and t do not commute, and hence P and t are not sharply defined simultaneously. Instead we have uncertainties ΔP and Δt on measuring P and t, which are given by the P–t uncertainty relation ΔPΔt ≥ k/2. It readily allows a discussion of the evolution of the entropy S of the isolated system in time t from S′ to S max. Now, the irreversible steps are correctly described by the entropy production P = dS/dt > 0, while the thermal equilibrium is given by P = 0, ΔP = 0, and thus the lifetime of the equilibrium state Δt = ∞. According to the P–t uncertainty relation, the Boltzmann constant k is similarly important to the quantum thermodynamics of irreversible processes like Planck′s constant h to usual quantum mechanics.
We derive geometrical bounds on the irreversibility in both quantum and classical Markovian open systems that satisfy the detailed balance condition. Using information geometry, we prove that irreversible entropy production is bounded from below by a modified Wasserstein distance between the initial and final states, thus strengthening the Clausius inequality in the reversible-Markov case. The modified metric can be regarded as a discrete-state generalization of the Wasserstein metric, which has been used to bound dissipation in continuous-state Langevin systems. Notably, the derived bounds can be interpreted as the quantum and classical speed limits, implying that the associated entropy production constrains the minimum time of transforming a system state. We illustrate the results on several systems and show that a tighter bound than the Carnot bound for the efficiency of quantum heat engines can be obtained.
We consider the temporal evolution of an isolated system of particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to the unexpected result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, which could not irreversibly change from S′ to S max by entropy production P > 0. This contradicts the second law of thermodynamics. The paradoxial result can be traced back to the Liouville theorem. To overcome this difficulty, we introduce the t–P space. The time t and the entropy production P are observables in quantum thermodynamics. They are defined by the eigenvalue equations t|t〉 = t|t〉 and P|P〉 = P|P〉. The operators t and P do not commute. We have a non-vanishing commutator, [t,P] = ik, and consequently a t–P uncertainty relation, ΔtΔP ≥ k/2. The Boltzmann constant k is characteristic of quantum thermodynamics and represents the atomic entropy unit. — The time evolution operator U(τ) = exp[−(i/k)τP] shifts the time t by τ, U(τ)|t〉 = |t + τ〉. The generator of τ is the operator P of entropy production. Then the eigenvector |P〉 is also an eigenket of U(t), and it follows with progressing time τ ≥ 0 that τP ≥ 0 and hence P = dS/dt ≥ 0. This is the second law of thermodynamics, which is correctly reproduced in quantum thermodynamics. — Exchanging −τ for +τ replaces the equations of forward time +τ by the equations of backward time −τ. Independent of the direction of the arrow of time, the entropy of the system always increases or remains constant in the limit of the equilibrium state, dS ≥ 0. This is characteristic of irreversibility, for the system does not return to its initial state on time reversal. — The t–P uncertainty relation allows to discuss the temporal evolution of the expectation value 〈P〉 of entropy production and the lifetime Δt of the transient states, the system passes through on approaching the equilibrium state. In case of a non-equilibrium state 〈P〉, ΔP, and Δt are finite. On approaching the equilibrium state, 〈P〉 and ΔP decrease, consequently Δt increases. Finally, in the case of equilibrium (eq), we have 〈P〉eq = 0, ΔP eq = 0, and Δt eq → ∞. The lifetime of the equilibrium state is unlimited, because the entropy production 〈P〉 and the uncertainty of entropy production ΔP exactly vanish. The temporal evolution of the system can be described by means of a phenomenological equation.
We develop a geometric formulation of stochastic dynamics in which noise, diffusion, path probabilities, fluctuation theorems, and entropy production arise from the intrinsic geometry of an evolving manifold rather than from externally imposed randomness. Within the theory of moving manifolds, we establish a curvature-noise correspondence: fluctuations are governed by the inverse curvature tensor, while entropy production is controlled by curvature deformation. The invariant continuity law on a moving hypersurface yields a geometric Fokker-Planck equation, and curvature-velocity coupling generates a quadratic Onsager-Machlup functional determining path weights. The resulting entropy functional satisfies a curvature-driven monotonicity law, providing a geometric derivation of the Second Law. In two dimensions, the curvature invariant reduces to Gaussian curvature and encodes topology, so topological transitions produce discrete entropy jumps. When the ambient space carries a Minkowskian signature, the same curvature-kinetic quadratic form that generates dissipative thermal weights produces oscillatory phase weights, and the Laplace-Beltrami operator governing entropy evolution acquires a Schrödinger-type structure. This provides a geometric resolution of the apparent distinction between classical stochastic behaviour and quantum dynamics. These results show that stochastic behaviour, thermodynamic irreversibility, and quantum transition amplitudes are unified within the moving manifold framework. Geometry does not merely accommodate stochasticity; stochastic behaviour arises as a consequence of deterministic geometric evolution. The theory predicts curvature-controlled anisotropic diffusion, entropy jumps at topology-changing events, and a geometric thermal-quantum crossover in which classical stochastic weights and quantum amplitudes are generated by the same curvature-kinetic action.