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EDP Sciences eBooks

Chapter 1 The wave function and Schrodinger equation

Published Apr 30, 2026• 0 citations
Publisher
DOI
10.1051/978-2-7598-3939-1.c002

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This chapter introduces the concepts of the relativistic theory to basic problems of quantum physics, in particular, the extension of the Schrodinger equation to a relativistic form. Starting from the fundamental laws of relativity, the chapter evaluates the Klein–Gordon equation and investigates if the equation can be considered a generalization of the non-relativistic Schrodinger equation to the case of the relativistic energy. The chapter shows that the wave function, which is a solution to the Klein–Gordon equation, cannot be connected with the probability wave function. For this reason, the Dirac equation is used to solve the problems faced by the Klein–Gordon equation. The Dirac equation also includes the spin. The advantage of the Dirac equation over the Schrodinger and Klein–Gordon equations is that it naturally includes the spin. In the Schrodinger and Klein–Gordon equations, the spin is not present and has to be added to the wave function manually whenever the wave function determines a system with the spin.

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The major problem in quantum physics is to find the wave function of a given physical system and to understand (predict) how the wave function of the system evolves in time, or how it changes under external influences. In 1926, Erwin Schrodinger predicted that the wave function of a given physical system might be completely determined if the total energy of the system was known. Since the equation represents a real physical system, it must satisfy the following conditions: the equation must be linear and coefficients appearing in this equation should only depend on the parameters characteristic of the particle. This chapter focuses on to the non-relativistic case only. It considers the case of a free particle moving in one dimension. The chapter shows that the Schrodinger equation can be obtained from the energy of the free particle. It shows that the Schrodinger equation guarantees the conservation of normalization of the wave function.

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This chapter introduces the concepts of the relativistic theory to basic problems of quantum physics, in particular, the extension of the Schrodinger equation to a relativistic form. Starting from the fundamental laws of relativity, the chapter evaluates the Klein–Gordon equation and investigates if the equation can be considered a generalization of the non-relativistic Schrodinger equation to the case of the relativistic energy. The chapter shows that the wave function, which is a solution to the Klein–Gordon equation, cannot be connected with the probability wave function. For this reason, the Dirac equation is used to solve the problems faced by the Klein–Gordon equation. The Dirac equation also includes the spin. The advantage of the Dirac equation over the Schrodinger and Klein–Gordon equations is that it naturally includes the spin. In the Schrodinger and Klein–Gordon equations, the spin is not present and has to be added to the wave function manually whenever the wave function determines a system with the spin.
The major problem in quantum physics is to find the wave function of a given physical system and to understand (predict) how the wave function of the system evolves in time, or how it changes under external influences. In 1926, Erwin Schrodinger predicted that the wave function of a given physical system might be completely determined if the total energy of the system was known. Since the equation represents a real physical system, it must satisfy the following conditions: the equation must be linear and coefficients appearing in this equation should only depend on the parameters characteristic of the particle. This chapter focuses on to the non-relativistic case only. It considers the case of a free particle moving in one dimension. The chapter shows that the Schrodinger equation can be obtained from the energy of the free particle. It shows that the Schrodinger equation guarantees the conservation of normalization of the wave function.