Chapter 21. Wave Mechanics - the Schrödinger Equation

Sergey V. Gaponenko

Let us return from optics to mechanics and explore the analogy to its fullest extent. In optics the old system of mechanics corresponds to intellectually operating with isolated mutually independent light rays. The new undulatory mechanics corresponds to the wave theory of light . Erwin Schrödinger, Nobel lecture , 1933 In this chapter we shall see that electromagnetic waves and electrons feature a number of common properties under conditions of spatial confinement. Simple and familiar problems from introductory quantum mechanics and textbook wave optics are recalled in this chapter to emphasize the basic features of waves in spatially inhomogeneous media. Herewith we make a first step towards understanding the properties of electrons and electromagnetic waves in nanostructures and notice that these properties in many instances are counterparts. Different formulas and statements of this chapter can be found in handbooks on quantum mechanics and wave optics. A few textbooks on quantum mechanics do consider analogies of propagation and reflection phenomena in wave optics with those in wave mechanics. Isomorphism of the Schrödinger and Helmholtz equations In Chapter 2 we discussed that an electron in quantum mechanics is described by the wave function, the square of its absolute value giving the probability of finding an electron at a specific point in space. This function satisfies the Schrödinger equation (2.56) which is the second-order differential equation with respect to space and the first-order differential equation with respect to time.

Maurice A. de Gosson

Ana Marı́a Cetto, Luis de la Peña

Chapter 4 shows that, just as Heisenberg’s matrix mechanics represented a break with classical physics and the beginning of a new physics, Schrödinger’s wave mechanics represented another, no less radical, break with classical physics and at the same time opened up another path to the quantum world. Schrödinger’s theory is shown to make substantial use of de Broglie’s waves and related phenomena. The Schrödinger equation, being wave-like, constitutes mathematically an eigenvalue problem for bounded systems, and thus naturally leads to quantization, as is illustrated with a couple of simple examples. The chapter ends with Dirac’s abstract formulation, which has the advantage of being suitable for any description, be it Heisenberg’s, Schrödinger’s or any other.

Gennaro Auletta, Mauro Fortunato, Giorgio Parisi A

In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems. Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.