This thesis explores non-equilibrium phenomena in quantum many-body systems, with a focus on correlated electron systems and photon Bose-Einstein condensates. The first part develops the theoretical foundation, beginning with the Lindblad master equation and the construction of non-equilibrium quantum field theory. The two-particle irreducible effective action formalism is introduced, from which the Kadanoff-Baym equations for real-time evolution and the Dyson equation for steady-states are derived. The theoretical groundwork continues with a treatment of strongly correlated electron systems, where non-equilibrium dynamical mean-field theory (DMFT), auxiliary particles, and the non-crossing approximation (NCA) are introduced. These techniques, together with the Lindblad and Kadanoff-Baym approaches, are used throughout the subsequent chapters. The second part presents the main research projects of this thesis. The first two projects are concerned with the fate of the heavy fermion state under irradiation of light. To accurately incorporate light-matter interactions in this case, dipole transitions must be included. In the first project a periodically driven system is considered, where the light can be treated semiclassically. A Floquet DMFT+NCA framework is developed, revealing the mechanisms and conditions under which the heavy fermion state is most strongly suppressed. The second project analyzes a THz spectroscopy experiment performed on CeCu6. In this case a semi-classical treatment of the light field is no longer sufficient, and a full two-time evolution of all the non-equilibrium Green functions is necessary. This approach reveals the microscopic mechanisms underlying the collapse and revival of the Kondo state observed in the experiment. The next project investigates a recent experiment regarding an observation of a non-Hermitian phase transition in EuO. The equilibrium properties of EuO are first analyzed, and then an exciton model is constructed that gives rise to the non-Hermitian phase transition, in good agreement with experimental observations. In the final project, a photon Bose-Einstein condensate in a dye-filled microcavity is studied. A stabilization mechanism, distinct from thermalization, is revealed which admits a condensate phase for orders of magnitude longer than the experimentally relevant timescales.
This thesis explores non-equilibrium phenomena in quantum many-body systems, with a focus on correlated electron systems and photon Bose-Einstein condensates. The first part develops the theoretical foundation, beginning with the Lindblad master equation and the construction of non-equilibrium quantum field theory. The two-particle irreducible effective action formalism is introduced, from which the Kadanoff-Baym equations for real-time evolution and the Dyson equation for steady-states are derived. The theoretical groundwork continues with a treatment of strongly correlated electron systems, where non-equilibrium dynamical mean-field theory (DMFT), auxiliary particles, and the non-crossing approximation (NCA) are introduced. These techniques, together with the Lindblad and Kadanoff-Baym approaches, are used throughout the subsequent chapters. The second part presents the main research projects of this thesis. The first two projects are concerned with the fate of the heavy fermion state under irradiation of light. To accurately incorporate light-matter interactions in this case, dipole transitions must be included. In the first project a periodically driven system is considered, where the light can be treated semiclassically. A Floquet DMFT+NCA framework is developed, revealing the mechanisms and conditions under which the heavy fermion state is most strongly suppressed. The second project analyzes a THz spectroscopy experiment performed on CeCu6. In this case a semi-classical treatment of the light field is no longer sufficient, and a full two-time evolution of all the non-equilibrium Green functions is necessary. This approach reveals the microscopic mechanisms underlying the collapse and revival of the Kondo state observed in the experiment. The next project investigates a recent experiment regarding an observation of a non-Hermitian phase transition in EuO. The equilibrium properties of EuO are first analyzed, and then an exciton model is constructed that gives rise to the non-Hermitian phase transition, in good agreement with experimental observations. In the final project, a photon Bose-Einstein condensate in a dye-filled microcavity is studied. A stabilization mechanism, distinct from thermalization, is revealed which admits a condensate phase for orders of magnitude longer than the experimentally relevant timescales.
In this thesis we study Bose-Einstein condensation of photons. In Chapter 1 we describe the current experimental set-up and we explain the two important features of the Bose-Einstein condensate of light: dissipation through the interaction with the external reservoir of dye molecules and driving by the external pumping. In Chapter 2 we use the Schwinger-Keldysh formalism to describe the complete time evolution of the light. We show that the finite-lifetime effects of the photons due to the interaction with the dye can be characterized by a single dimensionless parameter, that depends on the power of the external laser pumping the dye. We also determine spectral functions and collective modes of the photon gas in both the normal and the Bose-Einstein condensed phases. In Chapter 3 we demonstrate that the finite-lifetime effects on the spatial first-order correlation functions of the condensed light are negligible, but are important for the temporal first-order correlations. Furthermore, we show that in the normal state the first-order correlations of the photons are suppressed by the interaction with the dye. In Chapter 4 we develop a model to describe the effect of interactions on the number fluctuations in Bose-Einstein condensates. We find good agreement between the observed number fluctuations in the light Bose-Einstein condensate and the results of our model for different interaction strenghts. In Chapter 5 we propose an experiment to observe phase diffusion in the Bose-Einstein condensate of photons and we predict the outcome of individual measurements. In our model we incorporate quantum and thermal fluctuations as well as the finite-lifetime effects. In Chapter 6 we investigate the light in the presence of a periodic potential and we study the transition from a superfluid to a Mott-insulator. We demonstrate that in this system the true Mott-insulating state is longer present due the interactions with the dye molecules. Finally, in Chapter 7 we consider Bose-Einstein condensation of light in nano-fabricated semiconductor microcavities. We demonstrate that in this system there is also a single dimensionless damping parameter that depends on the external pumping. We propose to use the experimental freedom to investigate the superfluidity of the photons via the excitation of scissors modes. We determine the frequency and damping of these scissors modes. We also calculate the density-density correlations of the excited light fluid and we show that this contains a signature of the dynamical Casimir effect.
In this thesis, several cases of non-equilibrium phenomena and quantum phase transitions in strongly correlated electron systems are analyzed. The unconventional critical behavior near magnetic quantum phase transitions in various heavy-fermion metals has triggered proposals on the breakdown of the Kondo effect at the critical point. In part I, we investigate, within one specific scenario, the fate of such a zero-temperature transition upon coupling of the electronic to lattice degrees of freedom. We study a Kondo-Heisenberg model with volume-dependent Kondo coupling � this model displays both Kondo volume collapse and Kondo-breakdown transitions. Within a large-N treatment, we find that the Kondo breakdown transition remains of second order except for very soft lattices. Finally, we relate our findings to current heavy-fermion experiments. Using non-equilibrium Green�s functions, we derive transport equations for the degrees of freedom participating in the quantum critical region of the Kondo breakdown transition. We discuss conditions under which the transport of electrical charge is described by the independent motion of conduction electrons and auxiliary bosons. Under these conditions, we derive a semiclassical transport equation for the bosons and quantitatively discuss the electrical conductivity of the whole system. Motivated by pressure experiments on FeAs-122 superconductors, in part II we propose a scenario based on local-moment physics to explain salient features at the magnetic phase boundary of CaFe2As2. In this scenario, the low-pressure magnetic phase derives from Fe moments, which become screened in the paramagnetic high-pressure phase. The quantum phase transition can be described as an orbital-selective Mott transition, which is rendered first order by coupling to the lattice. These ideas are illustrated by a suitable mean-field analysis of an Anderson lattice model. An analytical description of non-equilibrium phenomena in interacting quantum systems is rarely possible. In part III we present one example where such a description can be achieved, namely the ferromagnetic Kondo model. In equilibrium, this model is tractable via perturbative renormalization-group techniques. We employ a recently developed extension of the flow-equation method to calculate the non-equilibrium decay of the local magnetization at zero temperature. The flow equations admit analytical solutions which become exact at short and long times, in the latter case revealing that the system always retains a memory of its initial state. Finally, in part IV we analyze the Nernst effect resulting from normal state quasiparticles in the cuprates in presence of various types of translational symmetry breaking. In the electron-doped cuprates, the Nernst signal resulting from a reconstruction of the Fermi surface due to spin density wave order is discussed. An order parameter consistent with the reconstruction of the Fermi surface detected in electron-doped materials is shown to sharply enhance the Nernst signal close to optimal doping. Within a semiclassical treatment, the obtained magnitude and position of the enhanced Nernst signal agrees with Nernst measurements in electron-doped cuprates. In the hole-doped cuprates, we discuss relations between the normal-state Nernst effect and stripe order. We find that Fermi pockets caused by translational symmetry breaking lead to a strongly enhanced Nernst signal with a sign depending on the modulation period of the ordered state and other details of the Fermi surface. This implies differences between antiferromagnetic and charge-only stripes. We compare our findings with recent data from La1.6−xNd0.4SrxCuO4 and YBa2Cu3Oy.
Quantum many-body systems coupling photonic and matter degrees of freedom are ideal for the realization of driven open quantum dynamics at the intersection of quantum optics and condensed matter. They offer the possibility to address unresolved issues regarding a variety of non-equilibrium phenomena. In such open systems, the substructure of the reservoir then introduces further timescales that may enter into competition with rapid system processes, raising long-standing questions about the influence of non-Markovian effects on dynamics and equilibration out of equilibrium. \n \nThe central result of this thesis is a general pseudo-particle technique that can be applied to a large class of models of interacting light and matter and allows for realistic and efficient simulations of the full non-equilibrium dynamics of these systems. Since organic molecules, as used in experiments with photon condensates, which provide the main area of application for this thesis, possess an electronic transition coupled to vibrational phonon modes, we construct a representation where an auxiliary boson is assigned to each vibrational state of the molecule. An operator constraint then enforces single occupation across all of these states. We emphasize that we implement the operator constraint exactly and that we are the first to apply a faithful auxiliary-boson representation to open quantum systems. \n \nAs a contribution to bridging the gap between well-understood equilibrium and less explored non-equilibrium phenomena, we investigate photon condensates as they are driven away from equilibrium. The earliest signs of the non-equilibrium character of the driven-dissipative photon gas do not manifest in the spectrally resolved intensity distribution but in the time dependence of the intensity fluctuations. The energy flow through the system renders it {non-Hermitian} and induces a novel driven-dissipative transition in the second-order correlations characterized by the appearance of exceptional points. If only the static intensity spectrum is monitored, this transition remains unnoticed, as does the fact that the system is not truly in equilibrium. Non-Markovian effects due to the non-separability of system and reservoir timescales are shown to become important far away from equilibrium. Furthermore, we derive a novel photon-condensate Gross-Pitaevskii equation, which is capable of describing photo-molecular coherence. Such effects cannot be captured by existing theories and hence serve as a validation of our auxiliary-boson method. These results provide a building block to understanding the properties of the photon condensates in stationary operation where they act as fluctuating light sources. In the future, lattice systems of coupled photon condensates may lead to the appearance of novel driven-dissipative phases of light.
Cold atoms trapped in optical lattices (crystals of light) provide a pristine platform for exploring quantum many body physics. Motivated by several recent experiments, this thesis examines the equilibrium and non-equilibrium dynamics of a Bose-Einstein condensate (BEC) loaded in a low dimensional optical lattice in order to realize novel quantum phases. There are two main research directions in this thesis. The first one involves the possibility that exotic order spontaneously forms when two-component bosons are trapped in a honeycomb lattice. My studies on this theme is motivated by the observation of a “twisted superfluid” state in Prof. Klaus Sengstock’s group at Hamburg (Soltan-Panahi et al., Nat. Phys. 8, 71 (2012)). A twisted superfluid involves Bose-Einstein condensation into a state whose order parameter has a spatially varying phase. In chapter 3, I study the stability of a Bose-Einstein condensate towards forming a twisted superfluid within the framework of mean field theory. Despite a exhaustive numerical search I do not find a parameter regime with a twisted superfluid. This search involved all experimentally relevant parameter regimes and therefore mean field theory predicted that the experimentalists should not observe a twisted superfluid. I conclude that the experimental observations were either a manifestation of counter superfluidity or due to interactions during time-of-flight. Subsequent experiments showed that the observations were an artifact of the measurement process. The second research direction in this thesis is an exploration of the stability of periodically driven quantum systems (also known as Floquet systems). Floquet systems can be used to realize exotic non-equilibrium quantum phases which do not have a counterpart in static systems. However, the driving can cause these systems to heat up which presents a major obstacle to creating exotic states. To explore this issue in a concrete example, I model an experiment (Parker, Ha, and Chin, Nat. Phys. 9, 769 (2013)) where a Bose-Einstein condensate loaded in an optical lattice is subjected to periodic shaking. I investigate the stability of this Floquet BEC to interactions. This research direction consists of 3 studies. In chapter 4, I first do this analysis for a purely one-dimensional system and identify a large parameter regime where the BEC is stable. In the next two chapters, I go beyond 1D and consider the role of transverse degrees of freedom. This is because the shaken lattice experiments that I model involves a 1D array of pancakes. I find that this geometry leads to much more dissipation than a purely 1D system. This extra dissipation arises because interactions can transfer energy between different directions. In chapter 5, I consider the extreme case where there is no transverse confinement. I find that in the absence of transverse confinement, a one-dimensional Floquet BEC is generically unstable. Finally, in chapter 6, I consider harmonic transverse confinement modeling the crossover between chapters 4 and 5. I find that as the transverse confinement is made stronger, the atom loss rate initially increases, but beyond a critical transverse confinement, the atom loss disappears due to unavailability of phase space for scattering. I also predict that if the transverse confinement is tuned to the vicinity of certain magic values, the heating rate exhibits a sharp drop. I perform similar analyses for a shaken square lattice and find that generically a low-dimensional Floquet BEC can be stabilized by suitably designing the transverse confinement.
The quantum theory of many-particle systems is deeply connected to the mathematical formalism and techniques of quantum field theory, which are crucial in order describe the emergent phenomena that arise in condensed matter physics. The main goal of this thesis is to provide a unified description of quantum field theory methods in the context of many-particle physics in order to extend and develop these techniques to better understand the different quantum properties of matter. This both furthers the conceptual understanding of quantum many-body correlation and also allows for the development of novel theoretical techniques that combine the different formalisms employed in condensed matter theory, quantum chemistry and nuclear physics. To achieve this aim, the thesis is composed of two parts. Part I deals with many-body fermion-fermion interactions and is physically motivated by the non-relativistic electronic structure problem. Here, we introduce the Keldysh contour formulation of quantum field theory to provide a unified presentation of quantum systems both in and out-ofequilibrium. Then, we extend the conventional quantum theory of many-particle systems, based on hermitian quantum mechanics, to describe systems governed by non-hermitan Hamiltonians. This allows us to present a natural unification of two major pillars in the ab initio quantum theory of many-particle systems: coupled-cluster theory and the Green’s function formalism. This unification is further demonstrated through the emergence of the coupled-cluster amplitude equations from the Green’s function formalism. In particular, this analysis has direct bearing on the development of novel theoretical approaches to the electronic structure and nuclear many-body problems. Our findings are also relevant to the study of general non-hermitian as well as open quantum systems. Part II focuses on the quantum field theory of electron-nuclear interactions in infinite solids. Here, we use the Keldysh contour representation presented in Part I to understand excited state dynamics that include electron-electron and electron-lattice interactions in materials. We also derive the analytic continuation of the Green’s function for systems that have continuous eigenspectra. This analysis demonstrates the relationship between the Green’s function formalism and scattering theory, making the role of the continuum and causality conditions explicitly clear in the context of the pole condition of the Dyson equation. Using the analytic continuation of the propagator, we provide an in-depth analysis of electron-phonon and exciton-phonon scattering channels, with a particular focus on phonon-driven exciton dissociation scattering. Our theoretical analysis then firmly demonstrates the connection between the extension of the Bethe-Salpeter equation approach to include electron-phonon interactions and effective field theories based on composite exciton-phonon coupling. We subsequently combine the techniques presented in Part I, based on the Dyson supermatrix formulation, with the analysis presented in Part II to calculate, from first principles, the effects of including electron-phonon interactions on the excited states of heterogeneous semiconductors. Finally, we provide a summary of the fundamental contributions presented in this thesis and the potential further research directions to be pursued.
In this thesis, we describe methods for solving quantum impurity models out of equilibrium, and consider several applications of these methods. Quantum impurity models describe systems in which a small subsystem (the impurity) is coupled to a large external environment (the bath). These models are useful in describing a wide variety of physical systems, including quantum dots, absorbed adatoms, and molecular junctions. They are also important for the study of lattice models, such as the Hubbard model, where they appear as auxiliary problems within the framework of dynamical mean field theory (DMFT). Many interesting phenomena in these systems, such as transport through a quantum dot, or optical pumping of a Mott insulator, occur away from equilibrium. Theoretical description of these phenomena requires methods that are capable of handling both real time evolution and strong correlation effects presenting a formidable challenge. In this thesis, we describe several methods for the solution of non-equilibrium quantum impurity models which meet this challenge. These methods are based on an expansion in the coupling between the impurity and the bath known as the hybridization expansion. Chapter 1 gives an introduction to the problems addressed in this thesis. Chapter 2 provides a brief overview of Keldysh formalism for nonequilibrium problems. Chapter 3 describes the bare hybridization expansion for the Anderson impurity model as well as its bold extensions. In particular we derive the non-crossing approximation (NCA), the one-crossing approximation (OCA), the inchworm expansion, and a bold expansion for the impurity Green's function. Chapter 4 describes the implementation of a quantum Monte Carlo algorithm based on the inchworm expansion. The rest of the thesis describes applications of these algorithms to problems of physical interest. Chapters 5 and 6 apply the methods previously described to understanding the Kondo effect in quantum dot systems. The first chapter examines the behavior of the Kondo effect under an applied voltage bias, a classic non-equilibrium strongly-correlated problem. The second chapter examines different ways of measuring the cloud of electrons which screen the impurity spin in the Kondo regime. Chapters 7 and 8 apply the same methods to the Hubbard model using the Dynamical mean-field theory (DMFT) mapping. The first chapter studies the Hubbard model in equilibrium using the numerically exact inchworm quantum Monte Carlo method. The second chapter studies the possibility of dynamic switching between the metal and Mott-insulator states of the Hubbard model using the one-crossing approximation (OCA). Finally chapter 9 gives some overall conclusions and suggests future directions for the development of hybridization expansion methods.