We demonstrate that entropy-optimized control protocols inspired by Quantum Heat Engine (QHE) cycles robustly reduce the Lyapunov exponent (quantum chaos rate) by ~42% in chaotic quantum systems. Comprehensive validation confirms the effect across system sizes (N=6-12), 50 independent trials (100% consistency), and multiple unitary types. We derive t_emergent = S/σ from Page-Wootters and Landauer principles, predicting that emergent time flow is proportional to entropy production rate. QHE-modified Page-Wootters simulation confirms ω_QHE/ω_standard = 0.6002. Direct entropy measurement validates the derivation causally: ΔS_QHE/ΔS_standard = 0.6000, matching the frequency ratio within 0.03%. These results establish that thermodynamic control of entropy production directly controls emergent time flow, providing the first numerical demonstration that time's flow rate can be modified via entropy management. Key results:• 42% Lyapunov suppression (λ ratio = 0.58)• Page-Wootters clock slowing (ω ratio = 0.6002)• Causal validation (entropy ratio = 0.6000)• Derived relationship: t_emergent = S/σ
We demonstrate that entropy-optimized control protocols inspired by Quantum Heat Engine (QHE) cycles robustly reduce the Lyapunov exponent (quantum chaos rate) by ~42% in chaotic quantum systems. Comprehensive validation confirms the effect across system sizes (N=6-12), 50 independent trials (100% consistency), and multiple unitary types. We derive t_emergent = S/σ from Page-Wootters and Landauer principles, predicting that emergent time flow is proportional to entropy production rate. QHE-modified Page-Wootters simulation confirms ω_QHE/ω_standard = 0.6002. Direct entropy measurement validates the derivation causally: ΔS_QHE/ΔS_standard = 0.6000, matching the frequency ratio within 0.03%. These results establish that thermodynamic control of entropy production directly controls emergent time flow, providing the first numerical demonstration that time's flow rate can be modified via entropy management. Key results:• 42% Lyapunov suppression (λ ratio = 0.58)• Page-Wootters clock slowing (ω ratio = 0.6002)• Causal validation (entropy ratio = 0.6000)• Derived relationship: t_emergent = S/σ
Standard quantum mechanics describes the evolution of physical systems through unitary Schr¨odinger dynamics, while decoherence and wavefunction collapse are introduced through additional postulates or environmental interactions. Although highly successful operationally, the theory does not provide a fundamental dynamical mechanism explaining the emergence of classical localization from microscopic evolution. n this work we propose an entropy-weighted causal dynamics framework, referred to as Quantum Causal Entropy (QCE), in which each microscopic causal transition contributes both a phase increment and an entropy cost. Starting from a local causal update rule, Ψ → eiθℓ−∆SℓΨ, we derive a modified evolution equation in which the standard Hamiltonian generator is supplemented by an entropy-production operator. The resulting entropy-corrected Schr¨odinger equation takes the form iℏ dΨ dt =H − iℏλSˆΨ, where Sˆ represents the entropy rate associated with microscopic causal processes and λ is an entropy coupling constant. We show that the standard unitary Schr¨odinger evolution is recovered in the limit of vanishing entropy coupling, while finite entropy production leads naturally to decoherence, interference suppression, and effective measurement localization without invoking an explicit collapse postulate. A corresponding density-matrix evolution equation is derived, providing a thermodynamic description of coherence decay. The framework therefore provides a dynamical link between quantum evolution, information entropy, and emergent classicality, and suggests experimentally testable corrections to coherence behavior in controlled quantum systems
Squeezed thermal reservoirs have been proposed as a route to boosting the efficiency and power of quantum heat engines beyond the standard Carnot bound, since squeezing injects an effective negative entropy that can, in principle, be converted into extra work. What remains poorly quantified is the entropy-production cost that driving a working qubit against a squeezed bath actually incurs once finite-time operation and reservoir decoherence are taken into account. We simulate a quantum Otto-cycle heat engine built from a two-level working system coupled alternately to a hot reservoir at temperature 4.2 K, squeezed with squeezing parameter r ranging from 0 to 1.2, and an unsqueezed cold reservoir at 0.8 K, integrating the Lindblad master equation across 42 combinations of squeezing parameter and cycle duration between 0.05 and 2.0 (in units of the inverse qubit gap). At r = 0, mean entropy production per cycle was 0.223 k_B, consistent with standard finite-time Otto-cycle behaviour, but rose to 0.361 k_B at r = 1.2, a 62% increase, even as extractable work per cycle increased by 41%, from 0.184 to 0.259 (in units of the qubit gap). The ratio of work output to entropy production, an effective thermodynamic figure of merit, was therefore not monotonic in squeezing: it peaked at r = 0.6, where work per unit entropy produced reached 0.98, 15% above the unsqueezed value of 0.85, before declining at higher squeezing as entropy production began to outpace the marginal work gain. Power output at the maximum-power cycle duration increased with squeezing across the full range tested, from 0.31 (gap units) at r = 0 to 0.52 at r = 1.2, a 68% gain, but efficiency at maximum power fell from 0.41 to 0.33 over the same range, a trade-off traced out in detail in Table 1. A decomposition of total entropy production attributed 58-71% to hot-bath coupling across all squeezing values, with the squeezed-bath contribution alone rising from undefined at r = 0 to 34% of hot-bath entropy production at r = 1.2, while coherence generated during the unitary strokes accounted for a comparatively stable 12-18% regardless of squeezing strength. These results indicate that reservoir squeezing in quantum heat engines delivers a genuine power and work advantage but at a non-negligible and squeezing-dependent entropy cost, with an intermediate squeezing level offering the best entropy-normalized performance rather than the strongest squeezing tested, a finding directly relevant to the design of squeezed-bath quantum thermal devices operating under realistic decoherence.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.
In closed quantum systems, local information spreads throughout the entire system and becomes highly complex under unitary evolution. In contrast, when the system is embedded in an environment, system-environment coupling can transfer information from the system into the environment, thereby reducing the rate of complexity growth within the system. This leads to the environment-induced scrambling transition established in previous works. In this work, we identify entropy injection from the environment as a different physical process that instead enhances many-body chaos. Our setup consists of coupling a system that is already in equilibrium with one environment to another environment, which serves as an entropy reservoir and drives the system into a non-equilibrium state. When entropy flows into the system through either heat transfer or particle transfer, the effective Hilbert space explored by the system enlarges, a mechanism that can enhance many-body chaos. We explicitly demonstrate this idea by constructing a solvable complex Brownian SYK model, in which both the relaxation toward the steady state and the steady-state quantum Lyapunov exponent can be computed analytically. Our results provide a controllable mechanism for tuning quantum scrambling through entropy flow in quantum many-body systems coupled to environments.
Thermodynamics of information identifies information flow as a thermodynamic resource, but whether quantum coherence and collective coupling can enhance it at low entropy-production cost remains unresolved. We address this question for interacting open quantum systems by deriving a thermodynamic uncertainty relation that bounds information flow in terms of entropy production in nonequilibrium steady states. We construct a quantum engine in which N-fold degenerate ground and excited states are collectively coupled to heat baths. Collective jumps enhance heat currents and information flow linearly with N, while entropy production remains independent of N, realizing a high-power, low-dissipation autonomous quantum Maxwell's demon that leverages collectively enhanced information flow to pump heat against a temperature gradient. Beyond steady states, collective interactions amplify the unitary component of quantum information flow, yielding a quadratic enhancement of the free-energy charging power of quantum batteries. Our results reveal scalable advantages of quantum coherence and collective effects in quantum engines.