In this Letter, we propose that superradiant echoes can be achieved at room temperature by applying a laser illumination and a microwave Hahn echo sequence to a diamond with a high concentration of nitrogen-vacancy (NV) centers placed in a dielectric microwave cavity. We identify that the combined action of two microwave driving pulses and a free evolution imprints a phase grating among NV spin sub-ensembles in frequency space, and multiple re-phasing of the grated spin sub-ensembles leads to multiple superradiant echoes through a collective coupling with the cavity. Furthermore, we show that the superradiant echoes can be actively tailored with the microwave pulses and the laser illumination by modifying the grating parameters, and the multiple re-phasing dynamics is analogous to the one leading to superradiant beats in optical clock system. In the future, the spin sub-ensembles grating and the resulting echoes can be further optimized with dynamical decoupling, which might pave the way for applications in quantum sensing.
Nitrogen-vacancy (NV) centers have emerged as a highly sensitive platform for spatially resolved temperature measurements. When the
∣0⟩→∣+1⟩ and
∣0⟩→∣−1⟩ transitions are nearly degenerate and the Rabi frequency is comparable to the transition splitting, the spin dynamics encountered during pulsed protocols for temperature measurement can significantly alter the intended accumulation of temperature-dependent phase. We investigate these triplet (
∣0⟩,
∣±1⟩) spin dynamics and their effect on pulsed thermometry protocols under these conditions. We find that the conventional thermal-echo timing produces negligible temperature-sensitive signal amplitudes at the common-mode detuning. However, we find that the nominal spin-echo timing produces resolvable oscillations at the common-mode detuning, leading to a strong temperature-sensitive carrier signal. This departure from the expected protocol behavior is qualitatively captured by an ensemble model of the triplet dynamics, which supports significant dark-state leakage as a plausible mechanism for the temperature-sensitive response. This mixing-enabled thermal echo uses a four-phase quadrature readout that resolves the signed oscillation frequency and is validated using independent sweeps of the microwave carrier frequency and fluid temperature. We further assess the ability of a four-refocusing-pulse (LDD4B) low-field dynamical-decoupling sequence to extend the NV coherence and find that while the echo retains a sensitivity to common-mode detuning, the effective phase-accumulation interval corresponds to approximately half the total evolution time. These findings could support the use of pulsed NV thermometry in biological or mobile applications where applying magnetic bias fields is impractical and microwave power may be limited.
Nitrogen-vacancy (NV) ensembles are viable magnetometers to be implemented on nanosatellites for monitoring geomagnetic fluctuations, which are credible precursors for predicting earthquakes at short notice. In this work, a Haar wavelet-based quantum sensing method is proposed to reconstruct the time-varying waveform of geomagnetic fluctuations in the very low frequency band. To collect different frequency components of fluctuations waveform at once, we propose a schematic to employ multiple NV ensembles (NVEs), with each controlled by an independent microwave source. Berry sequences are applied on one set of NVEs to extract the scaling coefficients from accumulated geometric phases to reconstruct near-dc components of a waveform. Spin-echo sequences are applied to another set of NVEs to extract the Haar wavelet coefficients from the dynamic phases to reconstruct high-frequency components. The efficacy of the proposed sensing protocol implemented on multiple NVEs is validated by reconstructing a waveform of geomagnetic fluctuations from a DEMETER satellite dataset through simulations. Each NVE is assumed to contain
N=108uncorrelated NV centers. The application of a Berry sequence to each NVE can achieve the maximum detectable magnetic field of over
460 μT, resolving the issues of phase ambiguity and hyperfine-induced detuning if conventional Ramsey sequence were applied. The feasibility of the proposed simulation scenario considering spin-bath noise within an NVE is justified by simulations. The effects of wavelet scales, Rabi frequency in Berry sequence, and number of NV centers in each NVE are analyzed. The proposed NVE quantum sensors operated with the proposed sensing protocol can be installed on nanosatellites to monitor global geomagnetic fluctuations, with sub-
μs temporal resolution in the near future.