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Science China Physics Mechanics and Astronomy

Theoretical study of superradiant masing with solid-state spins at room temperature

Qilong Wu, Yuan Zhang, Hao Wu, Shi‐Lei Su, Kaikai Liu, Mark Oxborrow, Chongxin Shan, Klaus Mølmer

Published May 14, 2024• 7 citations
Publisher
DOI
10.1007/s11433-023-2347-0

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Proposal for a room-temperature diamond maser

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The application of masers is limited by its demanding working conditions (high vacuum or low temperature). A room-temperature solid-state maser is highly desirable, but the lifetimes of emitters (electron spins) in solids at room temperature are usually too short (∼ns) for population inversion. Masing from pentacene spins in p-terphenyl crystals, which have a long spin lifetime (∼0.1 ms), has been demonstrated. This maser, however, operates only in the pulsed mode. Here we propose a room-temperature maser based on nitrogen-vacancy centres in diamond, which features the longest known solid-state spin lifetime (∼5 ms) at room temperature, high optical pumping efficiency (∼10(6) s(-1)) and material stability. Our numerical simulation demonstrates that a maser with a coherence time of approximately minutes is feasible under readily accessible conditions (cavity Q-factor ∼5 × 10(4), diamond size ∼3 × 3 × 0.5 mm(3) and pump power <10 W). A room-temperature diamond maser may facilitate a broad range of microwave technologies.

arXiv:1509.07909•Nature Communications•Sep 23, 2015•88 citations
Steady-state superradiance and superradiant lasing attract significant attentions in the field of optical lattice clocks, but have not been achieved so far due to the technical challenges and atom loss problem. In this article, we propose that their counter-part may be observed in the microwave domain with solid-state spins-microwave resonator systems at room temperature with realistic technical restrictions. To validate our proposal, we investigate systematically the system dynamics and steady-state by solving quantum master equations for the multi-level and multi-process dynamic of trillions of spins. To this end, we employ a mean-field approach, and convert the mean-field dynamics of the spin ensemble into the one in a more intuitive Dicke state picture. Our calculations show that for systems with nitrogen vacancy center spins and pentacene molecular spins the superradiant Rabi oscillations occur firstly due to transitions among different Dicke states, and the subsequent continuous-wave superradiant masing can achieve a linewidth well below millihertz. Our work may guide further exploration of transient and steady-state superradiant masing with the mentioned and other solid-state spins systems, such as silicon vacancy centers in silicon carbide and boron vacancy centers in hexagonal boron nitride, where the coherent radiation with ultra-narrow linewidth may find applications in deep-space communications, radio astronomy and high-precision metrology.
The application of masers is limited by its demanding working conditions (high vacuum or low temperature). A room-temperature solid-state maser is highly desirable, but the lifetimes of emitters (electron spins) in solids at room temperature are usually too short (∼ns) for population inversion. Masing from pentacene spins in p-terphenyl crystals, which have a long spin lifetime (∼0.1 ms), has been demonstrated. This maser, however, operates only in the pulsed mode. Here we propose a room-temperature maser based on nitrogen-vacancy centres in diamond, which features the longest known solid-state spin lifetime (∼5 ms) at room temperature, high optical pumping efficiency (∼10(6) s(-1)) and material stability. Our numerical simulation demonstrates that a maser with a coherence time of approximately minutes is feasible under readily accessible conditions (cavity Q-factor ∼5 × 10(4), diamond size ∼3 × 3 × 0.5 mm(3) and pump power <10 W). A room-temperature diamond maser may facilitate a broad range of microwave technologies.