Quantum systems interacting with a dissipative environment can effectively be described by a nonlinear modification of the Schrodinger equation. For some standard problems that possess analytical solutions, e.g. the free motion and the harmonic oscillator, also the nonlinear equation can be solved in a closed form and has Gaussian-shaped wave packet solutions. The equation determining the time-evolution of the wave-packet width is - already in the case of the usual conservative Schrodinger equation - nonlinear and provides the quantities that are necessary to construct the Green’s function for the respective system. The Green’s functions for the conservative and dissipative cases will be given explicitly in position and momentum space.
Quantum systems interacting with a dissipative environment can effectively be described by a nonlinear modification of the Schrodinger equation. For some standard problems that possess analytical solutions, e.g. the free motion and the harmonic oscillator, also the nonlinear equation can be solved in a closed form and has Gaussian-shaped wave packet solutions. The equation determining the time-evolution of the wave-packet width is - already in the case of the usual conservative Schrodinger equation - nonlinear and provides the quantities that are necessary to construct the Green’s function for the respective system. The Green’s functions for the conservative and dissipative cases will be given explicitly in position and momentum space.
We provide the exact analytic solution of the stochastic Schrödinger equation describing a harmonic oscillator interacting with a non-Markovian and dissipative environment. This result represents an arrival point in the study of non-Markovian dynamics via stochastic differential equations. It is also one of the few exactly solvable models for infinite-dimensional systems. We compute the Green's function; in the case of a free particle and with an exponentially correlated noise, we discuss the evolution of Gaussian wave functions.
Taking into account wave-particle duality and the uncertainty principle, a nonlinear Schrödinger wave equation (NLSE) for the description of dissipative systems can be constructed by applying only Newton's form of classical mechanics. A comparison between our NLSE for dissipative systems and the linear time-dependent SE for conservative systems shows that, for free motion and motion in a harmonic potential, both equations have Gaussian wave-packet solutions. The time dependence of the maximum of these functions is governed by the classical (real) Newtonian equation of motion. While the time dependence of the width of the wave packet can be determined from a nonlinear complex Bernoulli/Ricatti type differential equation. This can be done by transformation into a Newton-type equation for a real quantity α (which is proportional to the square root of the width), including a kind of “centrifugal force” term. This equation can be solved analytically and when taken with Newton's equation of motion for the mean value of the position, it forms a so-called Ermakov system. For the linear SE equation, this implies the existence of a dynamical invariant. For our NLSE we also obtain such an exact invariant, but now for a dissipative system. Furthermore, this complex nonlinear equation can be linearised using the logarithmic derivative of a complex quantity λ, thus yielding a complex Newtonian equation of motion. The absolute value of λ is equivalent to α, the phase angle can be determined using a relation that connects real and imaginary parts of λ. This relation is linked to a kind of “conservation of angular momentum” for the quantity λ in a complex plane. The relations between the above-mentioned quantities will be discussed in detail.
Based on Gaussian wave packet solutions of the time-dependent Schrödinger equation, a generalization of the conventional creation and annihilation operators and the corresponding coherent states can be obtained. This generalization includes systems where also the width of the coherent states is time-dependent as they occur for harmonic oscillators with time-dependent frequency or systems in contact with a dissipative environment. The key point is the replacement of the frequency ω 0 that occurs in the usual definition of the creation/annihilation operator by a complex time-dependent function that fulfils a nonlinear Riccati equation. This equation and its solutions depend on the system under consideration and on the (complex) initial conditions. Formal similarities also exist with supersymmetric quantum mechanics. The generalized creation and annihilation operators also allow to construct exact analytic solutions of the free motion Schrödinger equation in terms of Hermite polynomials with time-dependent variable.
The time-evolution of the maximum and the width of exact analytic wave packet (WP) solutions of the time-dependent Schrödinger equation (SE) represents the particle and wave aspects, respectively, of the quantum system.The dynamics of the maximum, located at the mean value of position, is governed by the Newtonian equation of the corresponding classical problem.The width, which is directly proportional to the position uncertainty, obeys a complex nonlinear Riccati equation which can be transformed into a real nonlinear Ermakov equation.The coupled pair of these equations yields a dynamical invariant which plays a key role in our investigation.It can be expressed in terms of a complex variable that linearizes the Riccati equation.This variable also provides the time-dependent parameters that characterize the Green's function, or Feynman kernel, of the corresponding problem.From there, also the relation between the classical and quantum dynamics of the systems can be obtained.Furthermore, the close connection between the Ermakov invariant and the Wigner function will be shown.Factorization of the dynamical invariant allows for comparison with creation/annihilation operators and supersymmetry where the partner potentials fulfil (real) Riccati equations.This provides the link to a nonlinear formulation of timeindependent quantum mechanics in terms of an Ermakov equation for the amplitude of the stationary state wave functions combined with a conservation law.Comparison with SUSY and the time-dependent problems concludes our analysis.
This thesis examines dissipative forces in physical systems in both microscopic and quantum level. The system-environment interaction is modeled by assuming that the environment is composed of simple harmonic oscillators and that there is a linear interaction between these oscillators and the system. The classical case is solved by determining the retarded Green’s function, which yields the equation of motion of the system. For quantum dissipation, the Lindblad master equation is used to describe the time evolution of the reduced density matrix of the system, and the propagator is investigated to identify important parameters, including the term of Newton's friction force.
The time-dependent Schrödinger equation for quadratic Hamiltonians has Gaussian wave packets as exact solutions. For the parametric oscillator with frequency ω(t), the width of these wave packets must be time-dependent. This time-dependence can be determined via the solution of a complex nonlinear Riccati equation or an equivalent real nonlinear Ermakov equation. All quantum dynamical properties of the system can easily be constructed from these solutions, e.g., uncertainties of position and momentum, their correlations, tunnelling currents, ground state energies, etc. In addition, the link to the corresponding classical dynamics is supplied via linearization of the Riccati equation to a complex Newtonian equation, actually representing two equations of the same kind: one for the real and one for the imaginary part. If the solution of one part is known, the missing (linear independent) solution of the other can be obtained via a conservation law for the motion in the complex plane. Knowing these two solutions, the solution of the Ermakov equation can be determined immediately plus the explicit expressions for all the quantum dynamical properties mentioned above. Furthermore, these two solutions also provide the time-dependent Green function for the systems propagation for any given initial condition, not only for Gaussians. It is also possible to obtain the corresponding Wigner function and generalized creation and annihilation operators in this way. In searching for problems with analytical solutions, the crucial point is to identify systems that have either a wave packet solution with time-dependent width (in closed form) that obeys a Riccati equation, or a classical parametric oscillator with frequency ω(t) that still enables an analytical solution of the Newtonian equation. Comparing the wave packets with the solution of the diffusion equation – also a Gaussian with time-dependent width – leads to a real Riccati equation. A first attempt at "complexifying" this equation turns out to be problematic. Nevertheless, it provides a clue to time-dependent frequencies inversely proportional to time that lead to Newtonian equations with analytical solutions. Following a detailed analysis of the corresponding quantum dynamics and energetics, possible extensions of the method are indicated.