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Journal of Mathematical Physics

On the quantum mechanical treatment of dissipative systems

Rainer W. Hasse

Published Oct 1, 1975• 310 citations
Publisher

Abstract

Two types of Hamiltonians are investigated which describe quantum mechanically a particle moving subject to a linear viscous force under the influence of a conservative force: the conventional explicitly time-dependent one and an alternative class of nonlinear Hamiltonians. In the latter group we propose a new form. By Ehrenfest’s theorem the expectation values of the operators of physical observables correspond to the classical quantities. For all Schrödinger equations we derive and discuss wavepacket, wave, stationary, and pseudostationary solutions of force free motion, free fall, and harmonic oscillator.

DOI
10.1063/1.522431

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CRC Press eBooks•Nov 30, 2003•0 citations
Two types of Hamiltonians are investigated which describe quantum mechanically a particle moving subject to a linear viscous force under the influence of a conservative force: the conventional explicitly time-dependent one and an alternative class of nonlinear Hamiltonians. In the latter group we propose a new form. By Ehrenfest’s theorem the expectation values of the operators of physical observables correspond to the classical quantities. For all Schrödinger equations we derive and discuss wavepacket, wave, stationary, and pseudostationary solutions of force free motion, free fall, and harmonic oscillator.
The usual treatment of damping forces in quantum mechanics starts from the introduction of the explicitly time dependent Kanai Hamiltonian, which actually represents a variable mass particle, and the misinterpretation of this Hamiltonian as representing a particle of constant mass leads to certain physical difficulties. However the Hamiltonian can be modified so that it can be reinterpreted as describing a constant mass particle. Here we explicitly introduce the mass as a new dynamical variable, which allows us to write a linear, time independent Hamiltonian for the system, which can be solved by conventional methods. The damped harmonic oscillator and damped free particle are treated in detail, both for the Kanai Hamiltonian and for our case, and the solutions are compared. Our solution can be reduced to the Kanai one in appropriate circumstances, but in general it has a much greater versatility, as a result of which it can be more easily reinterpreted as describing a constant mass particle subject to a damping force, which reinterpretation is of course necessary if the method is to have practical applicability. We also show how such a reinterpretation can be carried out in detail by introducing a ’’dissipation variable’’, in terms of which one may avoid the concept of a variable mass altogether.
The close connection between the Jacobi function for a velocity-dependent dissipative system and the nonlinear Schrödinger–Langevin equation is used to study some of the features of the latter equation. Starting with the Hamiltonian for a classical system, different forms of the Jacobi generating function are obtained. With the help of these, corresponding solutions of the nonlinear wave equation are studied. It is found that the solution of the wave equation is not unique, and that it admits quasi-stationary, decaying, and asymptotically stationary solutions. Since this nonlinear wave equation is derivable from a classical generating function, it preserves some of the characteristic properties of the linear quantum theory. Among these are: (a) the lack of any correlation between noninteracting particles moving in a viscous medium, (b) the gauge independence of the observable quantities, and (c) the constancy of the density of states in phase space. This discussion can also be extended to the problem of quantal description of a harmonically bound radiating electron.
Taking into account wave-particle duality and the uncertainty principle, a nonlinear Schrödinger wave equation (NLSE) for the description of dissipative systems can be constructed by applying only Newton's form of classical mechanics. A comparison between our NLSE for dissipative systems and the linear time-dependent SE for conservative systems shows that, for free motion and motion in a harmonic potential, both equations have Gaussian wave-packet solutions. The time dependence of the maximum of these functions is governed by the classical (real) Newtonian equation of motion. While the time dependence of the width of the wave packet can be determined from a nonlinear complex Bernoulli/Ricatti type differential equation. This can be done by transformation into a Newton-type equation for a real quantity α (which is proportional to the square root of the width), including a kind of “centrifugal force” term. This equation can be solved analytically and when taken with Newton's equation of motion for the mean value of the position, it forms a so-called Ermakov system. For the linear SE equation, this implies the existence of a dynamical invariant. For our NLSE we also obtain such an exact invariant, but now for a dissipative system. Furthermore, this complex nonlinear equation can be linearised using the logarithmic derivative of a complex quantity λ, thus yielding a complex Newtonian equation of motion. The absolute value of λ is equivalent to α, the phase angle can be determined using a relation that connects real and imaginary parts of λ. This relation is linked to a kind of “conservation of angular momentum” for the quantity λ in a complex plane. The relations between the above-mentioned quantities will be discussed in detail.
Within the framework of the quantum-statistical approach, utilizing both non-Hermitian Hamiltonian and Lindblad’s jump operators, one can derive various generalizations of the von Neumann equation for reduced density operators, also known as hybrid master equations. If one considers the evolution of pure states only, i.e., disregarding the coherence between states and spontaneous transitions from pure to mixed states, then one can resort to quantum-mechanical equations of the Schrödinger type. We derive them from the hybrid master equations and study their main properties, which indicate that our equations have a larger range of applicability compared to other generalized Schrödinger equations proposed hitherto. Among other features, they can describe not only systems which remain in the stationary eigenstates of the Hamiltonian as time passes, but also those which evolve from those eigenstates. As an example, we consider a simple but important model, a quantum harmonic oscillator driven by both Hamiltonian and non-Hamiltonian terms, and derive its classical limit, which turns out to be the damped harmonic oscillator. Using this model, we demonstrate that the effects of dissipative environments of different types can cancel each other, thus resulting in an effectively dissipation-free classical system. Another discussed phenomenon is whether a non-trivial quantum system can reduce to a classical system in free motion, i.e., without experiencing any classical Newtonian forces. This uncovers a large class of quantum-mechanical non-Hamiltonian systems whose dynamics are not determined by conventional mechanics’ potentials and forces, but rather come about through quantum statistical effects caused by the system’s environment.
Quantum systems interacting with a dissipative environment can effectively be described by a nonlinear modification of the Schrodinger equation. For some standard problems that possess analytical solutions, e.g. the free motion and the harmonic oscillator, also the nonlinear equation can be solved in a closed form and has Gaussian-shaped wave packet solutions. The equation determining the time-evolution of the wave-packet width is - already in the case of the usual conservative Schrodinger equation - nonlinear and provides the quantities that are necessary to construct the Green’s function for the respective system. The Green’s functions for the conservative and dissipative cases will be given explicitly in position and momentum space.