Chapter 3 introduces the student to the matrix formulation of quantum mechanics, pioneered by Heisenberg in collaboration with Born and Jordan. It provides the basic formal elements of the Heisenberg description in terms of operators and their matrix representation, derives the Heisenberg inequality, and applies the formalism to the harmonic oscillator as a central and particularly simple quantum problem. It introduces the state vectors and their Hilbert space, and concludes with a brief discussion hinting at the physical significance of the replacement of classical continuous dynamical variables with operators as a manifestation of the coupling of the particle to the radiation field.
Chapter 3 introduces the student to the matrix formulation of quantum mechanics, pioneered by Heisenberg in collaboration with Born and Jordan. It provides the basic formal elements of the Heisenberg description in terms of operators and their matrix representation, derives the Heisenberg inequality, and applies the formalism to the harmonic oscillator as a central and particularly simple quantum problem. It introduces the state vectors and their Hilbert space, and concludes with a brief discussion hinting at the physical significance of the replacement of classical continuous dynamical variables with operators as a manifestation of the coupling of the particle to the radiation field.
Quantum mechanics can be formulated either in terms of matrix mechanics or in terms of wave mechanics. This chapter centers on a discussion of the historical origins, mathematical structure, and extension to non-Hermitian quantum theory of matrix mechanics. The development of atomic discrete spectra and the old quantum theory showed that classical mechanics could not account for the discreteness of atomic energy levels and spectral lines, which motivated Heisenberg, Born, Jordan, and others to establish matrix mechanics centered on noncommuting physical quantities. Combining the Bohr atomic model, angular momentum quantization, and radiative transitions, one can see how matrix mechanics describes the energy level structure and quantum transitions of atomic systems, and how the Heisenberg equation of motion gives the fundamental form of quantum dynamics. The example of the harmonic oscillator further shows that the discreteness of the energy spectrum can be obtained directly from the matrix method, thereby establishing a clear connection among transition frequencies, matrix elements, and radiation-induced transitions. The matrix representation corresponds to the operator theory in Hilbert space, where state vectors, inner products, complete bases, and spectral decomposition constitute the fundamental mathematical framework of quantum mechanics. For closed quantum systems, physical observables are generally required to be represented by Hermitian or self-adjoint operators, so as to ensure that their eigenvalues possess the physically acceptable property of being real numbers. The Hermiticity of an operator is also closely related to its domain and boundary conditions, which provides a mathematical possibility for the emergence of non-Hermitian Hamiltonians. Based on these discussions, this chapter further explains how non-Hermitian dynamics is connected with open systems, dissipative processes, and special boundary conditions, thereby demonstrating the natural connection between traditional matrix mechanics and modern non-Hermitian quantum theory.
This chapter deals with the matrix and vector formulation of quantum mechanics. Topics covered under the chapter are: matrices and their basic algebra, bra and ket notations, vector space and the basis vectors, inner and outer products of vectors, the orthogonalization procedure for vectors, the Schwarz inequality, linear transformation of a vector, eigenvalues and eigenvectors of a matrix, numerical methods to find eigenvalue and eigenvector, different types of matrices used in quantum mechanics, diagonalization of a matrix, the Cayley-Hamilton theorem, change of basis in a vector space and the unitary transformations, infinite-dimensional and Hilbert spaces, representation of quantum states and operators in Hilbert space, the Schrödinger equation in matrix form, assumptions of quantum mechanics in matrix formulations, the general uncertainty principle, the one dimensional harmonic oscillator, solved examples and unsolved exercises. The objectives of this chapter are to introduce the important aspects of vector and matrix algebra that have been vital in the development and the description of modern quantum mechanics and in exhibiting that the Heisenberg and Schrödinger approaches to quantum mechanics are equivalent.
This chapter introduces Heisenberg’s trajectory from old quantum mechanics towards his quantum matrix mechanics. It shows his partnership with Born and for the study of the helium atom and molecules under the old quantum theory and his work on the core model to account for the anomalous Zeeman effect in collaboration with Landé. The collaboration between Heisenberg Kramers to present the treatment between matter and radiation under the scope of the old quantum mechanics is also displayed. Then, afterwards, it is shown the birth of the matrix mechanics by its three initial papers in 1925: the Heisenberg’s paper where he replaced the motion of the electron into its transition; the Born and Jordan’s paper where they placed Heisenberg equation into matrices and found the corresponding equation of motion and the commutator between linear momentum and position of the electron; the Heisenberg, Jordan and Born’s paper where they obtained the diagonal elements of the Hamiltonian matrix (the energy of a quantum state) and its application to one-electron harmonic oscillator. Dirac’s contribution to matrix mechanics is also introduced followed the application in the quantum angular momentum (184 words).
This chapter provides a self-contained introduction to the basic aspects of Quantum Mechanics, focusing on what is must for Quantum Field Theory. The notions of state space, unitary operators, self-adjoint operators, and projective representation are covered as well as Heisenberg’s uncertainty principle. A complete proof of Stone’s theorem is given, but the spectral theory is covered only at the heuristic level. We provide an introduction to Dirac’s formalism, which is almost universally used in physics literature. The time-evolution is described in both the Schrödinger and the Heisenberg picture. A complete treatment of the harmonic oscillator, providing an introduction to the fundamental idea of creation and annihilation operators concludes the chapter.
Abstract Momentum and position operators are essential in many areas of quantum mechanics. This chapter introduces these operators and discusses their mathematical and conceptual foundations. These operators are then applied to the widely used simple harmonic oscillator model. Simple methods lead to the formal description of both the coordinate-space and momentum-space wave functions for the oscillator model. The Heisenberg uncertainty relation for the oscillator model embodies the important concept of wave–particle duality in quantum mechanics.