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Springer advanced texts in chemistry

Postulates of Quantum Mechanics and Initial Considerations

Ralph E. Christoffersen

Published Jan 1, 1989• 0 citations
Publisher
DOI
10.1007/978-1-4684-6360-6_4

Related papers

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Quantum Mechanics is a successful model to describe physical phenomena. We show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. The main postulate is: Objects are described as energy distributions in Space–Time. 1 Quantum Mechanics from START It is universally accepted that Quantum Mechanics is a successful model to describe physical phenomena, in particular of the electronic structure of atoms, molecules and solids. As such it has been reformulated in several different forms (see for example: Nine formulations of quantum mechanics, Daniel F. Styer et al. [15]). The aim of the present paper is to show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. In our approach the main postulate is: Objects are described as energy distributions in Space–Time. The theory is in fact a systematic mathematical analysis of this postulate and of other general considerations about action, energy–momentum and the role of the theory as a useful description of Nature. The paper also shows the fundamental and basic status of Density Functional Theory, also contained in our approach. The initial mathematical structure is a geometric (quadratic form based) union of space, time and action. In physics bundles of trajectories are used to describe the objects of nature: distribution of heights over a surface, a real object is described as a bundle of space-time trajectories, here we use a description as a bundle of action valves in space-time (energy densities in space following light-like lines). The author is fully aware that the presentation is strongly guided by the knowledge of the usual computational approach to study atoms, molecules and condensed matter electronic structure.

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In a quantum universe with a strong arrow of time, it is standard to postulate that the initial wave function started in a particular macrostate--the special low-entropy macrostate selected by the Past Hypothesis. Moreover, there is an additional postulate about statistical mechanical probabilities according to which the initial wave function is a "typical" choice in the macrostate (the Statistical Postulate). Together, they support a probabilistic version of the Second Law of Thermodynamics: typical initial wave functions will increase in entropy. Hence, there are two sources of randomness in such a universe: the quantum-mechanical probabilities of the Born rule and the statistical mechanical probabilities of the Statistical Postulate. I propose a new way to understand time's arrow in a quantum universe. It is based on what I call the Thermodynamic Theories of Quantum Mechanics. According to this perspective, there is a natural choice for the initial quantum state of the universe, which is given by not a wave function but by a density matrix. The initial density matrix of the universe is exactly the (normalized) projection operator onto the Past Hypothesis subspace (of the Hilbert space of the universe). Thus, given an initial subspace, we obtain a unique choice of the initial density matrix. I call this property "the conditional uniqueness" of the initial quantum state. The conditional uniqueness provides a new and general strategy to eliminate statistical mechanical probabilities in the fundamental physical theories, by which we can reduce the two sources of randomness to only the quantum mechanical one. I also explore the idea of an "absolutely unique" initial quantum state, in a way that might realize Penrose's idea (1989) of a strongly deterministic universe.

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Postulates of Quantum Mechanics

Jochen Pade

Undergraduate lecture notes in physics•Nov 7, 2013•2 citations
Quantum Mechanics is a successful model to describe physical phenomena. We show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. The main postulate is: Objects are described as energy distributions in Space–Time. 1 Quantum Mechanics from START It is universally accepted that Quantum Mechanics is a successful model to describe physical phenomena, in particular of the electronic structure of atoms, molecules and solids. As such it has been reformulated in several different forms (see for example: Nine formulations of quantum mechanics, Daniel F. Styer et al. [15]). The aim of the present paper is to show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. In our approach the main postulate is: Objects are described as energy distributions in Space–Time. The theory is in fact a systematic mathematical analysis of this postulate and of other general considerations about action, energy–momentum and the role of the theory as a useful description of Nature. The paper also shows the fundamental and basic status of Density Functional Theory, also contained in our approach. The initial mathematical structure is a geometric (quadratic form based) union of space, time and action. In physics bundles of trajectories are used to describe the objects of nature: distribution of heights over a surface, a real object is described as a bundle of space-time trajectories, here we use a description as a bundle of action valves in space-time (energy densities in space following light-like lines). The author is fully aware that the presentation is strongly guided by the knowledge of the usual computational approach to study atoms, molecules and condensed matter electronic structure.
In a quantum universe with a strong arrow of time, it is standard to postulate that the initial wave function started in a particular macrostate--the special low-entropy macrostate selected by the Past Hypothesis. Moreover, there is an additional postulate about statistical mechanical probabilities according to which the initial wave function is a "typical" choice in the macrostate (the Statistical Postulate). Together, they support a probabilistic version of the Second Law of Thermodynamics: typical initial wave functions will increase in entropy. Hence, there are two sources of randomness in such a universe: the quantum-mechanical probabilities of the Born rule and the statistical mechanical probabilities of the Statistical Postulate. I propose a new way to understand time's arrow in a quantum universe. It is based on what I call the Thermodynamic Theories of Quantum Mechanics. According to this perspective, there is a natural choice for the initial quantum state of the universe, which is given by not a wave function but by a density matrix. The initial density matrix of the universe is exactly the (normalized) projection operator onto the Past Hypothesis subspace (of the Hilbert space of the universe). Thus, given an initial subspace, we obtain a unique choice of the initial density matrix. I call this property "the conditional uniqueness" of the initial quantum state. The conditional uniqueness provides a new and general strategy to eliminate statistical mechanical probabilities in the fundamental physical theories, by which we can reduce the two sources of randomness to only the quantum mechanical one. I also explore the idea of an "absolutely unique" initial quantum state, in a way that might realize Penrose's idea (1989) of a strongly deterministic universe.
Starting with a consideration of the implication of Bell inequalities in quantum mechanics, a new quantum postulate is suggested in order to restore classical locality and causality to quantum physics: only the relative coordinates between detected quantum events are valid observables. This postulate supports the EPR view that quantum mechanics is incomplete, while also staying compatible to the Bohr view that nothing exists beyond the quantum. The new postulate follows from a more general principle of quantum relativity, which states that only correlations between experimental detections of quantum events have a real classical existence. Quantum relativity provides a framework to differentiate the quantum and classical world.