Quantum Mechanics is a successful model to describe physical phenomena. We show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. The main postulate is: Objects are described as energy distributions in Space–Time. 1 Quantum Mechanics from START It is universally accepted that Quantum Mechanics is a successful model to describe physical phenomena, in particular of the electronic structure of atoms, molecules and solids. As such it has been reformulated in several different forms (see for example: Nine formulations of quantum mechanics, Daniel F. Styer et al. [15]). The aim of the present paper is to show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. In our approach the main postulate is: Objects are described as energy distributions in Space–Time. The theory is in fact a systematic mathematical analysis of this postulate and of other general considerations about action, energy–momentum and the role of the theory as a useful description of Nature. The paper also shows the fundamental and basic status of Density Functional Theory, also contained in our approach. The initial mathematical structure is a geometric (quadratic form based) union of space, time and action. In physics bundles of trajectories are used to describe the objects of nature: distribution of heights over a surface, a real object is described as a bundle of space-time trajectories, here we use a description as a bundle of action valves in space-time (energy densities in space following light-like lines). The author is fully aware that the presentation is strongly guided by the knowledge of the usual computational approach to study atoms, molecules and condensed matter electronic structure.
Quantum Mechanics is a successful model to describe physical phenomena. We show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. The main postulate is: Objects are described as energy distributions in Space–Time. 1 Quantum Mechanics from START It is universally accepted that Quantum Mechanics is a successful model to describe physical phenomena, in particular of the electronic structure of atoms, molecules and solids. As such it has been reformulated in several different forms (see for example: Nine formulations of quantum mechanics, Daniel F. Styer et al. [15]). The aim of the present paper is to show that a simple set of postulates about the description of objects in Nature allows the derivation of the principles of QM, transforming this theory into a deductive approach to Physics. In our approach the main postulate is: Objects are described as energy distributions in Space–Time. The theory is in fact a systematic mathematical analysis of this postulate and of other general considerations about action, energy–momentum and the role of the theory as a useful description of Nature. The paper also shows the fundamental and basic status of Density Functional Theory, also contained in our approach. The initial mathematical structure is a geometric (quadratic form based) union of space, time and action. In physics bundles of trajectories are used to describe the objects of nature: distribution of heights over a surface, a real object is described as a bundle of space-time trajectories, here we use a description as a bundle of action valves in space-time (energy densities in space following light-like lines). The author is fully aware that the presentation is strongly guided by the knowledge of the usual computational approach to study atoms, molecules and condensed matter electronic structure.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
Abstract Fundamental concepts about the structure of matter have been analyzed based on cause-and-effect relations leading to the postulates of quantum mechanics. The interpretation of the characteristics of a vacuum as properties of a universal carrier medium in terms of fluid mechanics has made it possible to select consistent models of the basic objects of condensed matter. The development of concepts of the structure of the photon and electron has been supplemented by descriptions of the processes of their production and transformation. The nature of electric charges and the picture of their interaction through volumetric interference fields have been discussed. The details of the structure of the atom, the sizes of electron orbits, and the internal characteristics of some elementary particles have been clarified. The physical nature of the quantization of matter at different dimensional and energy levels has been determined. The proposed solutions to problems of a quantum can be useful for the range of physicists dealing with problems that are fundamentally unsolvable in traditional terms.
Basic scientific theories usually start with a set of hypotheses or “postulates.” There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from ‘revelations’ in the minds of ‘geniuses,’ most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the “state functions,” “operators,” and “equations of motion.” In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
Quantum mechanics was developed as a response to the inability of the classical theories of mechanics and electromagnetism to provide a satisfactory explanation of some of the properties of electromagnetic radiation and of atomic structure. As a result, a theory has emerged whose basic principles can be used to explain not only the structure and properties of atoms, molecules and solids, but also those of nuclei and of “elementary” particles such as the proton and neutron. Although there are still many features of the physics of such systems that are not fully understood, there are presently no indications that the fundamental ideas of quantum mechanics are incorrect. In order to achieve this success, quantum mechanics has been built on a foundation that contains a number of concepts that are fundamentally different from those of classical physics and which have radically altered our view of the way the physical universe operates. This book aims to elucidate and discuss the conceptual basis of the subject as well as explaining its success in describing the behaviour of atomic and subatomic systems.
Quantum theory (QT) is usually formulated in terms of abstract mathematical postulates involving Hilbert spaces, state vectors and unitary operators. In this paper, we show that the full formalism of QT can instead be derived from five simple physical requirements, based on elementary assumptions regarding preparations, transformations and measurements. This is very similar to the usual formulation of special relativity, where two simple physical requirements—the principles of relativity and light speed invariance—are used to derive the mathematical structure of Minkowski space–time. Our derivation provides insights into the physical origin of the structure of quantum state spaces (including a group-theoretic explanation of the Bloch ball and its three dimensionality) and suggests several natural possibilities to construct consistent modifications of QT.