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Rotations et Moments Angulaires en Mecanique Quantique - Rotations and angular moments in quantum mechanics

Jacques Van de Wiele

Published Jan 1, 2001• 0 citations
OpenAlex

Abstract

As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.

Related papers

Rotations and angular moments in quantum mechanics

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Comme en mécanique classique, la rotation en mécanique quantique est une transformation qui fait intervenir le moment cinétique. La différence avec la mécanique classique vient du fait que le moment cinétique est un opérateur vectoriel et non pas un vecteur ordinaire, et que ses composantes ne commutent pas deux-à-deux. Comme pour toute transformation en mécanique quantique, à chaque rotation est associé un opérateur qui agit dans l'espace des états. L'expression de cet opérateur de rotation dépend du type de rotation envisagée : rotation passive si on effectue une rotation du système de référence sans changer le système physique, rotation active si on laisse le système de référence inchangé mais on effectue une rotation sur le système physique. La première partie (Chaps. 1 et 2) de cet ouvrage traite ces deux aspects. Après avoir défini la transformation géométrique associée à la rotation la plus générale, on donne l'expression de l'opérateur de rotation dans chacun des deux cas. Les lois de transformation des champs scalaires, des champs de vecteurs et des champs de spineurs sont données ainsi que les lois de transformation des opérateurs scalaires, vectoriels et plus généralement des opérateurs de rang quelconque. La seconde partie (Chaps. 3 et 4) traite l'algèbre des moments angulaires. On définit les coefficients de couplage de 2, 3 et 4 moments angulaires ainsi que les coefficients de recouplage. La notion d'opérateur tensoriel irréductible, généralisation des opérateurs scalaire, vectoriel est introduite ainsi que le théorème de Wigner-Eckart. Les formules d'application dans des cas complexes sont données.

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This chapter shows that the three operators are Hermitian and (in a rotationally invariant system) commute with the Hamiltonian; therefore they are observable constants of the motion. It finds out what their physical significance is. By knowing from classical mechanics, the constant of the motion arising from rotational invariance is the angular momentum. The angular momentum may split up into two parts: orbital and intrinsic. The orbital part can always be described by the dependence of a wave function, whereas the intrinsic part is by definition contained in the transformation property of the wave function. In the case of a single component (scalar), no intrinsic angular momentum exists. There are—apart from the vector addition and the scalar product—two other ways of combining two vectors: the direct sum and the direct product. Both occur in the theory of angular momentum, in fact whenever symmetry is involved.

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The angular momentum plays an important role in quantum mechanics. It is no longer an ordinary vector, instead it is a vector operator, whose three components do not commute with each other. In quantum mechanics, the angular momentum becomes a vector operator. A general angular momentum is defined as a vector operator whose components are Hermitian operators satisfying the commutation relations similar to those for the orbital angular momentum. In order to obtain the eigenvalues and eigenfunctions, it is more convenient to express the orbital angular momentum operators in spherical polar coordinates. Spin angular momentum is an intrinsic property of elementary particles. In quantum computing, a qubit or quantum bit is a quantum version of the classical binary bit physically realized in a two-state quantum-mechanical system.

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The addition theorem for spherical harmonics is just a special case of the law for the transformation of spherical harmonics under rotation of their arguments. Certain operators are scalars under rotation; this means that they commute with the total angular momentum and are unchanged by the transformation. The types of operators having simple transformation properties under rotation are known generally as tensor operators. The energy eigenstates of an atom, taking into account the spin-orbit interaction, are not usually eigenstates of the z component of the total orbital angular momentum, but are eigenstates of the total angular momentum, spin plus orbital. Sehwinger has looked at the theory of angular momentum from a point of view that enables one to carry out very elegant calculations of the various quantities occurring in the theory of angular momentum. The quanta of some different oscillators are simply the quarks that compose the strongly interacting particles.

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Abstract Angular momentum in classical mechanics is given by a vector. The plane perpendicular to this vector, in accordance to central field theory, determines the space in which particle motion takes place. No such simple picture exists in quantum mechanics. The states of a particle in a central field are proportional to spherical harmonics which do not define any plane of motion. In the first part of this paper we discuss the angular distribution of particle position and compare it to the classical probabilistic approach. In the second part, the matter of addition of angular momenta is discussed. In classical mechanics this means addition of vectors, while in quantum mechanics Clebsch–Gordan coefficients have to be used. We have found classical approximations to quantum coefficients and the limit of their applicability. This analysis gives a basis for the so-called ‘vector addition model’ used in some elementary textbooks on atomic physics. It can help to better understand the addition of angular momenta in quantum mechanics.

arXiv:1907.09930•European Journal of Physics•Oct 4, 2019•0 citations
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.
Comme en mécanique classique, la rotation en mécanique quantique est une transformation qui fait intervenir le moment cinétique. La différence avec la mécanique classique vient du fait que le moment cinétique est un opérateur vectoriel et non pas un vecteur ordinaire, et que ses composantes ne commutent pas deux-à-deux. Comme pour toute transformation en mécanique quantique, à chaque rotation est associé un opérateur qui agit dans l'espace des états. L'expression de cet opérateur de rotation dépend du type de rotation envisagée : rotation passive si on effectue une rotation du système de référence sans changer le système physique, rotation active si on laisse le système de référence inchangé mais on effectue une rotation sur le système physique. La première partie (Chaps. 1 et 2) de cet ouvrage traite ces deux aspects. Après avoir défini la transformation géométrique associée à la rotation la plus générale, on donne l'expression de l'opérateur de rotation dans chacun des deux cas. Les lois de transformation des champs scalaires, des champs de vecteurs et des champs de spineurs sont données ainsi que les lois de transformation des opérateurs scalaires, vectoriels et plus généralement des opérateurs de rang quelconque. La seconde partie (Chaps. 3 et 4) traite l'algèbre des moments angulaires. On définit les coefficients de couplage de 2, 3 et 4 moments angulaires ainsi que les coefficients de recouplage. La notion d'opérateur tensoriel irréductible, généralisation des opérateurs scalaire, vectoriel est introduite ainsi que le théorème de Wigner-Eckart. Les formules d'application dans des cas complexes sont données.
This chapter shows that the three operators are Hermitian and (in a rotationally invariant system) commute with the Hamiltonian; therefore they are observable constants of the motion. It finds out what their physical significance is. By knowing from classical mechanics, the constant of the motion arising from rotational invariance is the angular momentum. The angular momentum may split up into two parts: orbital and intrinsic. The orbital part can always be described by the dependence of a wave function, whereas the intrinsic part is by definition contained in the transformation property of the wave function. In the case of a single component (scalar), no intrinsic angular momentum exists. There are—apart from the vector addition and the scalar product—two other ways of combining two vectors: the direct sum and the direct product. Both occur in the theory of angular momentum, in fact whenever symmetry is involved.
The angular momentum plays an important role in quantum mechanics. It is no longer an ordinary vector, instead it is a vector operator, whose three components do not commute with each other. In quantum mechanics, the angular momentum becomes a vector operator. A general angular momentum is defined as a vector operator whose components are Hermitian operators satisfying the commutation relations similar to those for the orbital angular momentum. In order to obtain the eigenvalues and eigenfunctions, it is more convenient to express the orbital angular momentum operators in spherical polar coordinates. Spin angular momentum is an intrinsic property of elementary particles. In quantum computing, a qubit or quantum bit is a quantum version of the classical binary bit physically realized in a two-state quantum-mechanical system.
The addition theorem for spherical harmonics is just a special case of the law for the transformation of spherical harmonics under rotation of their arguments. Certain operators are scalars under rotation; this means that they commute with the total angular momentum and are unchanged by the transformation. The types of operators having simple transformation properties under rotation are known generally as tensor operators. The energy eigenstates of an atom, taking into account the spin-orbit interaction, are not usually eigenstates of the z component of the total orbital angular momentum, but are eigenstates of the total angular momentum, spin plus orbital. Sehwinger has looked at the theory of angular momentum from a point of view that enables one to carry out very elegant calculations of the various quantities occurring in the theory of angular momentum. The quanta of some different oscillators are simply the quarks that compose the strongly interacting particles.
Abstract Angular momentum in classical mechanics is given by a vector. The plane perpendicular to this vector, in accordance to central field theory, determines the space in which particle motion takes place. No such simple picture exists in quantum mechanics. The states of a particle in a central field are proportional to spherical harmonics which do not define any plane of motion. In the first part of this paper we discuss the angular distribution of particle position and compare it to the classical probabilistic approach. In the second part, the matter of addition of angular momenta is discussed. In classical mechanics this means addition of vectors, while in quantum mechanics Clebsch–Gordan coefficients have to be used. We have found classical approximations to quantum coefficients and the limit of their applicability. This analysis gives a basis for the so-called ‘vector addition model’ used in some elementary textbooks on atomic physics. It can help to better understand the addition of angular momenta in quantum mechanics.